LAPSE:2021.0652
Published Article
LAPSE:2021.0652
Promising Catalytic Systems for CO2 Hydrogenation into CH4: A Review of Recent Studies
M. Carmen Bacariza, Daniela Spataru, Leila Karam, José M. Lopes, Carlos Henriques
July 29, 2021
The increasing utilization of renewable sources for electricity production turns CO2 methanation into a key process in the future energy context, as this reaction allows storing the temporary renewable electricity surplus in the natural gas network (Power-to-Gas). This kind of chemical reaction requires the use of a catalyst and thus it has gained the attention of many researchers thriving to achieve active, selective and stable materials in a remarkable number of studies. The existing papers published in literature in the past few years about CO2 methanation tackled the catalysts composition and their related performances and mechanisms, which served as a basis for researchers to further extend their in-depth investigations in the reported systems. In summary, the focus was mainly in the enhancement of the synthesized materials that involved the active metal phase (i.e., boosting its dispersion), the different types of solid supports, and the frequent addition of a second metal oxide (usually behaving as a promoter). The current manuscript aims in recapping a huge number of trials and is divided based on the support nature: SiO2, Al2O3, CeO2, ZrO2, MgO, hydrotalcites, carbons and zeolites, and proposes the main properties to be kept for obtaining highly efficient carbon dioxide methanation catalysts.
Keywords
active metals, CO2 conversion, CO2 methanation, heterogeneous catalysts, Power-to-Gas, reaction mechanism, Sabatier reaction, supports
Suggested Citation
Bacariza MC, Spataru D, Karam L, Lopes JM, Henriques C. Promising Catalytic Systems for CO2 Hydrogenation into CH4: A Review of Recent Studies. (2021). LAPSE:2021.0652
Author Affiliations
Bacariza MC: c5Lab—Sustainable Construction Materials Association, Edifício Central Park, Rua Central Park 6, 2795-242 Linda-a-Velha, Portugal; Centro de Química Estrutural, Instituto Superior Técnico, Universidade de Lisboa, Av Rovisco Pais, 1049-001 Lisboa, Por [ORCID]
Spataru D: c5Lab—Sustainable Construction Materials Association, Edifício Central Park, Rua Central Park 6, 2795-242 Linda-a-Velha, Portugal; Centro de Química Estrutural, Instituto Superior Técnico, Universidade de Lisboa, Av Rovisco Pais, 1049-001 Lisboa, Por
Karam L: Sorbonne Université, Campus Pierre et Marie Curie, Laboratoire de Réactivité de Surface, UMR CNRS 7197, 4 Place Jussieu, F-75005 Paris, France; Department of Chemical Engineering, Faculty of Engineering, University of Balamand, P.O. Box 33 Amioun El Ko
Lopes JM: Centro de Química Estrutural and Departamento de Engenharia Química, Instituto Superior Técnico, Universidade de Lisboa, Av Rovisco Pais, 1049-001 Lisboa, Portugal [ORCID]
Henriques C: Centro de Química Estrutural and Departamento de Engenharia Química, Instituto Superior Técnico, Universidade de Lisboa, Av Rovisco Pais, 1049-001 Lisboa, Portugal
Journal Name
Processes
Volume
8
Issue
12
Article Number
E1646
Year
2020
Publication Date
2020-12-13
Published Version
ISSN
2227-9717
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Original Submission
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PII: pr8121646, Publication Type: Review
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LAPSE:2021.0652
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doi:10.3390/pr8121646
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Jul 29, 2021
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Jul 29, 2021
 
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