LAPSE:2023.12975
Published Article

LAPSE:2023.12975
Effect of In-Pore Wettability on Mass Transfer Performance of Fuel Cell Gas Diffusion Layer
February 28, 2023
Abstract
The gas diffusion layer (GDL), as the main mass transfer carrier in a hydrogen fuel cell, transports fuel and discharges water, the only by-product of the electrochemical reaction. The dispersion process of water in the pore will hinder the diffusion of gas, thus reducing the concentration of fuel gas at the catalytic site, resulting in the decrease of the electrochemical reaction rate. In this paper, the effect of wettability in the GDL hole on the water transport process is studied. When the pore wall is hydrophilic, the liquid phase is affected by the gas phase eddy current velocity field, and the particles at the center advance to the edge, forming a liquid phase interface with a thin center and thick edge. With the increase of the wall contact angle, the curvature of the three-phase interface increases, the wall adhesion decreases, and the liquid phase is more likely to be discharged. When the contact angle is 130°, the liquid phase almost does not shift in the hole with a radius of 5 μm. With the increase of the radius or inlet pressure difference, the liquid phase is discharged gradually, and the discharge rate of the liquid phase is only related to the wettability of the wall.
The gas diffusion layer (GDL), as the main mass transfer carrier in a hydrogen fuel cell, transports fuel and discharges water, the only by-product of the electrochemical reaction. The dispersion process of water in the pore will hinder the diffusion of gas, thus reducing the concentration of fuel gas at the catalytic site, resulting in the decrease of the electrochemical reaction rate. In this paper, the effect of wettability in the GDL hole on the water transport process is studied. When the pore wall is hydrophilic, the liquid phase is affected by the gas phase eddy current velocity field, and the particles at the center advance to the edge, forming a liquid phase interface with a thin center and thick edge. With the increase of the wall contact angle, the curvature of the three-phase interface increases, the wall adhesion decreases, and the liquid phase is more likely to be discharged. When the contact angle is 130°, the liquid phase almost does not shift in the hole with a radius of 5 μm. With the increase of the radius or inlet pressure difference, the liquid phase is discharged gradually, and the discharge rate of the liquid phase is only related to the wettability of the wall.
Record ID
Keywords
fuel cell, mass transfer, wettability
Subject
Suggested Citation
Niu Q, Li M, Lai L. Effect of In-Pore Wettability on Mass Transfer Performance of Fuel Cell Gas Diffusion Layer. (2023). LAPSE:2023.12975
Author Affiliations
Niu Q: School of Mechanical Engineering and Automation, Fuzhou University, Fuzhou 350002, China; School of Information and Electromechanical Engineering, Ningde Normal University, Ningde 350900, China
Li M: School of Mechanical Engineering and Automation, Fuzhou University, Fuzhou 350002, China [ORCID]
Lai L: School of Information and Electromechanical Engineering, Ningde Normal University, Ningde 350900, China
Li M: School of Mechanical Engineering and Automation, Fuzhou University, Fuzhou 350002, China [ORCID]
Lai L: School of Information and Electromechanical Engineering, Ningde Normal University, Ningde 350900, China
Journal Name
Energies
Volume
15
Issue
10
First Page
3474
Year
2022
Publication Date
2022-05-10
ISSN
1996-1073
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Original Submission
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PII: en15103474, Publication Type: Journal Article
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LAPSE:2023.12975
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https://doi.org/10.3390/en15103474
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Feb 28, 2023
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