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Records Added in May 2023
Records added in May 2023
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Showing records 201 to 225 of 418. [First] Page: 5 6 7 8 9 10 11 12 13 Last
Investigating the Parameter-Driven Cathode Gas Diffusion of PEMFCs with a Piecewise Linearization Model
Siwen Gu, Jiaan Wang, Xinmin You, Yu Zhuang
May 23, 2023 (v1)
Keywords: cathode, gas diffusion, PEMFC, Simulation, structural parameter
Improving mass transfer in gas diffusion layers is critical to achieving high-performance proton-exchange membrane fuel cells (PEMFCs). Leaks through the interface between the gas and the membrane electrode assembly frame have been widely investigated, and the controllability of the cathode gas diffusion has not been achieved in most studies. In this study, we develop a structural parameter to investigate the controllability of the gas diffusion mechanism in the cathode in order to improve upon the design and performance of PEMFCs. This parameter accounts for the cathode gas diffusion layer porosity and carbon loading inside the catalyst layer. It is comprehensively calculated to relax the two segments’ distribution along three directions of the coordinate axis. The experimental and simulation results show that the obtained values of the parameter vary and change during voltage stabilization. According to the results, regardless of the materials in the cathode gas diffusion layer, the... [more]
Characterization of Thermophysical and Electrical Properties of SiC and BN Nanofluids
Wagd Ajeeb, S. M. Sohel Murshed
May 23, 2023 (v1)
Subject: Materials
Keywords: BN nanoparticles, electrical conductivity, nanofluids, rheology, SiC nanoparticles, thermal conductivity, thermal diffusivity
Experimental data associated with the thermophysical properties (TPPs) of various nanofluids (NFs) are essential for their diverse applications in energy storage and conversion, as well as thermal management. This study experimentally investigated important TPPs such as thermal conductivity (TC), thermal diffusivity, density and viscosity, as well as the electrical conductivity of two new types of NFs, namely silica (SiC) and boron nitride (BN) nanofluids. The NFs are prepared at five low concentrations of nanoparticles from 0.01 to 0.05 vol.% dispersed into a mixture of ethylene glycol (EG) and distilled water (DW). The TPPs are measured, and their enhancements are evaluated in comparison with their base fluids. The results show a good increase in TC and thermal diffusivity for both types of nanofluids with increasing concentrations until reaching the maximum enhancement of about 4.4% for the SiC nanofluid and about 7.0% for the BN nanofluid at the same concentration (0.05 vol.%). On... [more]
The Influence of Water Temperature on the Hydrogeochemical Composition of Groundwater during Water Extraction and Reinjection with Geothermal Heat
Timotej Verbovšek
May 23, 2023 (v1)
Keywords: calcite, GHP/GSHP, groundwater, heat pump, hydrogeochemistry, Slovenia
This study presents a simulation of potential changes in groundwater in three wells within a Quaternary gravel aquifer in the city of Ljubljana when groundwater cooled by about 4 °C is reinjected into it. The research focuses on the mass transport of calcite in the vicinity of boreholes. According to our results, the impact of the changes in the geochemical composition of the water is relatively small (around 1%). Although the waters are approximately in equilibrium, calcite may be dissolved and sometimes precipitated within the aquifer when cooled water is reinjected into it. The amounts of precipitated calcite always decrease with decreasing temperatures of the reinjected water, which can lead to calcite dissolution if the temperature difference is large enough and the water is only slightly oversaturated. This novel finding is significant since previously published studies have mostly focused on understanding the scaling (precipitation) of calcite and not its dissolution. The mass t... [more]
Fast and Robust Prediction of Multiphase Flow in Complex Fractured Reservoir Using a Fourier Neural Operator
Tie Kuang, Jianqiao Liu, Zhilin Yin, Hongbin Jing, Yubo Lan, Zhengkai Lan, Huanquan Pan
May 23, 2023 (v1)
Keywords: deep learning, Fourier neural operator, fractured reservoirs, multiphase flow
