LAPSE:2023.5475
Published Article

LAPSE:2023.5475
Activated Carbon for Pharmaceutical Removal at Point-of-Entry
February 23, 2023
Abstract
Pharmaceuticals are an increasing problem in waterways due to improper disposal and lack of removal at wastewater treatment plants. Long-term exposure impacts to humans are unknown but have been observed in model organisms (i.e., fish), impacting reproduction, changing temperament, and causing organ damage. The application of activated carbon (AC) for organic contaminant removal is widespread and applied successfully for water treatment. The objective of this study is to rapidly adsorb ibuprofen using AC to determine the feasibility as a point-of-entry treatment option for removal of pharmaceuticals in the toilet. AC factors analyzed include type of AC raw material, adsorbent particle size, contact time, and competitive adsorption of ibuprofen and common toilet bowl cleaner components such as chlorine and methylene blue dye. A coconut-based AC with a high surface area adsorbed the highest quantity of ibuprofen. There was no significant impact to ibuprofen adsorption upon the introduction of other compounds to the solution, thus demonstrating rapid adsorption and the potential for application at the point-of-entry.
Pharmaceuticals are an increasing problem in waterways due to improper disposal and lack of removal at wastewater treatment plants. Long-term exposure impacts to humans are unknown but have been observed in model organisms (i.e., fish), impacting reproduction, changing temperament, and causing organ damage. The application of activated carbon (AC) for organic contaminant removal is widespread and applied successfully for water treatment. The objective of this study is to rapidly adsorb ibuprofen using AC to determine the feasibility as a point-of-entry treatment option for removal of pharmaceuticals in the toilet. AC factors analyzed include type of AC raw material, adsorbent particle size, contact time, and competitive adsorption of ibuprofen and common toilet bowl cleaner components such as chlorine and methylene blue dye. A coconut-based AC with a high surface area adsorbed the highest quantity of ibuprofen. There was no significant impact to ibuprofen adsorption upon the introduction of other compounds to the solution, thus demonstrating rapid adsorption and the potential for application at the point-of-entry.
Record ID
Keywords
activated carbon, adsorption capacity, adsorption kinetics, ibuprofen, raw materials, surface area, surface chemistry
Subject
Suggested Citation
Finn M, Giampietro G, Mazyck D, Rodriguez R. Activated Carbon for Pharmaceutical Removal at Point-of-Entry. (2023). LAPSE:2023.5475
Author Affiliations
Finn M: Department of Environmental Engineering Sciences, University of Florida, 314 AP Black Hall, Gainesville, FL 32611, USA
Giampietro G: Department of Environmental Engineering Sciences, University of Florida, 314 AP Black Hall, Gainesville, FL 32611, USA [ORCID]
Mazyck D: Department of Environmental Engineering Sciences, University of Florida, 314 AP Black Hall, Gainesville, FL 32611, USA
Rodriguez R: C12 Environmental Services, Gainesville, FL 32607, USA
Giampietro G: Department of Environmental Engineering Sciences, University of Florida, 314 AP Black Hall, Gainesville, FL 32611, USA [ORCID]
Mazyck D: Department of Environmental Engineering Sciences, University of Florida, 314 AP Black Hall, Gainesville, FL 32611, USA
Rodriguez R: C12 Environmental Services, Gainesville, FL 32607, USA
Journal Name
Processes
Volume
9
Issue
7
First Page
1091
Year
2021
Publication Date
2021-06-23
ISSN
2227-9717
Version Comments
Original Submission
Other Meta
PII: pr9071091, Publication Type: Journal Article
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LAPSE:2023.5475
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https://doi.org/10.3390/pr9071091
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[v1] (Original Submission)
Feb 23, 2023
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Feb 23, 2023
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