LAPSE:2023.0899
Published Article
LAPSE:2023.0899
Incorporated Metal−Organic Framework Hybrid Materials for Gas Separation, Catalysis and Wastewater Treatment
Zahirah Jaffar, Normawati M. Yunus, Maizatul Shima Shaharun, Muhammad Faizadmesa Allim, Asyraf Hanim Ab Rahim
February 21, 2023
The special features of metal−organic frameworks (MOFs), namely, tunable porosity, exceptional structure, high surface area and high adsorption capability enable them to be widely studied in many applications including carbon capture and storage (CCS), biomedical engineering, catalysis and pollutant treatment. Despite these remarkable properties, MOFs are known to be moisture-sensitive, hardly recyclable and expensive in fabrication cost which limits their breakthrough performance in more efficient uses. Recently, extensive studies have been devoted to counter those shortcomings by embedding MOFs with support materials using various series of synthetic designs to yield incorporated MOF hybrid materials to counter their limitations. In view of this interest, this review summarizes the latest developments of incorporated MOFs with various materials, namely, ionic liquids (ILs), membranes and metal species. Pre-synthetic and post-synthetic synthesis methods are also discussed. This review also aims to highlight the factors associated with incorporated MOF performance such as materials selection and mass ratio which could have favorable effects in gas separation, catalysis and wastewater treatment applications. The data indicate that incorporated MOF hybrid materials exhibit exceptional properties including excellent robustness and stability. Correspondingly, in comparison to pristine MOFs, incorporated MOF hybrid materials significantly improve, among others, the gas selectivity, catalyst activity and dye removal efficiency in gas separation, catalysis and wastewater treatment, respectively. In addition, the challenge related to the utilization of this newly incorporated material is mentioned.
Keywords
Catalysis, gas separation, hybrid, incorporated, MOF, Wastewater
Subject
Suggested Citation
Jaffar Z, Yunus NM, Shaharun MS, Allim MF, Rahim AHA. Incorporated Metal−Organic Framework Hybrid Materials for Gas Separation, Catalysis and Wastewater Treatment. (2023). LAPSE:2023.0899
Author Affiliations
Jaffar Z: Institute of Contaminant Management, Centre for Research in Ionic Liquid (CORIL), Department of Fundamental and Applied Sciences, Universiti Teknologi PETRONAS, Seri Iskandar 32610, Malaysia
Yunus NM: Institute of Contaminant Management, Centre for Research in Ionic Liquid (CORIL), Department of Fundamental and Applied Sciences, Universiti Teknologi PETRONAS, Seri Iskandar 32610, Malaysia [ORCID]
Shaharun MS: Institute of Contaminant Management, Centre for Contaminant Control & Utilization (CenCoU)), Department of Fundamental and Applied Sciences, Universiti Teknologi PETRONAS, Seri Iskandar 32610, Malaysia [ORCID]
Allim MF: Department of Fundamental and Applied Sciences, Universiti Teknologi PETRONAS, Seri Iskandar 32610, Malaysia
Rahim AHA: Institute of Contaminant Management, Centre for Research in Ionic Liquid (CORIL), Department of Fundamental and Applied Sciences, Universiti Teknologi PETRONAS, Seri Iskandar 32610, Malaysia
Journal Name
Processes
Volume
10
Issue
11
First Page
2368
Year
2022
Publication Date
2022-11-11
Published Version
ISSN
2227-9717
Version Comments
Original Submission
Other Meta
PII: pr10112368, Publication Type: Review
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LAPSE:2023.0899
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doi:10.3390/pr10112368
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Feb 21, 2023
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CC BY 4.0
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Feb 21, 2023
 
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