Predicting multiphase flow in complex fractured reservoirs is essential for developing unconventional resources, such as shale gas and oil. Traditional numerical methods are computationally expensive, and deep learning methods, as an alternative approach, have become an increasingly popular topic. Fourier neural operator (FNO) networks have been shown to be a hundred times faster than convolutional neural networks (CNNs) in predicting multiphase flow in conventional reservoirs. However, there are few relevant studies on applying FNO to predict multiphase flow in reservoirs with complex fractures. In the present study, FNO-net and U-net (CNN-based) were successfully applied to predict pressure and gas saturation fields for the 2D heterogeneous fractured reservoirs. The tested results show that FNO can accurately depict the influence of fine fractures, while the CNN-based method has relatively poor performance in the treatment of fracture systems, both in terms of accuracy and computatio... [more]
Structure-Circuit Resistor Integrated Design Optimization of Piezoelectric Energy Harvester Considering Stress Constraints
Taekyun Kim, Jihoon Kim, Tae Hee Lee
May 23, 2023 (v1)
Subject: Optimization
Keywords: manufacturable design, multi-physics, piezoelectric energy harvester, resistor design, stress constraint, topology optimization
A piezoelectric energy harvester (PEH) transduces mechanical energy into electrical energy, which can be utilized as an energy source for self-powered or low-power devices. Therefore, maximizing the power of a PEH is a crucial design objective. It is well known that structural designs are firstly conducted for controlling resonance characteristics, and then circuit designs are pursued through impedance matching for improving power. However, a PEH contains solid mechanics, electrostatics, and even a circuit-coupled multi-physics system. Therefore, this research aims to design a PEH considering a circuit-coupled multi-physics. As a design process, a conceptual design is developed by topology optimization, and a detailed design is developed sequentially by applying size optimization as a post-processing step to refine the conceptual design results for manufacturable design. In the two optimization processes, design optimizations of a structure coupled with circuit resistor are performed t... [more]
Study on the Effect of Dedicated Microelement Mixture (DMM) on the Kick-Off Phase of the Digester and Stabilization of the Methane Fermentation Process
Sławomir Łazarski, Andrzej Butarewicz, Marcin Cichosz, Urszula Kiełkowska
May 23, 2023 (v1)
Keywords: anaerobic digestion, biogas, methane yield, microelements
The kick-off process is an important aspect of the proper operation of an agricultural biogas plant. At this stage, various operational problems may arise, mainly related to the stabilization of the fermentation process and reaching the full biogas production capacity. This paper presents the results of research on the kick-off of the fermentation process carried out on three selected biogas plants located in Poland. For the experiments, titration, potentiometric, and spectroscopic methods (ICP-MS) were used. The biogas plants during the kick-off period operated on the following substrates: a mixture of cattle and pig manure, corn silage, and whey liquor. Special attention was paid to the dosing process of the formulation developed by the authors (CMP-S1) containing Mo, Co, Ni, Se, and Mn for the fermentation chambers, to which the mixture of the selected microelements was not dosed. The study was carried out under real conditions on an engineering scale. The study showed that suppleme... [more]
A Model Independent Predictive Control of PMSG Wind Turbine Systems with a New Mechanism to Update Variables
Yuzhe Zhang, Xiaodong Liu, Haitao Li, Zhenbin Zhang
May 23, 2023 (v1)
Keywords: back-to-back power converters, model-independent predictive control, PMSG wind turbines, robust control
Permanent magnet synchronous generator (PMSG) wind power system with full power rating converter configuration is especially suitable for wind energy applications. Direct model predictive control (DMPC) has led to more possibilities in terms of choice because of its straightforward concept for PMSG wind turbine systems in high-power off-shore wind farms. However, due to complete dependence on the model knowledge, parameter mismatches will seriously deteriorate the system control performances. This work presents a model/parameter-independent predictive control method with a novel mechanism to update current/power variations online. The proposed method makes use of only two measurements from the former intervals and the selected control vectors to estimate all variations of the candidate vectors in the present interval. Benefiting from this updating mechanism, the proposed method is completely independent of the model parameters in the state prediction. However, it still has a very low c... [more]
A Bridgeless Cuk-BB-Converter-Based BLDCM Drive for MEV Applications
Tanmay Shukla, Srete Nikolovski
May 23, 2023 (v1)
Keywords: bridgeless Cuk-buckboost (BL-Cuk-BB) converter, brushless DC motor (BLDCM), DICM (discontinuous inductor current mode), power quality (PQ), voltage source inverter (VSI)
