LAPSE:2023.26716
Published Article

LAPSE:2023.26716
Valorization of Cynara Cardunculus L. Oil as the Basis of a Biorefinery for Biodiesel and Biolubricant Production
April 3, 2023
Abstract
The production of sustainable and biodegradable products, for energy or material use, is becoming important for local economies. Thus, biorefineries can play an important role in sustainable development at regional levels and therefore the search for feedstocks with multiple uses is vital. The goal of this research was to assess the implementation of Cynara Cardunculus L. oil as the basis of a biorefinery for biodiesel and biolubricant production, proposing the main steps for this purpose. The chemical reaction selected for biodiesel and biolubricant production was transesterification, using methanol and other more complex alcohols. The optimization of each step was carried out, assessing the yield by gas chromatography. Once the optimum conditions were selected, the main characteristics of the biofuel or biolubricant were measured, paying attention to viscosity and oxidative stability. As a result, Cynara Cardunculus L. oil could be a suitable feedstock for a biorefinery, as long as some antioxidants are added in final products, especially to increase its oxidative stability in biodiesel (whose value was 1.35 h). Concerning biolubricant production, the yields were acceptable (exceeding 92%) and the products showed variable viscosity values (from 8.6 to 18.85 cSt), implying a desirable diversification of production depending on demand.
The production of sustainable and biodegradable products, for energy or material use, is becoming important for local economies. Thus, biorefineries can play an important role in sustainable development at regional levels and therefore the search for feedstocks with multiple uses is vital. The goal of this research was to assess the implementation of Cynara Cardunculus L. oil as the basis of a biorefinery for biodiesel and biolubricant production, proposing the main steps for this purpose. The chemical reaction selected for biodiesel and biolubricant production was transesterification, using methanol and other more complex alcohols. The optimization of each step was carried out, assessing the yield by gas chromatography. Once the optimum conditions were selected, the main characteristics of the biofuel or biolubricant were measured, paying attention to viscosity and oxidative stability. As a result, Cynara Cardunculus L. oil could be a suitable feedstock for a biorefinery, as long as some antioxidants are added in final products, especially to increase its oxidative stability in biodiesel (whose value was 1.35 h). Concerning biolubricant production, the yields were acceptable (exceeding 92%) and the products showed variable viscosity values (from 8.6 to 18.85 cSt), implying a desirable diversification of production depending on demand.
Record ID
Keywords
2-ethyl-1-hexanol, 2,2-dimethyl-1,3-propanediol, cardoon, oxidative stability, transesterification, viscosity, viscosity index
Subject
Suggested Citation
Nogales-Delgado S, Sánchez N, Encinar JM. Valorization of Cynara Cardunculus L. Oil as the Basis of a Biorefinery for Biodiesel and Biolubricant Production. (2023). LAPSE:2023.26716
Author Affiliations
Nogales-Delgado S: Department of Chemical Engineering and Physical-Chemistry, University of Extremadura, Avenida de Elvas s/n, 06006 Badajoz, Spain [ORCID]
Sánchez N: Department of Chemical Engineering and Physical-Chemistry, University of Extremadura, Avenida de Elvas s/n, 06006 Badajoz, Spain
Encinar JM: Department of Chemical Engineering and Physical-Chemistry, University of Extremadura, Avenida de Elvas s/n, 06006 Badajoz, Spain [ORCID]
Sánchez N: Department of Chemical Engineering and Physical-Chemistry, University of Extremadura, Avenida de Elvas s/n, 06006 Badajoz, Spain
Encinar JM: Department of Chemical Engineering and Physical-Chemistry, University of Extremadura, Avenida de Elvas s/n, 06006 Badajoz, Spain [ORCID]
Journal Name
Energies
Volume
13
Issue
19
Article Number
E5085
Year
2020
Publication Date
2020-09-29
ISSN
1996-1073
Version Comments
Original Submission
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PII: en13195085, Publication Type: Journal Article
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LAPSE:2023.26716
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https://doi.org/10.3390/en13195085
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