Abstract
Aqueous zinc-ion batteries are considered one of the promising large-scale energy storage devices of the future because of their high energy density, simple preparation process, efficient and safe discharge process, abundant zinc reserves, and low cost. However, the development of cathode materials with high capacity and stable structure has become one of the key elements to further development of aqueous zinc-ion batteries. Vanadium-based compounds, as one of the cathode materials for aqueous zinc-ion batteries, have various structures and high reversible capacities. Among them, vanadium-based sulfides have higher academic ability, better electrochemical activity, lower ion diffusion potential barrier, and a faster ion diffusion rate. As a result, vanadium-based sulfides have received extensive attention and research. In this review, we summarize the recent progress of vanadium-based sulfides applied in aqueous zinc-ion batteries, highlighting their effective strategies for designing optimized electrochemical performance and the underlying electrochemical mechanisms. Finally, an overview is provided of current vanadium-based sulfides and their prospects, and other perspectives on vanadium-based sulfide cathode materials for aqueous zinc-ion batteries are also discussed.