LAPSE:2023.20328v1
Published Article

LAPSE:2023.20328v1
Physicochemical Characterization and Thermal Behavior of Different Wood Species from the Amazon Biome
March 17, 2023
Abstract
The Brazilian Amazon is one of the main tropical wood-producing regions in the world, where exploration and industrial processing are among its main economic activities. Wood is characterized as a material consisting mainly of compounds with a high degree of polymerization and molecular weight such as cellulose, hemicellulose and lignin, in addition to other compounds such as ash and extractives. This chemical complexity of wood brings with it a wide possibility of chemical and thermochemical processing aiming at the production of bioproducts and biofuels. In this context, it is essential to know the physicochemical properties and thermal behavior of wood species from the Amazon biome to add value to the product, reducing waste and maximizing the species used. This work presents an investigation into the physicochemical and thermogravimetric characteristics of 21 species of wood from the Amazon, in addition to the determination of the higher heating value (HHV) of each one of them, focusing on the energy use of the biomass under analysis. The samples showed a high lignin content, varying between 26.8% and 33.9%, with a standard deviation of 1.7% and an average of 30.0%. The Trattinnickia sp. had the highest lignin content (33.86 ± 0.13%). The cellulose content varied from 31.3% to 55.9%, with a standard deviation of 7.3% and an average of 41.74%. The Ruizterania albiflora had the highest cellulose content (55.90 ± 1.20%). For the hemicellulose content, the variation ranged from 8.6% to 17.0%, with a standard deviation of 2.6% and an average of 12.38%. The samples that showed the highest HHVs were Ocotea sp. (18.588 ± 0.082 MJ kg−1) followed by Ferreiraa spectabilis (18.052 ± 0.157 MJ kg−1).
The Brazilian Amazon is one of the main tropical wood-producing regions in the world, where exploration and industrial processing are among its main economic activities. Wood is characterized as a material consisting mainly of compounds with a high degree of polymerization and molecular weight such as cellulose, hemicellulose and lignin, in addition to other compounds such as ash and extractives. This chemical complexity of wood brings with it a wide possibility of chemical and thermochemical processing aiming at the production of bioproducts and biofuels. In this context, it is essential to know the physicochemical properties and thermal behavior of wood species from the Amazon biome to add value to the product, reducing waste and maximizing the species used. This work presents an investigation into the physicochemical and thermogravimetric characteristics of 21 species of wood from the Amazon, in addition to the determination of the higher heating value (HHV) of each one of them, focusing on the energy use of the biomass under analysis. The samples showed a high lignin content, varying between 26.8% and 33.9%, with a standard deviation of 1.7% and an average of 30.0%. The Trattinnickia sp. had the highest lignin content (33.86 ± 0.13%). The cellulose content varied from 31.3% to 55.9%, with a standard deviation of 7.3% and an average of 41.74%. The Ruizterania albiflora had the highest cellulose content (55.90 ± 1.20%). For the hemicellulose content, the variation ranged from 8.6% to 17.0%, with a standard deviation of 2.6% and an average of 12.38%. The samples that showed the highest HHVs were Ocotea sp. (18.588 ± 0.082 MJ kg−1) followed by Ferreiraa spectabilis (18.052 ± 0.157 MJ kg−1).
Record ID
Keywords
Amazon biome, physicochemical composition, thermal behavior, wood species
Subject
Suggested Citation
Bimestre TA, Silva FS, Tuna CE, dos Santos JC, de Carvalho JA Jr, Canettieri EV. Physicochemical Characterization and Thermal Behavior of Different Wood Species from the Amazon Biome. (2023). LAPSE:2023.20328v1
Author Affiliations
Bimestre TA: Chemistry and Energy Department, School of Engineering, São Paulo State University UNESP, Guaratinguetá 12516-410, SP, Brazil [ORCID]
Silva FS: Chemistry and Energy Department, School of Engineering, São Paulo State University UNESP, Guaratinguetá 12516-410, SP, Brazil
Tuna CE: Chemistry and Energy Department, School of Engineering, São Paulo State University UNESP, Guaratinguetá 12516-410, SP, Brazil
dos Santos JC: Associated Laboratory of Combustion and Propulsion—LCP/INPE, Cachoeira Paulista 12630-970, SP, Brazil
de Carvalho JA Jr: Chemistry and Energy Department, School of Engineering, São Paulo State University UNESP, Guaratinguetá 12516-410, SP, Brazil
Canettieri EV: Chemistry and Energy Department, School of Engineering, São Paulo State University UNESP, Guaratinguetá 12516-410, SP, Brazil
Silva FS: Chemistry and Energy Department, School of Engineering, São Paulo State University UNESP, Guaratinguetá 12516-410, SP, Brazil
Tuna CE: Chemistry and Energy Department, School of Engineering, São Paulo State University UNESP, Guaratinguetá 12516-410, SP, Brazil
dos Santos JC: Associated Laboratory of Combustion and Propulsion—LCP/INPE, Cachoeira Paulista 12630-970, SP, Brazil
de Carvalho JA Jr: Chemistry and Energy Department, School of Engineering, São Paulo State University UNESP, Guaratinguetá 12516-410, SP, Brazil
Canettieri EV: Chemistry and Energy Department, School of Engineering, São Paulo State University UNESP, Guaratinguetá 12516-410, SP, Brazil
Journal Name
Energies
Volume
16
Issue
5
First Page
2257
Year
2023
Publication Date
2023-02-27
ISSN
1996-1073
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Original Submission
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PII: en16052257, Publication Type: Journal Article
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