The competitiveness of companies in emerging countries implies many European countries must transform their production systems to be more efficient. Indeed, the new context created by the COVID-19 pandemic increases the necessity of digital transformation and focuses attention on its limited uptake by manufacturing companies. In France, the Industry 4.0 concepts are already implemented in large companies. Despite the demonstration and validation of their benefits, SMEs are reluctant to move towards implementation. This problem of SME performance improvement increases with the current geopolitical situation in Europe (raw materials and gasoil cost). It is thus urgent and paramount to find a better solution for encouraging SMEs in their transformation. Taking note of the brakes on uptake of Industry 4.0 concepts in SMEs, the objectives of this paper are to find levers to accelerate implementation of Industry 4.0 concepts in SMEs, through the development and the deployment of a sustainabl... [more]

Based on the empirical literature of the payments for environmental services (PES) projects for the environmental improvement and poverty reduction, this paper uses a meta-regression analysis method to study whether PES can achieve the effects of improving environmental quality and reducing poverty levels. For the meta-regression analysis, the literature was mainly searched by the Web of Science core journal database. The explanatory variables of meta-regression analysis are the hypothesis and related features of the models in the original literature by generally taking the binary dummy variables or categorical variables. The dependent variables used in this paper are environmental improvement and poverty reduction. The results show that PES projects based on private ownership rights are more conducive to poverty reduction and environmental improvement. If the country is a buyer of a PES project, it is more likely to achieve the effects of environmental enhancement and poverty alleviat... [more]

Extending the use of a component without compromising its intended functionality is the neatest approach to enhance sustainability. From this perspective, limiting the working life of a cutting tool based merely on the blunting of its cutting edge to a specific value is highly questionable. The very question that serves as the motivation for this work is, “why should tool life criterion be based on the shape of the tool when all that matters for business is the quality of the part being machined?”. This work puts forward a tool life criterion based on the surface quality of the machined part. The proof of the concept is provided by a series of face-turning experiments performed on a commonly used alloy steel using the following cutting inserts in dry conditions: (1) uncoated carbide; (2) coated carbide; and (3) cubic boron nitride (CBN). It is found that different combinations of tooling and cutting parameters lead to entirely different values of surface roughness at the same level of... [more]

Borehole instability problems are commonly encountered while drilling highly deviated and horizontal shale gas wells within the shale formations associated with high-dip bedding planes. An integrated rock mechanical study is described in this paper to evaluate the risk of the borehole instability problems in this area. First, a set of uniaxial compressive tests are carried out to measure the strength of the bedding shales on cores with different angles between the load direction and the bedding planes. A critical strength criterion is then proposed based on the test results. Next, the stress state of the borehole with arbitrary inclination and azimuth is determined through coordinate transformations. Finally, through combining the strength criterion and the stress state of the borehole, the risk of borehole instability is investigated for deviated and horizontal wells in shale formations with different bedding dips (0−90°) and dip directions (45° and 90° to the direction of minimum hor... [more]

Protective coal seam mining can not only effectively prevent coal and gas outbursts in mines, but also provide stress unloading space for the protected coal seam. The coal body in the protected coal seam might undergo deformation, internal damage and structural damage, which changes its gas seepage characteristics. This study aims to explore the variations of permeability of the coal body in the protected coal seam under axial unloading. With the coal body from the outburst coal seam in the Huaibei mining area as the research object, experiments were conducted to explore the gas seepage characteristics of axially unloaded coal body under different confining pressures and gas pressures, using the TAWD-2000 coal-rock mechanics-seepage experimental system. According to the results, with respect to the gas seepage, the variations of permeabilities of axially unloaded coal samples are closely related to their deformation and damage. As the confining pressure and gas pressure rise, the diffe... [more]

This work aims to characterize the adsorption process of propranolol HCl, an emerging pollutant and a widely used β-blocker, onto kiwi peels, an agricultural waste. The use of UV-vis spectroscopy was considered to obtain information about the pollutant removal working in the in-batch mode. In a relatively short time, the adsorption process could remove the pollutant from water. A kiwi peel maximum adsorption capacity of 2 mg/g was obtained. With the perspective of scaling up the process, preliminary in-flux measurements were also performed. The investigation of the whole in-batch adsorption process was conducted by studying the effect of ionic strength (adopting salt concentrations from 0 to 0.4 M), pH values (from 2 to 12), adsorbent/pollutant amounts (from 25 to 100 mg and from 7.5 to 15 mg/L, respectively), and temperature values (from 289 to 305 K). The thermodynamics, the adsorption isotherms, and the kinetics of the adsorption process were also carefully investigated. The Langmui... [more]

