The research on pore structure and heterogeneity of shale reservoirs has always been a hotspot in the study of unconventional reservoir characteristics. China is a country dominated by continental shale. Compared with marine shale, continental shale has lower maturity and stronger reservoir heterogeneity. In this study, Sha-4 shale in the Liaohe Western Depression was selected for low-temperature nitrogen adsorption, scanning electron microscopy and other experiments revealing the pore structure and fractal characteristics of continental low mature organic-rich shale. The fractal dimension was calculated by the FHH model and the effects of TOC and mineral composition on pore structure and fractal characteristics were discussed. The results show that the Sha-4 shale in the study area is mainly mesoporous and the main pore types are inorganic pores with relatively large pore diameters, such as intergranular pores and inter-crystalline pores. The pore morphology is very complex, mainly narrow slit and flat pore, and the pore is often filled with organic matter. The fractal dimensions D1 range from 2.58 to 2.87 and D2 range from 2.18 to 2.55, and the pore structure shows obvious dual fractal characteristics. The pore structure and fractal characteristics of shale are mainly affected by TOC and quartz due to the low degree of the thermal evolution of shale and their effects are different from those of marine shale reservoirs. The increase in TOC reduces the heterogeneity of the shale reservoir. In addition, mineral particles with strong weathering resistance and stability such as quartz can protect the pore structure of shale, improve the pore structure and reduce the reservoir heterogeneity. This study can provide support for the study of low maturity continental shale reservoir heterogeneity in the Sha-4 member of the Liaohe Western Depression.