This article presents a brushless DC motor (BLDCM) drive for a maritime electric vehicle (MEV) application. The presented BLDCM drive uses a bridgeless Cuk-buckboost (BL-Cuk-BB) converter for input-side power factor (PF) improvement. The BL-Cuk-BB converter uses the buckboost converter for the negative half-cycles of the input AC voltages and the Cuk converter for the positive half-cycles. In the case of MEVs, the drive systems are generally fed by diesel engine generators (DEGs). The asymmetric BL-Cuk-BB converter is operated in a discontinuous inductor current mode (DICM) in the present work to attain better power quality. The usage of a second-order buckboost converter with a fourth-order Cuk converter results in a decrement in the net order of the system. Additionally, the input inductor of the Cuk converter also participates as the filter component along with capacitor C2 during buckboost converter operation to enhance the power quality. The total component count reduction in the... [more]
On the Thermal Stability of a Counter-Current Fixed-Bed Gasifier
Marco Mancini, Andreas Schwabauer
May 23, 2023 (v1)
Keywords: gasification, Modelling, stability, updraft
In recent years, gasification gained attention again, both as an industrial application and as a research topic. This trend has led to the necessity to understand the process and optimize reactors for various materials and configurations. In this article, the thermal structure of a counter-current reactor is investigated to demonstrate that constraints on the temperature mainly determine the oxidation and the pyrolysis region. A non-dimensional set of equations is written and numerically solved using the method of lines (MOL) with spatial discretization based on a spectral algorithm. The results show that four thermal structures can be identified, two of which are the most common ones found in reactors of practical applications. Two stationary operation positions have been determined, one in the upper and one in the lower part of the reactor. Existence and stability conditions have been discussed based on non-dimensional parameters. The knowledge derived from this analysis was applied... [more]
Lab-Scale Investigation of the Integrated Backup/Storage System for Wind Turbines Using Alkaline Electrolyzer
Hossein Pourrahmani, Rahim Zahedi, Sareh Daneshgar, Jan Van herle
May 23, 2023 (v1)
Keywords: alkaline electrolyzer (AEL), hybrid system, power curve, power demand, proton-exchange membrane fuel cell (PEMFC), renewable resources
The depletion of fossil fuel sources has encouraged the authorities to use renewable resources such as wind energy to generate electricity. A backup/storage system can improve the performance of wind turbines, due to fluctuations in power demand. The novelty of this study is to utilize a hybrid system for a wind farm, using the excess electricity generated by the wind turbines to produce hydrogen in an alkaline electrolyzer (AEL). The hydrogen storage tank stores the produced hydrogen and provides hydrogen to the proton-exchange membrane fuel cell (PEMFC) to generate electricity once the power demand is higher than the electricity generated by the wind turbines. The goal of this study is to use the wind profile of a region in Iran, namely the Cohen region, to analyze the performance of the suggested integrated system on a micro scale. The output results of this study can be used as a case study for construction in the future, based on the exact specification of NTK300 wind turbines. Th... [more]
Model for Predicting CO2 Adsorption in Coal Left in Goaf Based on Backpropagation Neural Network
Fei Gao, Peng Wang, Dapeng Wang, Yulong Yang, Xun Zhang, Gang Bai
May 23, 2023 (v1)
Keywords: CO2 sequestration, Coal, influence factors, Machine Learning, pore structure
Injecting power plant flue gas into a goaf stores CO2 in the flue gas and effectively prevents the spontaneous combustion of the coal remaining in the goaf. Here, we investigated the adsorption behavior of three types of coal at normal temperature and pressure using a self-developed adsorption experimental device. We used a specific surface area and porosity analyzer to study the effects of pore structure, mineral content, and moisture content on CO2 adsorption in coal. Based on the experimental data, we designed a multifactor CO2 adsorption prediction model based on a backpropagation (BP) neural network. The results indicated that the pore size of most micropores in coal was in the range of 0.5−0.7 and 0.8−0.9 nm. The specific surface area and pore volume were positively correlated with the CO2-saturated adsorption capacity, whereas the mean pore diameter, mineral content, and moisture content were inversely associated with the CO2-saturated adsorption amount. The accuracy of the mult... [more]
