LAPSE:2023.36651
Published Article
LAPSE:2023.36651
Physical and Chemical Phenomena during the Production of Hydrogen in the Microwave Discharge Generated in Liquid Hydrocarbons with the Barbotage of Various Gases
September 20, 2023
The physical and chemical characteristics of the microwave discharge in petroleum solvent during hydrogen production processes involving Ar, He, and CO2 barbotage were studied. Gas chromatography, emission spectroscopy, high-speed photography, and shadow photography were used for diagnosis. The results demonstrated the dependence of hydrogen yield on the flow rates of Ar, He, and CO2. The maximum yield values of hydrogen were 791 mL/min and 811 mL/min, while the maximum energy efficiency reached 135.6 NL/kWh and 162.2 NL/kWh in Nefras with Ar and He barbotage, respectively. The dynamics of discharge structure and the rotational and vibrational temperatures of C2 molecules were studied.
Keywords
discharge in liquids, gas chromatography, hydrogen production, microwave discharge, optical emission spectroscopy, shadow photographs
Subject
Suggested Citation
Batukaev TS, Bilera IV, Krashevskaya GV, Lebedev YA. Physical and Chemical Phenomena during the Production of Hydrogen in the Microwave Discharge Generated in Liquid Hydrocarbons with the Barbotage of Various Gases. (2023). LAPSE:2023.36651
Author Affiliations
Batukaev TS: A.V. Topchiev Institute of Petrochemical Synthesis of the Russian Academy of Sciences (TIPS RAS), Leninsky Ave., 29, Moscow 119991, Russia [ORCID]
Bilera IV: A.V. Topchiev Institute of Petrochemical Synthesis of the Russian Academy of Sciences (TIPS RAS), Leninsky Ave., 29, Moscow 119991, Russia [ORCID]
Krashevskaya GV: A.V. Topchiev Institute of Petrochemical Synthesis of the Russian Academy of Sciences (TIPS RAS), Leninsky Ave., 29, Moscow 119991, Russia; Institute LAPLAZ, National Research Nuclear University MEPhI, Kashirskoe Shosse, 31, Moscow 115409, Russia
Lebedev YA: A.V. Topchiev Institute of Petrochemical Synthesis of the Russian Academy of Sciences (TIPS RAS), Leninsky Ave., 29, Moscow 119991, Russia [ORCID]
Journal Name
Processes
Volume
11
Issue
8
First Page
2292
Year
2023
Publication Date
2023-07-31
Published Version
ISSN
2227-9717
Version Comments
Original Submission
Other Meta
PII: pr11082292, Publication Type: Journal Article
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LAPSE:2023.36651
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doi:10.3390/pr11082292
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Sep 20, 2023
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CC BY 4.0
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[v1] (Original Submission)
Sep 20, 2023
 
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Sep 20, 2023
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Original Submitter
Calvin Tsay
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