Carbon Capture, Utilization and Storage (CCUS) is a method of burying the captured CO2 into the reservoir and displacement of crude oil from reservoirs, which considers both economy and environmental protection. At present, it is considered as an important means to deal with global climate change. To ensure the safety of the CCUS scheme, it is very important to study the invasion and migration of CO2 in different types of caprocks. In this paper, we first choose the injection-production method of fixed gas injection rate at the top of the reservoir and constant pressure oil production at the bottom. Secondly, the distribution of porosity and permeability in the caprock is designed, and four types of caprock models are established: homogeneous caprock, layered homogeneous caprock, heterogeneous caprock, and layered heterogeneous caprock. Finally, the intrusion amount and migration characteristics of CO2 in caprock of four schemes in injection-production stage and burial stage are studie... [more]

Heating, ventilation, air conditioning and refrigeration (HVAC&R) systems provide physical environment comfort for the occupants at a possible expense of large amount of energy consumption [...]

Air pollution is a problem shared by the entire world population, and researchers have highlighted its adverse effects on human health in recent years. The object of this paper was the relationship between the pollutants’ concentrations measured in the air and the quantity of pollutant itself inhaled by the human body. The area chosen for the study has a high environmental impact given the significant presence on the territory of polluting activities. The Acerra area (HI) has a waste-to-energy plant and numerous industries to which polluting emissions are attributed. This area has always been the subject of study as the numbers of cancer patients are high. A survey on male patients to evaluate the heavy metals concentrations in the blood was conducted in the two areas and then linked to its values aero-dispersed. Using the air quality data measured by the monitoring networks in two zones, one with high environmental impact (HI) and one with low environmental impact (LI), the chronicle... [more]

Diethyl phthalate (DEP), one of the six typical PAEs priority pollutants declared by the US EPA, has attracted tremendous attention due to its widespread pollution and was selected as the adsorbate in this study. Properties of biochar samples obtained from three different feedstocks, i.e., sawdust (SDBC), rice straw (RSBC), and giant reed (GRBC), pyrolyzed at 400 °C as well as their ability to adsorb DEP from an aqueous solution were investigated. The results showed that the adsorption kinetics were well fitted with the pseudo-second-order model (R2 > 0.99) and the intraparticle diffusion model (R2 > 0.98). The maximal adsorption capacity of the DEP by the prepared biochar was in an order of GRBC (46.04 mg g−1) > RSBC (31.54 mg g−1) > and SDBC (18.39 mg g−1). The higher adsorption capacity of DEP by GRBC is mainly attributed to the higher surface area. The reduction in adsorption capacity of the biochar against DEP with an increase in the solution pH (from 2.5 to 10.0) was possibly due... [more]

Currently, the production of energy from traditional fossil sources is beginning to give way to renewable energy technologies [...]

Heavy metal and pesticide pollution have become an inevitable part of the modern industrialized environment that find their way into all ecosystems. Because of their persistent nature, recalcitrance, high toxicity and biological enrichment, metal and pesticide pollution has threatened the stability of the environment as well as the health of living beings. Due to the environmental persistence of heavy metals and pesticides, they get accumulated in the environs and consequently lead to food chain contamination. Therefore, remediation of heavy metals and pesticide contaminations needs to be addressed as a high priority. Various physico-chemical approaches have been employed for this purpose, but they have significant drawbacks such as high expenses, high labor, alteration in soil properties, disruption of native soil microflora and generation of toxic by-products. Researchers worldwide are focusing on bioremediation strategies to overcome this multifaceted problem, i.e., the removal, imm... [more]

At present, there are significant knowledge gaps in the research on the resource and environmental effects of rare earth exploitation, especially the carbon emission coefficient. This study applies the life cycle assessment approach to calculate the carbon footprint of producing mixed oxide rare earths using ionic rare earth resources and analyze the sources and influencing factors of the carbon footprint. The results show that the carbon footprint of producing 1 kg of mixed oxide rare earths using ionic rare earths is 17.8~24.3 kg CO2 eq, but its uncertainty is 15.54%; the total carbon footprint from 2012 to 2017 reaches 1.6 × 108~2.19 × 108 kg CO2 eq/year, and after 2018, the carbon footprint decreases to 1.51 × 108~2.07 × 108 kg CO2 eq /year. The total carbon footprint of illegal mining is around 1.50 × 108~1.59 × 108 kg CO2 eq/ year. In principle, the higher the recovery rate, the lower the carbon footprint of 1 kg REO production, but with the increase in the recovery rate, the car... [more]