Numerical Simulation of Nonlinear Processes in the “Thruster—Downhole Motor—Bit” System While Extended Reach Well Drilling
Andrey A. Kunshin, George V. Buslaev, Matthias Reich, Dmitriy S. Ulyanov, Dmitriy I. Sidorkin
May 23, 2023 (v1)
Keywords: Computational Fluid Dynamics, downhole hydraulic thrusting device, drilling efficiency, ERD wells, PDC bits, vibration reduction, weight on the bit
The relevance of the application of hydraulic thruster technology is determined by the technological limitations of drilling both vertical and horizontal wells. The existing experimental studies confirm the effectiveness of the technology, but its widespread implementation is hindered by the lack of scientific foundations for its operation in combination with a downhole motor and bit. Our research methodology includes methods for analyzing scientific and technical information as well as methods of numerical modeling using programming languages and ready-made software packages for CFD calculations. Verification of the simulation results was carried out on the basis of the experimental field studies previously conducted with the participation of the authors of the article. This article presents the results of the analysis of the current state of the problem and computer physical and mathematical modeling of the work of the thruster together with the bit and downhole motor when drilling a... [more]
Investigation of Heat Extraction in an Enhanced Geothermal System Embedded with Fracture Networks Using the Thermal−Hydraulic−Mechanical Coupling Model
Xin-Yue Duan, Di Huang, Wen-Xian Lei, Shi-Chao Chen, Zhao-Qin Huang, Chuan-Yong Zhu
May 23, 2023 (v1)
Keywords: enhanced geothermal system, fracture networks, heat extraction, thermal–hydraulic–mechanical
This paper presents a numerical study on thermal energy mining from hot dry rock (HDR) using an enhanced geothermal system (EGS). In these simulations, the thermal−hydraulic−mechanical (THM) coupling model is employed on the basis of the embedded discrete fracture model. The evolution of physical fields of the fractured reservoir, including temperature field, pressure field, and stress field is studied over time, and the effects of different controllable factors, such as fracture morphology, fluid injection rate, and the distances between the injection well and producing well on the heat recovery capacity are investigated. The results show that the fracture morphology significantly influences heat extraction performance. The working fluid mainly flows along with the fracture networks, which causes locally low temperatures and low mean effective stress near fractures. The porosity and permeability increase due to the decrease in mean effective stress. For reservoir models with inclined... [more]
A CNN-Architecture-Based Photovoltaic Cell Fault Classification Method Using Thermographic Images
Chiwu Bu, Tao Liu, Tao Wang, Hai Zhang, Stefano Sfarra
May 23, 2023 (v1)
Keywords: automatic fault classification, CNN, deep learning, PV cell faults, thermography
Photovoltaic (PV) cells are a major part of solar power stations, and the inevitable faults of a cell affect its work efficiency and the safety of the power station. During manufacturing and service, it is necessary to carry out fault detection and classification. A convolutional-neural-network (CNN)-architecture-based PV cell fault classification method is proposed and trained on an infrared image data set. In order to overcome the problem of the original dataset’s scarcity, an offline data augmentation method is adopted to improve the generalization ability of the network. During the experiment, the effectiveness of the proposed model is evaluated by quantifying the obtained results with four deep learning models through evaluation indicators. The fault classification accuracy of the CNN model proposed here has been drawn by the experiment and reaches 97.42%, and it is superior to that of the models of AlexNet, VGG 16, ResNet 18 and existing models. In addition, the proposed model ha... [more]
Energetic Analysis of Low Global Warming Potential Refrigerants as Substitutes for R410A and R134a in Ground-Source Heat Pumps
Laura Fedele, Sergio Bobbo, Davide Menegazzo, Michele De Carli, Laura Carnieletto, Fabio Poletto, Andrea Tarabotti, Dimitris Mendrinos, Giulia Mezzasalma, Adriana Bernardi
May 23, 2023 (v1)
Keywords: ground-source heat pumps, low-GWP refrigerants, thermodynamic cycle efficiency
