LAPSE:2023.5826
Published Article

LAPSE:2023.5826
Production of Biodiesel from Waste Cooking Oil via Deoxygenation Using Ni-Mo/Ac Catalyst
February 23, 2023
Abstract
Waste cooking oil (WCO) from palm oil is one of the most prospective biodiesel feedstock when compared to other oil seeds. Thus, WCO has great potential as a green source of diesel fuel for engines in motor vehicles and machinery. This project aimed to study the potential of three randomly selected types of WCO, namely; sample A (used 1× once to fry an egg), sample B (used 3−5× to fry salted fish), and sample C (used repeatedly to fry banana fritter) for the production of green diesel fuel over Ni-Mo/AC (nickel and molybdenum oxides incorporated with activated carbon) catalyst through the deoxygenation (DO) process. The prepared catalyst was characterized through X-ray diffraction (XRD), thermogravimetric analysis (TGA), and field emission scanning electron microscopy (FESEM). The DO process was performed at 350 °C to remove oxygen from the WCO samples. The liquid products were analysed by gas chromatography-mass spectrometer (GC-MS) and gas chromatography-flame ionization detector (GC-FID), to measure the yields of straight-chain hydrocarbons and fractions in the range C8‒C20. Results showed that the highest n-(C8‒C20) hydrocarbon fractions were produced in the order of sample B (89.93%) > C (88.84%) > A (82.81%).
Waste cooking oil (WCO) from palm oil is one of the most prospective biodiesel feedstock when compared to other oil seeds. Thus, WCO has great potential as a green source of diesel fuel for engines in motor vehicles and machinery. This project aimed to study the potential of three randomly selected types of WCO, namely; sample A (used 1× once to fry an egg), sample B (used 3−5× to fry salted fish), and sample C (used repeatedly to fry banana fritter) for the production of green diesel fuel over Ni-Mo/AC (nickel and molybdenum oxides incorporated with activated carbon) catalyst through the deoxygenation (DO) process. The prepared catalyst was characterized through X-ray diffraction (XRD), thermogravimetric analysis (TGA), and field emission scanning electron microscopy (FESEM). The DO process was performed at 350 °C to remove oxygen from the WCO samples. The liquid products were analysed by gas chromatography-mass spectrometer (GC-MS) and gas chromatography-flame ionization detector (GC-FID), to measure the yields of straight-chain hydrocarbons and fractions in the range C8‒C20. Results showed that the highest n-(C8‒C20) hydrocarbon fractions were produced in the order of sample B (89.93%) > C (88.84%) > A (82.81%).
Record ID
Keywords
biodiesel, deoxygenation, green fuel, heterogeneous catalyst, waste cooking oil
Subject
Suggested Citation
Azman NS, Marliza TS, Mijan NA, Yun Hin TY, Khairuddin N. Production of Biodiesel from Waste Cooking Oil via Deoxygenation Using Ni-Mo/Ac Catalyst. (2023). LAPSE:2023.5826
Author Affiliations
Azman NS: Department of Basic Science and Engineering, Faculty of Agriculture and Food Sciences, Universiti Putra Malaysia Bintulu Sarawak Campus, Bintulu 97008, Malaysia [ORCID]
Marliza TS: Department of Basic Science and Engineering, Faculty of Agriculture and Food Sciences, Universiti Putra Malaysia Bintulu Sarawak Campus, Bintulu 97008, Malaysia; Catalysis Science and Technology Research Centre, Faculty of Science, Universiti Putra Malays
Mijan NA: Department of Chemical Sciences, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, UKM Bangi, Bangi 43600, Malaysia
Yun Hin TY: Catalysis Science and Technology Research Centre, Faculty of Science, Universiti Putra Malaysia, UPM Serdang, Serdang 43300, Malaysia; Chancellery Office, Universiti Malaysia Sabah, Kota Kinabalu 88400, Malaysia
Khairuddin N: Department of Basic Science and Engineering, Faculty of Agriculture and Food Sciences, Universiti Putra Malaysia Bintulu Sarawak Campus, Bintulu 97008, Malaysia [ORCID]
Marliza TS: Department of Basic Science and Engineering, Faculty of Agriculture and Food Sciences, Universiti Putra Malaysia Bintulu Sarawak Campus, Bintulu 97008, Malaysia; Catalysis Science and Technology Research Centre, Faculty of Science, Universiti Putra Malays
Mijan NA: Department of Chemical Sciences, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, UKM Bangi, Bangi 43600, Malaysia
Yun Hin TY: Catalysis Science and Technology Research Centre, Faculty of Science, Universiti Putra Malaysia, UPM Serdang, Serdang 43300, Malaysia; Chancellery Office, Universiti Malaysia Sabah, Kota Kinabalu 88400, Malaysia
Khairuddin N: Department of Basic Science and Engineering, Faculty of Agriculture and Food Sciences, Universiti Putra Malaysia Bintulu Sarawak Campus, Bintulu 97008, Malaysia [ORCID]
Journal Name
Processes
Volume
9
Issue
5
First Page
750
Year
2021
Publication Date
2021-04-23
ISSN
2227-9717
Version Comments
Original Submission
Other Meta
PII: pr9050750, Publication Type: Journal Article
Record Map
Published Article

LAPSE:2023.5826
This Record
External Link

https://doi.org/10.3390/pr9050750
Publisher Version
Download
Meta
Record Statistics
Record Views
240
Version History
[v1] (Original Submission)
Feb 23, 2023
Verified by curator on
Feb 23, 2023
This Version Number
v1
Citations
Most Recent
This Version
URL Here
https://psecommunity.org/LAPSE:2023.5826
Record Owner
Auto Uploader for LAPSE
Links to Related Works
[0.1 s]
