Abstract
CO2 reutilization processes contribute to the mitigation of CO2 as a potent greenhouse gas (GHG) through reusing and converting it into economically valuable chemical products including methanol, dimethyl ether, and methane. Solar thermochemical conversion and photochemical and electrochemical CO2 reduction processes are emerging technologies in which solar energy is utilized to provide the energy required for the endothermic dissociation of CO2. Owing to the surface-dependent nature of these technologies, their performance is significantly reliant on the solid reactant/catalyst accessible surface area. Solid porous structures either entirely made from the catalyst or used as a support for coating the catalyst/solid reactants can increase the number of active reaction sites and, thus, the kinetics of CO2 reutilization reactions. This paper reviews the principles and application of porous materials for CO2 reutilization pathways in solar thermochemical, photochemical, and electrochemical reduction technologies. Then, the state of the development of each technology is critically reviewed and evaluated with the focus on the use of porous materials. Finally, the research needs and challenges are presented to further advance the implementation of porous materials in the CO2 reutilization processes and the commercialization of the aforementioned technologies.