This article presents the results of comparative studies on streamer propagation and breakdown in a point-insulating plate electrode system in mineral oil and two ester liquids. The studies were performed for a 10-mm gap and a positive standard lightning impulse. The work was focused on the comparison of light waveforms registered using the photomultiplier technique. The results indicated that both esters demonstrate a lower resistance against the appearance of fast energetic streamers than mineral oil. The reason for such a conclusion is that the number of lightning impulses supplied to the electrode system for which the above-mentioned fast streamers appeared at a given voltage level was always higher in the case of ester liquids than mineral oil. In terms of breakdown, the esters tested were assessed as more susceptible to the appearance of breakdown in the investigated electrode system. The number of breakdowns recorded in the case of esters was always greater than the corresponding number of breakdowns in mineral oil. This may be supposed on the basis of the obtained results that imply that, in both synthetic and natural ester, the formed breakdown channel, which bridged the gap through the surface of pressboard plate, is characterized by higher energy than in the case of mineral oil.