The European building sector is responsible for approximately 40% of total energy consumption and for 36% of greenhouse gas emissions. Identifying technological solutions capable of reducing energy consumption and greenhouse gas emissions is one of the main objectives of the European Commission. Ground source heat pumps (GSHPs) are of particular interest for this purpose, promising a considerable reduction in greenhouse gas emissions of HVAC systems. This paper reports the results of the energetic analysis carried out within the EU research project GEO4CIVHIC about the performance of geothermal heat pumps working with low-GWP refrigerants as alternatives for R134a and R410A. The work has been carried out through computer simulations based on base and regenerative reverse cycles. Several heat sink and heat source temperature conditions have been considered in order to evaluate the GSHPs’ performance in the whole range of real conditions that can be found in Europe. Particular attention... [more]
Reinforcement-Learning-Based Multi-Objective Differential Evolution Algorithm for Large-Scale Combined Heat and Power Economic Emission Dispatch
Xu Chen, Shuai Fang, Kangji Li
May 23, 2023 (v1)
Subject: Optimization
Keywords: combined heat and power, economic emission dispatch, large-scale system, multi-objective differential evolution, reinforcement learning
As social and environmental issues become increasingly serious, both fuel costs and environmental impacts should be considered in the cogeneration process. In recent years, combined heat and power economic emission dispatch (CHPEED) has become a crucial optimization problem in power system management. In this paper, a novel reinforcement-learning-based multi-objective differential evolution (RLMODE) algorithm is suggested to deal with the CHPEED problem considering large-scale systems. In RLMODE, a Q-learning-based technique is adopted to automatically adjust the control parameters of the multi-objective algorithm. Specifically, the Pareto domination relationship between the offspring solution and the parent solution is used to determine the action reward, and the most-suitable algorithm parameter values for the environment model are adjusted through the Q-learning process. The proposed RLMODE was applied to solve four CHPEED problems: 5, 7, 100, and 140 generating units. The simulatio... [more]
Women Will Drive the Demand for EVs in the Middle East over the Next 10 Years—Lessons from Today’s Kuwait and 1960s USA
Andri Ottesen, Sumayya Banna, Basil Alzougool
May 23, 2023 (v1)
Keywords: early majority/pragmatist, electric vehicles, women drivers
The Middle East, Gulf Cooperation Council Countries (GCC), and Kuwait, in particular, are currently experiencing a similar transition as the USA in the 1970s regarding the empowerment and independence of women, fueled by a declining birth rate from four per women to less than two. In addition, the percentage of women with university degrees has been increasing at a logarithmic rate every decade since the 1960s in the USA and since 1990 in Kuwait, resulting in women comprising well over half of all university graduates. This has led to women obtaining better jobs and enjoying greater independence to make their own decisions. In the 1960s, Toyota and other Japanese car manufactures used this phenomenon to penetrate the US market, with significant success. Their selling points were lower maintenance requirements, higher reliability, safety, better environment friendliness and slicker interior designs, the last being especially adapted to women’s tastes. We believe that Chinese and Korean... [more]
Optimal Neutral Grounding in Bipolar DC Networks with Asymmetric Loading: A Recursive Mixed-Integer Quadratic Formulation
Walter Gil-González, Oscar Danilo Montoya, Jesús C. Hernández
May 23, 2023 (v1)
Subject: Optimization
Keywords: bipolar DC systems, optimal neutral grounding, recursive mixed-integer quadratic model
This paper presents a novel approach to tackle the problem of optimal neutral wire grounding in bipolar DC networks including asymmetric loading, which naturally involves mixed-integer nonlinear programming (MINLP) and is challenging to solve. This MINLP model is transformed into a recursive mixed-integer quadratic (MIQ) model by linearizing the hyperbolic relation between voltage and powers in constant power terminals. A recursive algorithm is implemented to eliminate the possible errors generated by linearization. The proposed recursive MIQ model is assessed in two bipolar DC systems and compared against three solvers of the GAMS software. The results obtained validate the performance of the proposed MIQ model, which finds the global optimum of the model while reducing power losses for bipolar DC systems with 21, 33, and 85 buses by 4.08%, 2.75%, and 7.40%, respectively, when three nodes connected to the ground are considered. Furthermore, the model exhibits a superior performance wh... [more]
