LAPSE:2023.26780
Published Article
LAPSE:2023.26780
Identification of Phase Fraction−Temperature Curves from Heat Capacity Data for Numerical Modeling of Heat Transfer in Commercial Paraffin Waxes
Tilman Barz, Johannes Krämer, Johann Emhofer
April 3, 2023
The area-proportional baseline method generates phase fraction−temperature curves from heat capacity data of phase change materials. The curves describe the continuous conversion from solid to liquid over an extended temperature range. They are consistent with the apparent heat capacity and enthalpy modeling approach for the numerical solution of heat transfer problems. However, the curves are non-smooth, discrete signals. They are affected by noise in the heat capacity data and should not be used as input to continuous simulation models. This contribution proposes an alternative method based on spline approximation for the generation of consistent and smooth phase fraction−temperature, apparent heat capacity−temperature and enthalpy−temperature curves. Applications are presented for two commercial paraffins from Rubitherm GmbH considering heat capacity data from Differential Scanning Calorimetry and 3-layer-calorimetry. Apparent heat capacity models are validated for melting experiments using a compact heat exchanger. The best fitting models and the most efficient numerical solutions are obtained for heat capacity data from 3-layer-calorimetry using the proposed spline approximation method. Because of these promising results, the method is applied to melting data of all 44 Rubitherm paraffins. The computer code of the corresponding phase transition models is provided in the Supplementary Information.
Keywords
apparent heat capacity method, numerical modeling, paraffin heat capacity data, phase fraction–temperature curves, solid–liquid phase transition
Suggested Citation
Barz T, Krämer J, Emhofer J. Identification of Phase Fraction−Temperature Curves from Heat Capacity Data for Numerical Modeling of Heat Transfer in Commercial Paraffin Waxes. (2023). LAPSE:2023.26780
Author Affiliations
Barz T: AIT Austrian Institute of Technology GmbH, Giefingasse 2, 1210 Vienna, Austria [ORCID]
Krämer J: AIT Austrian Institute of Technology GmbH, Giefingasse 2, 1210 Vienna, Austria
Emhofer J: AIT Austrian Institute of Technology GmbH, Giefingasse 2, 1210 Vienna, Austria
Journal Name
Energies
Volume
13
Issue
19
Article Number
E5149
Year
2020
Publication Date
2020-10-02
Published Version
ISSN
1996-1073
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PII: en13195149, Publication Type: Journal Article
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doi:10.3390/en13195149
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