LAPSE:2018.0344
Published Article
LAPSE:2018.0344
Synthesis and Characterization of Ampholytic Flocculant CPCTS-g-P (CTA-DMDAAC) and Its Flocculation Properties for Microcystis Aeruginosa Removal
July 31, 2018
The ampholytic chitosan based flocculant carboxylated chitosan graft-(3-chloro-2-hydroxypropyl) trimethylammonium chloride-dimethyl diallyl ammonium chloride (CPCTS-g-P (CTA-DMDAAC)) was synthesized by photo polymerization using carboxylated chitosan (CPCTS), 3-chloro-2-chloropropyltrimethylammonium chloride (CTA) and dimethyldiallylammonium chloride (DMDAAC) as the cationic co-monomers. The effects of monomer concentration, the ratio of CPCTS and cationic monomers, cationic degree, initiator time, photoinitiator concentration, and pH value on the properties of CPCTS-g-P (CTA-DMDAAC) were studied. The microcystis aeruginosa that was cultured in laboratory was used for CPCTS-g-P (CTA-DMDAAC) flocculation tests. The effects of CPCTS-g-P (CTA-DMDAAC) dosage, pH value and G value on flocculation performance were investigated. The maximum removal rate of chlorophyll-a (Chl-a) and chemical oxygen demand (COD) that were obtained by CPCTS-g-P (CTA-DMDAAC) were 98.8% and 96.5% under the conditions of dosage 4 mg/L, pH 7 and G value 200 s−1, respectively. The flocculation experiments showed that chitosan-based flocculant CPCTS-g-P (CTA-DMDAAC) had better flocculation performance than commercially available flocculants cationic polyacrylamide (CPAM), Polyferric Sulfate (PFS), and polymeric aluminium (PAC).
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Keywords
alga removal, chitosan-based flocculant, flocculation properties, graft copolymerization, photopolymerization
Subject
Suggested Citation
Chen L, Liu C, Sun Y, Sun W, Xu Y, Zheng H. Synthesis and Characterization of Ampholytic Flocculant CPCTS-g-P (CTA-DMDAAC) and Its Flocculation Properties for Microcystis Aeruginosa Removal. (2018). LAPSE:2018.0344
Author Affiliations
Chen L: Jiangsu Key Laboratory of Industrial Water-Conservation & Emission Reduction, College of Environment, Nanjing Tech University, Nanjing 211800, China
Liu C: College of Urban Construction, Nanjing Tech University, Nanjing 211800, China
Sun Y: College of Urban Construction, Nanjing Tech University, Nanjing 211800, China
Sun W: College of Urban Construction, Nanjing Tech University, Nanjing 211800, China
Xu Y: Jiangsu Key Laboratory of Industrial Water-Conservation & Emission Reduction, College of Environment, Nanjing Tech University, Nanjing 211800, China
Zheng H: Key laboratory of the Three Gorges Reservoir Region’s Eco-Environment, State Ministry of Education, Chongqing University, Chongqing 400045, China
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Liu C: College of Urban Construction, Nanjing Tech University, Nanjing 211800, China
Sun Y: College of Urban Construction, Nanjing Tech University, Nanjing 211800, China
Sun W: College of Urban Construction, Nanjing Tech University, Nanjing 211800, China
Xu Y: Jiangsu Key Laboratory of Industrial Water-Conservation & Emission Reduction, College of Environment, Nanjing Tech University, Nanjing 211800, China
Zheng H: Key laboratory of the Three Gorges Reservoir Region’s Eco-Environment, State Ministry of Education, Chongqing University, Chongqing 400045, China
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Journal Name
Processes
Volume
6
Issue
5
Article Number
E54
Year
2018
Publication Date
2018-05-11
Published Version
ISSN
2227-9717
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Original Submission
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PII: pr6050054, Publication Type: Journal Article
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LAPSE:2018.0344
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doi:10.3390/pr6050054
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[v1] (Original Submission)
Jul 31, 2018
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