LAPSE:2023.5799
Published Article

LAPSE:2023.5799
Freeze-Drying versus Heat-Drying: Effect on Protein-Based Superabsorbent Material
February 23, 2023
Abstract
Porcine plasma protein is a by-product of the meat industry, which has already been applied in the manufacture of superabsorbent materials. The effects of plasticizer content (0%, 25%, 50%), together with those of the drying method (freeze-drying, thermal drying at 50 °C), during the processing of superabsorbent porcine plasma matrices were studied in this manuscript. Although the presence of glycerol accelerated the water absorption kinetics, the highest water absorption (~550%) was achieved by samples not containing any plasticizer. Viscoelasticity decreased at higher glycerol contents and especially after water absorption. When swollen samples were dried through freeze-drying, porous structures with a sponge-like appearance were obtained. Oppositely, thermally dried samples suffered an evident shrinkage that reduced porosity, displaying a more uniform surface. The effect of the drying method was observed since only freeze-dried samples can be rehydrated, displaying a superabsorbent ability (absorption higher than 1000%), which could be used in several applications (food, agriculture, personal care).
Porcine plasma protein is a by-product of the meat industry, which has already been applied in the manufacture of superabsorbent materials. The effects of plasticizer content (0%, 25%, 50%), together with those of the drying method (freeze-drying, thermal drying at 50 °C), during the processing of superabsorbent porcine plasma matrices were studied in this manuscript. Although the presence of glycerol accelerated the water absorption kinetics, the highest water absorption (~550%) was achieved by samples not containing any plasticizer. Viscoelasticity decreased at higher glycerol contents and especially after water absorption. When swollen samples were dried through freeze-drying, porous structures with a sponge-like appearance were obtained. Oppositely, thermally dried samples suffered an evident shrinkage that reduced porosity, displaying a more uniform surface. The effect of the drying method was observed since only freeze-dried samples can be rehydrated, displaying a superabsorbent ability (absorption higher than 1000%), which could be used in several applications (food, agriculture, personal care).
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Keywords
polymer processing, porcine plasma protein, rheology, superabsorbent materials
Subject
Suggested Citation
Álvarez-Castillo E, Bengoechea C, Felix M, Guerrero A. Freeze-Drying versus Heat-Drying: Effect on Protein-Based Superabsorbent Material. (2023). LAPSE:2023.5799
Author Affiliations
Álvarez-Castillo E: Departamento de Ingeniería Química, Escuela Politécnica Superior, C/Virgen de África, 7, Universidad de Sevilla, 41011 Sevilla, Spain [ORCID]
Bengoechea C: Departamento de Ingeniería Química, Escuela Politécnica Superior, C/Virgen de África, 7, Universidad de Sevilla, 41011 Sevilla, Spain [ORCID]
Felix M: Departamento de Ingeniería Química, Escuela Politécnica Superior, C/Virgen de África, 7, Universidad de Sevilla, 41011 Sevilla, Spain [ORCID]
Guerrero A: Departamento de Ingeniería Química, Escuela Politécnica Superior, C/Virgen de África, 7, Universidad de Sevilla, 41011 Sevilla, Spain [ORCID]
Bengoechea C: Departamento de Ingeniería Química, Escuela Politécnica Superior, C/Virgen de África, 7, Universidad de Sevilla, 41011 Sevilla, Spain [ORCID]
Felix M: Departamento de Ingeniería Química, Escuela Politécnica Superior, C/Virgen de África, 7, Universidad de Sevilla, 41011 Sevilla, Spain [ORCID]
Guerrero A: Departamento de Ingeniería Química, Escuela Politécnica Superior, C/Virgen de África, 7, Universidad de Sevilla, 41011 Sevilla, Spain [ORCID]
Journal Name
Processes
Volume
9
Issue
6
First Page
1076
Year
2021
Publication Date
2021-06-21
ISSN
2227-9717
Version Comments
Original Submission
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PII: pr9061076, Publication Type: Journal Article
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LAPSE:2023.5799
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https://doi.org/10.3390/pr9061076
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Feb 23, 2023
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