Abstract
Phase change materials (PCM) have been widely used in Thermal Energy Storage (TES) Systems. Considering the energy efficiency and the use of domestic hot water, the melting temperature range of phase change materials is considered to be optimal in the range of 50−60 °C. The most commonly used is sodium acetate trihydrate-based phase change material, which has the advantages of high latent heat and low price, but its high supercooling, low thermal conductivity, and phase separation affect its application. Therefore, this paper used sodium acetate trihydrate, disodium hydrogen phosphate dodecahydrate (DSP), and expanded graphite (EG) as raw materials to prepare composite phase change materials (CPCM) and used physical disturbance to further improve their properties. Firstly, their thermophysical properties were investigated by the step cooling curve method, differential scanning calorimetry (DSC), and x-ray diffraction (XRD). Secondly, in order to further evaluate the effect of physical disturbance on CPCM crystallization, further experimental studies were carried out by adjusting the rotor mass and rotational speed. The experimental results showed that when 1.5 wt.% DSP, 1.5 wt.% EG and physical perturbation work together, the CPCM phase transition temperature is 56.7 °C, and the latent heat is as high as 258.98 kJ/kg. At this time, its thermal conductivity increased from 0.62 w/m·k to 1.1625 w/m·k, and its subcooling degree decreased from above 20 °C to less than 0.5 °C, and no phase separation occurred. The greater the disturbance momentum (the greater the rotor mass or the greater the rotational speed), the shorter the induction time, which is more conducive to the crystallization of CPCM. The results obtained in this paper are instructive for the preparation of efficient new CPCMs.