LAPSE:2023.36247
Published Article
LAPSE:2023.36247
Transport Properties of Carbohydrates: Towards the Minimization Toxicological Risks of Cobalt and Chromium Ions
July 7, 2023
The influence of oligosaccharides (α-cyclodextrin, β-cyclodextrin and γ-cyclodextrin), and a polysaccharide, sodium hyaluronate (NaHy), on the diffusion of aqueous solutions of cobalt and chromium chlorides has been investigated. Cobalt and chromium are constituents of metal alloys for biomedical use, including dental prostheses. Thus, the release of these ions in the human body can lead to harmful biological effects. The interaction of metal ions with saccharides might have information on the role of mouthwashes in preventing these effects. This interaction has been assessed by measuring multicomponent intermolecular diffusion coefficients at 298.15 K. It has been found that β-cyclodextrin has the highest interaction towards cobalt and chromium ions. This work will contribute to unveiling the mechanisms responsible for transport by diffusion in aqueous solutions, and, therefore, mitigating the potential toxicity inherent to those metal ions.
Record ID
Keywords
chromium, Co-Cr alloys, cobalt, cyclodextrins, diffusion coefficient, hyaluronic acid, Taylor dispersion, transport properties
Subject
Suggested Citation
Trindade ACV, Fangaia SIG, Nicolau PMG, Messias A, Ribeiro ACF, Silva DSA, Valente AJM, Rodrigo MM, Esteso MA. Transport Properties of Carbohydrates: Towards the Minimization Toxicological Risks of Cobalt and Chromium Ions. (2023). LAPSE:2023.36247
Author Affiliations
Trindade ACV: Faculty of Medicine, CIROS, Institute of Implantology and Prosthodontics, University of Coimbra, Av. Bissaya Barreto, Blocos de Celas, 3000-075 Coimbra, Portugal
Fangaia SIG: Faculty of Medicine, CIROS, Institute of Implantology and Prosthodontics, University of Coimbra, Av. Bissaya Barreto, Blocos de Celas, 3000-075 Coimbra, Portugal; CQC-IMS, Department of Chemistry, University of Coimbra, 3004-535 Coimbra, Portugal [ORCID]
Nicolau PMG: Faculty of Medicine, CIROS, Institute of Implantology and Prosthodontics, University of Coimbra, Av. Bissaya Barreto, Blocos de Celas, 3000-075 Coimbra, Portugal; Center of Mechanical Engineering Materials and Processes (CEMMPRE), Departamento de Engenhar
Messias A: Faculty of Medicine, CIROS, Institute of Implantology and Prosthodontics, University of Coimbra, Av. Bissaya Barreto, Blocos de Celas, 3000-075 Coimbra, Portugal; Center of Mechanical Engineering Materials and Processes (CEMMPRE), Departamento de Engenhar [ORCID]
Ribeiro ACF: CQC-IMS, Department of Chemistry, University of Coimbra, 3004-535 Coimbra, Portugal [ORCID]
Silva DSA: CQC-IMS, Department of Chemistry, University of Coimbra, 3004-535 Coimbra, Portugal
Valente AJM: CQC-IMS, Department of Chemistry, University of Coimbra, 3004-535 Coimbra, Portugal [ORCID]
Rodrigo MM: U.D. Química Física, Universidad de Alcalá de Henares, 28805 Alcalá de Henares, Spain [ORCID]
Esteso MA: U.D. Química Física, Universidad de Alcalá de Henares, 28805 Alcalá de Henares, Spain; Faculty of Health Sciences, Universidad Católica de Ávila, Calle Los Canteros s/n, 05005 Ávila, Spain [ORCID]
Fangaia SIG: Faculty of Medicine, CIROS, Institute of Implantology and Prosthodontics, University of Coimbra, Av. Bissaya Barreto, Blocos de Celas, 3000-075 Coimbra, Portugal; CQC-IMS, Department of Chemistry, University of Coimbra, 3004-535 Coimbra, Portugal [ORCID]
Nicolau PMG: Faculty of Medicine, CIROS, Institute of Implantology and Prosthodontics, University of Coimbra, Av. Bissaya Barreto, Blocos de Celas, 3000-075 Coimbra, Portugal; Center of Mechanical Engineering Materials and Processes (CEMMPRE), Departamento de Engenhar
Messias A: Faculty of Medicine, CIROS, Institute of Implantology and Prosthodontics, University of Coimbra, Av. Bissaya Barreto, Blocos de Celas, 3000-075 Coimbra, Portugal; Center of Mechanical Engineering Materials and Processes (CEMMPRE), Departamento de Engenhar [ORCID]
Ribeiro ACF: CQC-IMS, Department of Chemistry, University of Coimbra, 3004-535 Coimbra, Portugal [ORCID]
Silva DSA: CQC-IMS, Department of Chemistry, University of Coimbra, 3004-535 Coimbra, Portugal
Valente AJM: CQC-IMS, Department of Chemistry, University of Coimbra, 3004-535 Coimbra, Portugal [ORCID]
Rodrigo MM: U.D. Química Física, Universidad de Alcalá de Henares, 28805 Alcalá de Henares, Spain [ORCID]
Esteso MA: U.D. Química Física, Universidad de Alcalá de Henares, 28805 Alcalá de Henares, Spain; Faculty of Health Sciences, Universidad Católica de Ávila, Calle Los Canteros s/n, 05005 Ávila, Spain [ORCID]
Journal Name
Processes
Volume
11
Issue
6
First Page
1701
Year
2023
Publication Date
2023-06-02
Published Version
ISSN
2227-9717
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Original Submission
Other Meta
PII: pr11061701, Publication Type: Journal Article
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Published Article
LAPSE:2023.36247
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External Link
doi:10.3390/pr11061701
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Version History
[v1] (Original Submission)
Jul 7, 2023
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Jul 7, 2023
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https://psecommunity.org/LAPSE:2023.36247
Original Submitter
Calvin Tsay
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