Predicting Energy Consumption in Residential Buildings Using Advanced Machine Learning Algorithms
Fateme Dinmohammadi, Yuxuan Han, Mahmood Shafiee
May 23, 2023 (v1)
Keywords: energy consumption, Machine Learning, Net-Zero, prediction, residential building
The share of residential building energy consumption in global energy consumption has rapidly increased after the COVID-19 crisis. The accurate prediction of energy consumption under different indoor and outdoor conditions is an essential step towards improving energy efficiency and reducing carbon footprints in the residential building sector. In this paper, a PSO-optimized random forest classification algorithm is proposed to identify the most important factors contributing to residential heating energy consumption. A self-organizing map (SOM) approach is applied for feature dimensionality reduction, and an ensemble classification model based on the stacking method is trained on the dimensionality-reduced data. The results show that the stacking model outperforms the other models with an accuracy of 95.4% in energy consumption prediction. Finally, a causal inference method is introduced in addition to Shapley Additive Explanation (SHAP) to explore and analyze the factors influencing... [more]
Analysis and Explanation of Resonant Phenomena Involving EHV Transformers during Power System Restoration Tests
Roberto Benato, Sebastian Dambone Sessa, Giorgio Maria Giannuzzi, Cosimo Pisani, Michele Poli, Francesco Sanniti
May 23, 2023 (v1)
Keywords: harmonic resonances, power system restoration, transformer energization, weak networks
This paper deals with the simulation and the experimental confirmation of electromagnetic events that could interfere with the successful formation of the restoration path during the power system restoration procedure. The studied phenomena are more relevant for bulk power systems characterized by a low short circuit power as the restoration backbone. In particular, two case studies have been simulated and analyzed: one related to a transformer energization during the formation of the restoration path, and the other one occurred after the de-energization of some transmission lines and one autotransformer belonging to the restoration path. From the simulation results, it emerged that such events are related to the resonant effects between the supplying transformer and the restored network. Such resonances could have negative effects on the restoration if they are not effectively managed. In order to evaluate the impact of such phenomena in real networks, the measurement recordings of on... [more]
Nuclear Power Plant to Support Indonesia’s Net Zero Emissions: A Case Study of Small Modular Reactor Technology Selection Using Technology Readiness Level and Levelized Cost of Electricity Comparing Method
Mujammil Asdhiyoga Rahmanta, Andang Widi Harto, Alexander Agung, Mohammad Kholid Ridwan
May 23, 2023 (v1)
Keywords: levelized cost of electricity, nuclear power plant, small modular reactor, technology readiness level
Most power plants, particularly those that burn fossil fuels such as coal, oil, and gas, create CO2, a greenhouse gas that contributes to climate change. By 2060, the Indonesian government has committed to reach net zero emissions. With the lowest CO2 emissions, nuclear power plants are dependable sources of energy. Small modular reactors (SMRs) are a particular kind of nuclear power plant that has the potential to be Indonesia’s first commercial nuclear power plant because of their small size, low capacity, uncomplicated design, and modular characteristics. The purpose of this study is to examine the economics and technological feasibility of SMRs. In this analysis, the levelized cost of electricity (LCOE) comparative method and the technology readiness level (TRL) approach are both applied. The SMRs with a minimum TRL value of 7 were CAREM-25 (TRL7), KLT-40S (TRL8), and HTR-PM (TRL 8), according to the results of this research. Although CAREM-25 and KLT-40S are still in the demonstra... [more]
Elimination of Line Overloads in a Power System Saturated with Renewable Energy Sources
Paweł Pijarski, Piotr Kacejko
May 23, 2023 (v1)
Keywords: line overloads, metaheuristics, optimisation, power system congestion, renewable energy sources, transmission lines
