Abstract
This paper presents a method for use in estimating the state of charge (SOC) of lithium-ion batteries which is based on an electrochemical impedance equivalent circuit model with a controlled source. Considering that the open-circuit voltage of a battery varies with the SOC, an equivalent circuit model with a controlled source is proposed which the voltage source and current source interact with each other. On this basis, the radial basis function (RBF) neural network is adopted to estimate the uncertainty in the battery model online, and a non-linear observer based on the radial basis function of the RBF neural network is designed to estimate the SOC of batteries. It is proved that the SOC estimation error is ultimately bounded by Lyapunov stability analysis, and the error bound can be arbitrarily small. The high accuracy and validity of the non-linear observer based on the RBF neural network in SOC estimation are verified with experimental simulation results. The SOC estimation results of the extended Kalman filter (EKF) are compared with the proposed method. It improves convergence speed and accuracy.