LAPSE:2023.14920
Published Article

LAPSE:2023.14920
Formation of an Ammonium Nitrate Fuel Oil Similar Type of Explosive under Fire Conditions: Materials Based on Selected Polymers (PUR)
March 2, 2023
Abstract
Polyurethanes (PURs) are a group of polymers with the most versatile properties and the broadest spectrum of application. Their name comes from the urethane group. PURs were introduced to the market on a large-scale basis by Bayer in 1942, in the form of Perlon U and Igamid U fibers produced by gradual polyaddition of diisocyanates and polyols. The development of PURs-production technology and the multitude of applications resulted in their widespread use. This group is so extensive that polyurethanes alone accounted for about 6% of the global production of polymers (2019)—most of them in the form of foam. Therefore, polyurethane can be found in a huge number of products—some of them stored in the vicinity of ammonium nitrate (AN). In the previous two articles, we showed that polymers and AN—stored within the same building—in fire conditions may, under certain circumstances, spontaneously transform into a material of explosive properties. The aim of this article is to check whether PUR, when in contact with AN, creates additional hazards, similarly to the previously tested polymers.
Polyurethanes (PURs) are a group of polymers with the most versatile properties and the broadest spectrum of application. Their name comes from the urethane group. PURs were introduced to the market on a large-scale basis by Bayer in 1942, in the form of Perlon U and Igamid U fibers produced by gradual polyaddition of diisocyanates and polyols. The development of PURs-production technology and the multitude of applications resulted in their widespread use. This group is so extensive that polyurethanes alone accounted for about 6% of the global production of polymers (2019)—most of them in the form of foam. Therefore, polyurethane can be found in a huge number of products—some of them stored in the vicinity of ammonium nitrate (AN). In the previous two articles, we showed that polymers and AN—stored within the same building—in fire conditions may, under certain circumstances, spontaneously transform into a material of explosive properties. The aim of this article is to check whether PUR, when in contact with AN, creates additional hazards, similarly to the previously tested polymers.
Record ID
Keywords
ammonium nitrate, ANFO, polyurethane foam, self-acting formation of explosives, sponge
Subject
Suggested Citation
Wolny P, Tuśnio N, Lewandowski A, Mikołajczyk F, Kuberski S. Formation of an Ammonium Nitrate Fuel Oil Similar Type of Explosive under Fire Conditions: Materials Based on Selected Polymers (PUR). (2023). LAPSE:2023.14920
Author Affiliations
Wolny P: Faculty of Process and Environmental Engineering, Lodz University of Technology, 90-924 Lodz, Poland [ORCID]
Tuśnio N: Faculty of Safety Engineering and Civil Protection, The Main School of Fire Service, 01-629 Warsaw, Poland [ORCID]
Lewandowski A: Faculty of Process and Environmental Engineering, Lodz University of Technology, 90-924 Lodz, Poland
Mikołajczyk F: Faculty of Process and Environmental Engineering, Lodz University of Technology, 90-924 Lodz, Poland
Kuberski S: Faculty of Process and Environmental Engineering, Lodz University of Technology, 90-924 Lodz, Poland
Tuśnio N: Faculty of Safety Engineering and Civil Protection, The Main School of Fire Service, 01-629 Warsaw, Poland [ORCID]
Lewandowski A: Faculty of Process and Environmental Engineering, Lodz University of Technology, 90-924 Lodz, Poland
Mikołajczyk F: Faculty of Process and Environmental Engineering, Lodz University of Technology, 90-924 Lodz, Poland
Kuberski S: Faculty of Process and Environmental Engineering, Lodz University of Technology, 90-924 Lodz, Poland
Journal Name
Energies
Volume
15
Issue
5
First Page
1674
Year
2022
Publication Date
2022-02-23
ISSN
1996-1073
Version Comments
Original Submission
Other Meta
PII: en15051674, Publication Type: Journal Article
Record Map
Published Article

LAPSE:2023.14920
This Record
External Link

https://doi.org/10.3390/en15051674
Publisher Version
Download
Meta
Record Statistics
Record Views
277
Version History
[v1] (Original Submission)
Mar 2, 2023
Verified by curator on
Mar 2, 2023
This Version Number
v1
Citations
Most Recent
This Version
URL Here
https://psecommunity.org/LAPSE:2023.14920
Record Owner
Auto Uploader for LAPSE
Links to Related Works
(0.09 seconds)
[0.09 s]
