LAPSE:2023.29356
Published Article

LAPSE:2023.29356
Effects of MgO Nanoparticles on Thermo-Physical Properties of LiNO3-NaNO3-KNO3 for Thermal Energy Storage
April 13, 2023
Abstract
Molten salt LiNO3-NaNO3-KNO3 has been investigated as heat transfer and thermal storage media for its low melting point and good thermal performance. In this paper, nanofluids were synthesized by dispersing MgO nanoparticles into LiNO3-NaNO3-KNO3, and the effects of nanoparticles on thermal properties were studied with different sizes (20−100 nm) and mass percent concentrations (0.5−2.0 wt.%). The addition of nanoparticles had little effect on melting temperature, and led to a slight increase in enthalpy of fusion by 2.0−5.5%. Compared with base salt, the density of nanofluid increased a little by 0.22−1.15%. The scanning electron microscope (SEM) test implied that nubby and punctate microstructures were responsible for larger surface area and interfacial energy, which could lead to the improvement of specific heat capacity reaching 2.6−10.6%. The heat transfer characteristics remarkably increased with the addition of nanoparticles, and the enhancement of average thermal diffusivity and conductivity of salt with 1 wt.% nano-MgO could be 5.3−11.7% and 11.3−21.2%, respectively. Besides, the viscosities of nanofluids slightly increased for 3.3−8.1%. As a conclusion, nano-MgO was positively influential on the thermal properties of LiNO3-NaNO3-KNO3 base salt.
Molten salt LiNO3-NaNO3-KNO3 has been investigated as heat transfer and thermal storage media for its low melting point and good thermal performance. In this paper, nanofluids were synthesized by dispersing MgO nanoparticles into LiNO3-NaNO3-KNO3, and the effects of nanoparticles on thermal properties were studied with different sizes (20−100 nm) and mass percent concentrations (0.5−2.0 wt.%). The addition of nanoparticles had little effect on melting temperature, and led to a slight increase in enthalpy of fusion by 2.0−5.5%. Compared with base salt, the density of nanofluid increased a little by 0.22−1.15%. The scanning electron microscope (SEM) test implied that nubby and punctate microstructures were responsible for larger surface area and interfacial energy, which could lead to the improvement of specific heat capacity reaching 2.6−10.6%. The heat transfer characteristics remarkably increased with the addition of nanoparticles, and the enhancement of average thermal diffusivity and conductivity of salt with 1 wt.% nano-MgO could be 5.3−11.7% and 11.3−21.2%, respectively. Besides, the viscosities of nanofluids slightly increased for 3.3−8.1%. As a conclusion, nano-MgO was positively influential on the thermal properties of LiNO3-NaNO3-KNO3 base salt.
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Keywords
nanofluid, ternary nitrate salt, thermal energy storage, thermal properties
Subject
Suggested Citation
Lu J, Zhang Z, Wang W, Ding J. Effects of MgO Nanoparticles on Thermo-Physical Properties of LiNO3-NaNO3-KNO3 for Thermal Energy Storage. (2023). LAPSE:2023.29356
Author Affiliations
Lu J: School of Materials Science and Engineering, Sun Yat-Sen University, Guangzhou 510006, China [ORCID]
Zhang Z: School of Intelligent Systems Engineering, Sun Yat-Sen University, Guangzhou 510006, China [ORCID]
Wang W: School of Materials Science and Engineering, Sun Yat-Sen University, Guangzhou 510006, China
Ding J: School of Materials Science and Engineering, Sun Yat-Sen University, Guangzhou 510006, China
Zhang Z: School of Intelligent Systems Engineering, Sun Yat-Sen University, Guangzhou 510006, China [ORCID]
Wang W: School of Materials Science and Engineering, Sun Yat-Sen University, Guangzhou 510006, China
Ding J: School of Materials Science and Engineering, Sun Yat-Sen University, Guangzhou 510006, China
Journal Name
Energies
Volume
14
Issue
3
First Page
677
Year
2021
Publication Date
2021-01-28
ISSN
1996-1073
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PII: en14030677, Publication Type: Journal Article
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