LAPSE:2023.6642
Published Article
LAPSE:2023.6642
Promising Hydrate Formation Promoters Based on Sodium Sulfosuccinates of Polyols
Yulia F. Chirkova, Ulukbek Zh. Mirzakimov, Matvei E. Semenov, Roman S. Pavelyev, Mikhail A. Varfolomeev
February 24, 2023
Abstract
The use of natural gas as an energy source is increasing significantly due to its low greenhouse gas emissions. However, the common methods of natural gas storage and transportation, such as liquefied or compressed natural gas, are limited in their applications because they require extreme conditions. Gas hydrate technology can be a promising alternative to conventional approaches, as artificially synthesized hydrates provide an economical, environmentally friendly, and safe medium to store energy. Nevertheless, the low rate of hydrate formation is a critical problem that hinders the industrial application of this technology. Therefore, chemical promoters are being developed to accelerate the kinetics of gas hydrate formation. In this paper, the effect of new sodium sulfosuccinate compounds, synthesized based on glycerol and pentaerythritol, on methane hydrate formation was studied. Experiments under dynamic conditions using high-pressure autoclaves demonstrated that the conversion of water-to-hydrate forms increased from 62 ± 5% in pure water to 86 ± 4% for the best promoter at concentration 500 ppm. In addition, the rate of hydrate formation increases 2−4 times for different concentrations. Moreover, none of the synthesized reagents formed foam, compared to sodium dodecyl sulfate, in which the foam rate was 3.7 ± 0.2. The obtained reagents showed good promotional properties and did not form foam, which makes them promising promoters for gas hydrate technology.
Keywords
hydrate formation promoters, kinetic promoters, methane hydrate, natural gas storage and transportation, sulfosuccinates
Suggested Citation
Chirkova YF, Mirzakimov UZ, Semenov ME, Pavelyev RS, Varfolomeev MA. Promising Hydrate Formation Promoters Based on Sodium Sulfosuccinates of Polyols. (2023). LAPSE:2023.6642
Author Affiliations
Chirkova YF: Department of Petroleum Engineering, Kazan Federal University, 420008 Kazan, Russia
Mirzakimov UZ: Department of Petroleum Engineering, Kazan Federal University, 420008 Kazan, Russia
Semenov ME: Department of Petroleum Engineering, Kazan Federal University, 420008 Kazan, Russia [ORCID]
Pavelyev RS: Department of Petroleum Engineering, Kazan Federal University, 420008 Kazan, Russia [ORCID]
Varfolomeev MA: Department of Petroleum Engineering, Kazan Federal University, 420008 Kazan, Russia [ORCID]
Journal Name
Energies
Volume
16
Issue
1
First Page
359
Year
2022
Publication Date
2022-12-28
ISSN
1996-1073
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Original Submission
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PII: en16010359, Publication Type: Journal Article
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LAPSE:2023.6642
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https://doi.org/10.3390/en16010359
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