Liquid phase-based microextraction techniques (LPµETs) have attracted great attention from the scientific community since their invention and implementation mainly due to their high efficiency, low solvent and sample amount, enhanced selectivity and precision, and good reproducibility for a wide range of analytes. This review explores the different possibilities and applications of LPμETs including dispersive liquid−liquid microextraction (DLLME) and single-drop microextraction (SDME), highlighting its two main approaches, direct immersion-SDME and headspace-SDME, hollow-fiber liquid-phase microextraction (HF-LPME) in its two- and three-phase device modes using the donor−acceptor interactions, and electro membrane extraction (EME). Currently, these LPμETs are used in very different areas of interest, from the environment to food and beverages, pharmaceutical, clinical, and forensic analysis. Several important potential applications of each technique will be reported, highlighting its a... [more]

The borehole wall stability of depleted reservoirs is a key problem that restricts the deeper potential exploitation of old oilfields. Based on these, according to the seepage and elastic mechanics theory of porous media, combined with laboratory rock mechanics experiments, the dynamic evaluation model of geomechanical parameters of the old reservoir is established, and on this basis, the evaluation method of wellbore stability of new wells in the old reservoir is established, and the changing laws and influencing factors of the wellbore stability of the old reservoir are quantitatively evaluated. The research shows that reservoir pressure, reservoir porosity, effective stress coefficient, strength, in situ magnitude, and direction were all changed due to long-term exploitation; both collapse and fracture pressure decreased, the loss risk of drilling fluid was increased, and safe drilling azimuth was changed. The results can guide reasonable choices such as well position, track and mud... [more]

The intensive production of fossil fuels has led to serious polycyclic aromatic hydrocarbon (PAH) contamination in water and soil environments (as PAHs are typical types of emerging contaminants). Bio-Fenton, an alternative to Fenton oxidation, which generates hydrogen peroxide at a nearly neutral pH condition, could ideally work as a pretreatment to recalcitrant organics, which could be combined with the subsequent biological treatment without any need for pH adjustment. The present study investigated the performance of a Bio-Fenton-assisted biological process for mineralization of three typical types of PAHs. The hydrogen peroxide production, PAH removal, overall organic mineralization, and microbial community structure were comprehensively studied. The results showed that the combined process could achieve efficient chemical oxygen demand (COD) removal (88.1%) of mixed PAHs as compared to activated sludge (33.1%), where individual PAH removal efficiencies of 99.6%, 83.8%, and 91.3%... [more]

Commercialization in the meat-processing industry has emerged as one of the major agrobusiness challenges due to the large volume of wastewater produced during slaughtering and cleaning of slaughtering facilities. Slaughterhouse wastewater (SWW) contains proteins, fats, high organic contents, microbes, and other emerging pollutants (pharmaceutical and veterinary residues). It is important to first characterize the wastewater so that adequate treatment techniques can be employed so that discharge of this wastewater does not negatively impact the environment. Conventional characterization bulk parameters of slaughterhouse wastewater include pH, color, turbidity, biochemical oxygen demand (BOD), chemical oxygen demand (COD), total organic carbon (TOC), total suspended solids (TSS), total nitrogen (TN), total phosphorus (TP), and coliform counts. Characterization studies conducted have revealed the effects of the pollutants on microbial activity of SWW through identification of toxicity of... [more]

There is a “symbiotic relationship” between permafrost and the forest ecosystem; the melted permafrost provides sufficient water for forest growth, and the forest ecosystem plays an important role in protecting the permafrost. Aiming to study the effects of different forest types on soil organic carbon (SOC) and dissolved organic carbon (DOC) in the permafrost region of the Daxing’anling Mountains, this research focuses on the soil of the three forest types of pinus sylvestris var. mongolica forest, larch forest, and birch forest in Beiji Village, Mohe County, Daxing’anling Region, and collected vertical profile soil samples from the three soil layers of 0−10, 10−20, and 20−30 cm at three different sites types (upslope, mesoslope, and downslope) in August 2017. The results show that the forest type is the main influencing factor for the content of SOC and DOC. The site type has a significant effect on the content of SOC and DOC in the three forest types, but the difference varies sligh... [more]

Jet loop reactors are standard multiphase reactors used in chemical, biological and environmental processes. The strong liquid jet provided by a nozzle enforces both internal circulation of liquid and gas as well as entrainment and dispersion of the gas phase. We present a one-dimensional compartment model based on a momentum balance that describes the internal circulation of gas and liquid phase in the jet loop reactor. This model considers the influence of local variations of the gas volume fraction on the internal circulation. These local variations can be caused by coalescence of gas bubbles, additional gas-feeding points and gas consumption or production. In this work, we applied the model to study the influence of a gas-consuming reaction on the internal circulation. In a comprehensive sensitivity analysis, the interaction of different parameters such as rate of reaction, power input through the nozzle, gas holdup, reactor geometry, and circulation rate were investigated. The res... [more]

