LAPSE:2023.2101
Published Article

LAPSE:2023.2101
Investigation on Spectral Characteristics of Gliding Arc Plasma Assisted Ammonia Lean Combustion
February 21, 2023
Abstract
Ammonia as a non-carbon fuel is expected to play an important role in the future, but it is difficult to be effectively utilized at this stage due to its flame retardancy and other characteristics. Therefore, we propose to use gliding arc plasma combined with a swirl burner to enhance the combustion performance of ammonia. The electrical characteristics, electron density, gas rotational temperature and the distribution of key active species in the burner were studied via optical emission spectroscopy (OES). With the increase of equivalence ratio (EQR), the width of the Hα line decreases significantly, indicating that the electron density shows a downward trend, even as the gas rotational temperature shows an upward trend. When the equivalence ratio was 0.5, the gas rotational temperature increases by about 320 K compared with the pure air condition. During pure air discharge, there will still be obvious NO emission due to the plasma reaction, but with the addition of NH3, the NO content in the emission is significantly reduced. The light intensity of O atoms in the burner gradually decreases with the increase of the equivalence ratio, the light intensity of H atoms increases first and then decreases, and the light intensity of NH shows an upward trend. The reason may be that the plasma discharge effectively strengthens NH3(E)->NH2+H, NH2+H->NH+H2 and other reactions promote the initial reaction step of NH3 which thus effectively strengthens the NH3 combustion.
Ammonia as a non-carbon fuel is expected to play an important role in the future, but it is difficult to be effectively utilized at this stage due to its flame retardancy and other characteristics. Therefore, we propose to use gliding arc plasma combined with a swirl burner to enhance the combustion performance of ammonia. The electrical characteristics, electron density, gas rotational temperature and the distribution of key active species in the burner were studied via optical emission spectroscopy (OES). With the increase of equivalence ratio (EQR), the width of the Hα line decreases significantly, indicating that the electron density shows a downward trend, even as the gas rotational temperature shows an upward trend. When the equivalence ratio was 0.5, the gas rotational temperature increases by about 320 K compared with the pure air condition. During pure air discharge, there will still be obvious NO emission due to the plasma reaction, but with the addition of NH3, the NO content in the emission is significantly reduced. The light intensity of O atoms in the burner gradually decreases with the increase of the equivalence ratio, the light intensity of H atoms increases first and then decreases, and the light intensity of NH shows an upward trend. The reason may be that the plasma discharge effectively strengthens NH3(E)->NH2+H, NH2+H->NH+H2 and other reactions promote the initial reaction step of NH3 which thus effectively strengthens the NH3 combustion.
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Keywords
ammonia combustion, gliding arc, spectrum, swirl burner
Suggested Citation
Zhu X, Zhao Y, Zhai M, Lv P, Zhou W, Huang B. Investigation on Spectral Characteristics of Gliding Arc Plasma Assisted Ammonia Lean Combustion. (2023). LAPSE:2023.2101
Author Affiliations
Zhu X: School of Energy Science and Engineering, Harbin Institute of Technology, Harbin 150001, China
Zhao Y: School of Energy Science and Engineering, Harbin Institute of Technology, Harbin 150001, China
Zhai M: School of Energy Science and Engineering, Harbin Institute of Technology, Harbin 150001, China
Lv P: School of Energy Science and Engineering, Harbin Institute of Technology, Harbin 150001, China
Zhou W: School of Energy Science and Engineering, Harbin Institute of Technology, Harbin 150001, China
Huang B: Beijing International S&T Cooperation Base for Plasma Science and Energy Conversion, Institute of Electrical Engineering, Chinese Academy of Sciences, Beijing 100190, China [ORCID]
Zhao Y: School of Energy Science and Engineering, Harbin Institute of Technology, Harbin 150001, China
Zhai M: School of Energy Science and Engineering, Harbin Institute of Technology, Harbin 150001, China
Lv P: School of Energy Science and Engineering, Harbin Institute of Technology, Harbin 150001, China
Zhou W: School of Energy Science and Engineering, Harbin Institute of Technology, Harbin 150001, China
Huang B: Beijing International S&T Cooperation Base for Plasma Science and Energy Conversion, Institute of Electrical Engineering, Chinese Academy of Sciences, Beijing 100190, China [ORCID]
Journal Name
Processes
Volume
10
Issue
9
First Page
1750
Year
2022
Publication Date
2022-09-02
ISSN
2227-9717
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Original Submission
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PII: pr10091750, Publication Type: Journal Article
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LAPSE:2023.2101
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https://doi.org/10.3390/pr10091750
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