LAPSE:2020.1185
Published Article
LAPSE:2020.1185
Evolution of Specific Heat Capacity with Temperature for Typical Supports Used for Heterogeneous Catalysts
Xiaojia Lu, Yanjun Wang, Lionel Estel, Narendra Kumar, Henrik Grénman, Sébastien Leveneur
December 17, 2020
Heterogeneous catalysts are widely used in the chemical industry. Compared with homogeneous catalysts, they can be easily separated from the reaction mixture. To design and optimize an efficient and safe chemical process one needs to calculate the energy balance, implying the need for knowledge of the catalyst’s specific heat capacity. Such values are typically not reported in the literature, especially not the temperature dependence. To fill this gap in knowledge, the specific heat capacities of commonly utilized heterogeneous catalytic supports were measured at different temperatures in a Tian−Calvet calorimeter. The following materials were tested: activated carbon, aluminum oxide, amberlite IR120 (H-form), H-Beta-25, H-Beta-38, H-Y-60, H-ZSM-5-23, H-ZSM-5-280, silicon dioxide, titanium dioxide, and zeolite 13X. Polynomial expressions were successfully fitted to the experimental data.
Keywords
heterogeneous catalytic material, micro-calorimeter C80, specific heat capacity
Subject
Suggested Citation
Lu X, Wang Y, Estel L, Kumar N, Grénman H, Leveneur S. Evolution of Specific Heat Capacity with Temperature for Typical Supports Used for Heterogeneous Catalysts. (2020). LAPSE:2020.1185
Author Affiliations
Lu X: Normandie Univ, INSA Rouen, UNIROUEN, LSPC, EA4704, 76000 Rouen, France; Laboratory of Industrial Chemistry and Reaction Engineering, Johan Gadolin Process Chemistry Centre, Åbo Akademi University, Biskopsgatan 8, FI-20500 Åbo/Turku, Finland
Wang Y: Normandie Univ, INSA Rouen, UNIROUEN, LSPC, EA4704, 76000 Rouen, France
Estel L: Normandie Univ, INSA Rouen, UNIROUEN, LSPC, EA4704, 76000 Rouen, France [ORCID]
Kumar N: Laboratory of Industrial Chemistry and Reaction Engineering, Johan Gadolin Process Chemistry Centre, Åbo Akademi University, Biskopsgatan 8, FI-20500 Åbo/Turku, Finland
Grénman H: Laboratory of Industrial Chemistry and Reaction Engineering, Johan Gadolin Process Chemistry Centre, Åbo Akademi University, Biskopsgatan 8, FI-20500 Åbo/Turku, Finland
Leveneur S: Normandie Univ, INSA Rouen, UNIROUEN, LSPC, EA4704, 76000 Rouen, France [ORCID]
Journal Name
Processes
Volume
8
Issue
8
Article Number
E911
Year
2020
Publication Date
2020-08-01
Published Version
ISSN
2227-9717
Version Comments
Original Submission
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PII: pr8080911, Publication Type: Journal Article
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LAPSE:2020.1185
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doi:10.3390/pr8080911
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Dec 17, 2020
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CC BY 4.0
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Dec 17, 2020
 
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Dec 17, 2020
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Calvin Tsay
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