The increasing number of renewable energy sources (RESs) connected to power grids contributes to the emergence of not only balancing problems but also technical ones, such as the overloading of power lines. If renewable sources with a high generation level are planned to be connected in the area under consideration, then a large number of significant overloads should be expected, especially during contingency analysis. As a rule, high-voltage networks have a mesh topology, which is why the concept of using advanced mathematical algorithms was developed, with the help of which the resulting threats can be eliminated. This article presents a proposal for a new method of eliminating line overloads and determining the currently available nodal generation levels. Its innovation is a new method of eliminating problems related to the capacity of power grids. The high efficiency of the method results from the appropriately defined response of properly selected RES sources to the state of netwo... [more]
Effect of Plasto-Oil Blended with Diesel Fuel on the Performance and Emission Characteristics of Partly Premixed Charge Compression Ignition Engines with and without Exhaust Gas Recirculation (EGR)
Krishna Moorthy Rajendran, Deepak Kumar, Bhawna Yadav Lamba, Praveen Kumar Ghodke, Amit Kumar Sharma, Leonidas Matsakas, Alok Patel
May 23, 2023 (v1)
Keywords: diesel engine, municipal mixed plastic waste, PCCI, plasto-oil, thermal brake efficiency
Municipal mixed plastic waste (MMPW) recycling is an innovative way to turn environmental waste into energy fuels. In the present study, a thermochemical process was applied to depolymerize MMPW to produce hydrocarbon fuels known as plasto-oil. The obtained plasto-oil was blended with conventional diesel to test the performance of the PCCI-mode single-cylinder, four-stroke, direct-injection diesel engine. The PCCI combustion mixture was tested with 15% and 30% fuel vapor to ensure homogeneity with and without exhaust gas recirculation. The modified engine findings were compared to a standard conventional engine. At higher loads, PCCI combustion showed reduced emission of carbon monoxide and nitrogen oxides. While the thermal braking efficiency was marginally reduced at all engine loads while using the blends. The results showed that with and without 10% exhaust gas recirculation, an increase in air mix reduced NOx emissions; however, in the case of smoke emissions, an opposite trend wa... [more]
Mechanistic Exploration of Dendrite Growth and Inhibition for Lithium Metal Batteries
Yuanliang Chen, Xingping Yuan, Cuiping He, Qingyi Gou, Ni Yang, Gang Xie, Keyu Zhang, Yaochun Yao, Yanqing Hou
May 23, 2023 (v1)
Subject: Materials
Keywords: anisotropy intensity of surface energy, dendrite growth, initial nucleation spacing, interfacial electrochemical driving force, Li metal battery, phasefield model
Li metal has been considered an ideal anode in lithium batteries due to its high theoretical capacity of 3860 mAh·g−1 and lowest negative reduction potential of −3.040 V among the standard hydrogen electrodes. However, lithium dendrites can easily grow on the surface of the negative electrode during charging, which results in a short circuit of the battery and reduces its efficiency. This paper investigated dendrite growth and inhibition mechanisms in lithium metal batteries to improve battery life. The impacts of the initial nucleation spacing, surface energy anisotropy strength, and interfacial electrochemical driving force on lithium dendrite growth were analyzed with electrochemical experiments and mathematical models. The results showed that the smaller nucleation spacing inhibits the growth of dendrite side branches and reduces the roughness of lithium metal deposition on the negative electrode. A lower interfacial energy anisotropy strength can slow down the growth of dendrite t... [more]
Hydrogen Production from Supercritical Water Gasification of Model Compounds of Crude Glycerol from Biodiesel Industries
Kapil Khandelwal, Philip Boahene, Sonil Nanda, Ajay K. Dalai
May 23, 2023 (v1)
Keywords: design of experiments, glycerol, Hydrogen, response surface methodology, supercritical water gasification
Biodiesel production through transesterification results in a large quantity of crude glycerol as a byproduct, the utilization of which is technically and economically challenging. Because of the ability to efficiently process wet feedstocks, supercritical water gasification (SCWG) is utilized in this study to convert crude glycerol into hydrogen-rich syngas. A significant challenge addressed through this study is the decomposition routes of different heterogeneous components of crude glycerol during SCWG. Pure glycerol, methanol and oleic acid were investigated for SCWG as the model compounds of crude glycerol. SCWG of model compounds at temperature, pressure, feedstock concentration and reaction time of 500 °C, 23−25 MPa, 10 wt% and 1 h, respectively, revealed methanol to exhibit the highest H2 yield of 7.7 mmol/g, followed by pure glycerol (4.4 mmol/g) and oleic acid (1.1 mmol/g). The effects of feedstock concentration from 30 wt% to 10 wt% increased H2 yield from all model compound... [more]
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