Global primary energy consumption has increased tenfold over the course of the 20th Century, the availability of non-renewable energy is becoming scarce, and the burning of fossil fuels is leading to global warming. Climate change has now become tangible. The will to act against fossil fuels has become apparent in the western world, and in Germany in particular. This poses a particular challenge for the chemical and pharmaceutical industry, since, in the future, not only will the energy input, but also the feedstock, have to come from non-fossil sources. They must be replaced by carbon capture and utilization, and the exploitation of a circular economy. Concepts for a climate-neutral chemical−pharmaceutical industry have been developed and evaluated. Due to a high predicted consumption of renewable energies and an insufficient expansion of these, Germany will remain an energy importer in the future. The largest consumer in a climate-neutral chemical−pharmaceutical industry will be elec... [more]

Attending both the United Nations Decade of Education for Sustainable Development (2005−2014) and the United Nations 2030 Agenda for Sustainable Development, this review is presented, bearing in mind that green chemistry is essential to contribute to sustainability. This work has compiled all the information relating to green chemistry metrics, so that stakeholders can select an appropriate model, under the Green Chemistry Protocol, to evaluate how much green is a process. The review was organized considering the following convenient sections: the mass valuation, the recognition of the human health and environmental impact, metrics using computational programs (software and spreadsheets), and finally global metrics. This review was developed by consulting the principal databases, since the appearance of the first green chemistry textbook in 1998. A massive number of references were attained involving the keywords proposed below, with six languages observed, highlighted by the English l... [more]

Heavy metals in groundwater and soil are toxic to humans. An accurate risk assessment of heavy metal contamination can aid in environmental security decision making. In this study, the improved ecological risk index (RI) is used to comprehensively investigate the influence of heavy metals in soil and groundwater within electroplating factories and their surrounding regions. In the non-overlapping area, the RI of soil and groundwater is computed individually, and in the overlapping area, the greater RI of soil and groundwater is employed. Two typical electroplating factories are used to examine the heavy metal distribution pattern. The heavy metal concentrations are compared between Factory A, which is in operation, and Factory B, which is no longer in operation, in order to analyze the heavy metal concentrations and associated ecological risks. Heavy metals continue to spread horizontally and vertically after Factory B was closed. Heavy metal concentrations in groundwater surrounding F... [more]

This article focuses on the properties of ecological energy carriers, which are used in agricultural and forestry technology. The aim of the article is to describe the degradation of the working fluid from the point of view of the atomic emission spectrometer, which is used for the purpose of monitoring contaminants and additive elements. The working fluid examined was Shell Naturelle HF-E 46, a universal ecological transmission−hydraulic fluid, which was tested on laboratory test equipment. The laboratory measurement was performed for 200 h, during which the gear hydraulic pump with external gearing was cyclically loaded according to the Vickers standard. The analysis of the transmission−hydraulic fluid was performed after every 50 working hours, where the analysis of the working fluid showed that there were no significant changes in the properties of the working fluid and fluid is suitable for work in agricultural and forestry machines operating in environmentally sensitive environme... [more]

This research aims to utilise heterogeneous sensor fusion using 3D Light Detection and Ranging (LiDAR) and cameras, combined with an object recognition system and a ranging system, to construct an edge computing platform such that a vehicle equipped with the platform can perform computations offline in real time. This work comprises two main sections: the first is heterogeneous fusion, and the second is obstacle recognition and ranging detection. To achieve heterogeneous sensor fusion, 3D−3D point matching was used to find rigid body transformation between two sensors and finally project the LiDAR 3D point cloud image onto the 2D image. For object recognition, YOLOv4-Tiny was used as the detection network. A lightweight network architecture and high computational speed could be effectively used on edge computing hardware with limited performance. Further, by drawing the bounding box, we could detect the point cloud within the bounding box to estimate the distance to the obstacle. For d... [more]

Powder coatings represent an environmentally friendly VOC-free alternative to widely used solvent-borne zinc-rich coatings, with economic and ecological benefits. In particular, powder coatings have several advantageous properties, such as chemical resistance and mechanical strength. However, the performance and characteristics of polyester-based zinc-containing powder coatings remain unknown. In this study, the corrosion performance of polyester powder coatings containing up to 80% zinc is compared. Electrochemical and salt-spray testing results indicate that coatings formulated with 80% zinc demonstrate superior anti-corrosive properties than coatings with lower zinc dosages. Two distinct behavioral phases of the coating with 80% zinc were observed by measurements of open circuit potential (OCP) and polarization resistance (Rp) during immersion tests—a phase indicative of a barrier effect and a phase consistent with galvanic protection. The evolution of the coating was further charac... [more]