LAPSE:2021.0266
Published Article
LAPSE:2021.0266
Phosphorus-Doped Carbon Supported Vanadium Phosphate Oxides for Catalytic Oxidation of 5-Hydroxymethylfurfural to 2,5-Diformylfuran
Sha Wen, Kai Liu, Yi Tian, Yanping Xiang, Xianxiang Liu, Dulin Yin
April 29, 2021
2,5-diformylfuran (DFF) is an important downstream product obtained by selective oxidation of the biomass-based platform compound 5-hydroxymethylfurfural (HMF). In this study, a phosphorus-doped carbon (P-C) supported vanadium phosphate oxide (VPO) catalyst was successfully prepared and showed remarkably high catalytic activity in the selective oxidation of HMF to produce DFF with air as an oxidant. The effects of the reaction temperature, reaction time, solvent, catalyst amount, and VPO loading amount were investigated. The results showed that an HMF conversion rate of 100% and a DFF yield of 97.0% were obtained under suitable conditions, and DMSO was found to be the most suitable solvent under an air atmosphere.
Keywords
2,5-diformylfuran, 5-hydroxymethylfurfural, Catalysis, selective oxidation, vanadium phosphate oxides
Suggested Citation
Wen S, Liu K, Tian Y, Xiang Y, Liu X, Yin D. Phosphorus-Doped Carbon Supported Vanadium Phosphate Oxides for Catalytic Oxidation of 5-Hydroxymethylfurfural to 2,5-Diformylfuran. (2021). LAPSE:2021.0266
Author Affiliations
Wen S: National & Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources, Key Laboratory of the Assembly and Application of Organic Functional Molecules of Hunan Province, College of Chemistry and Chemical Engineeri
Liu K: National & Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources, Key Laboratory of the Assembly and Application of Organic Functional Molecules of Hunan Province, College of Chemistry and Chemical Engineeri
Tian Y: National & Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources, Key Laboratory of the Assembly and Application of Organic Functional Molecules of Hunan Province, College of Chemistry and Chemical Engineeri
Xiang Y: National & Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources, Key Laboratory of the Assembly and Application of Organic Functional Molecules of Hunan Province, College of Chemistry and Chemical Engineeri
Liu X: National & Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources, Key Laboratory of the Assembly and Application of Organic Functional Molecules of Hunan Province, College of Chemistry and Chemical Engineeri
Yin D: National & Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources, Key Laboratory of the Assembly and Application of Organic Functional Molecules of Hunan Province, College of Chemistry and Chemical Engineeri
Journal Name
Processes
Volume
8
Issue
10
Article Number
E1273
Year
2020
Publication Date
2020-10-11
Published Version
ISSN
2227-9717
Version Comments
Original Submission
Other Meta
PII: pr8101273, Publication Type: Journal Article
Record Map
Published Article

LAPSE:2021.0266
This Record
External Link

doi:10.3390/pr8101273
Publisher Version
Download
Files
[Download 1v1.pdf] (1.8 MB)
Apr 29, 2021
Main Article
License
CC BY 4.0
Meta
Record Statistics
Record Views
343
Version History
[v1] (Original Submission)
Apr 29, 2021
 
Verified by curator on
Apr 29, 2021
This Version Number
v1
Citations
Most Recent
This Version
URL Here
https://psecommunity.org/LAPSE:2021.0266
 
Original Submitter
Calvin Tsay
Links to Related Works
Directly Related to This Work
Publisher Version