Proceedings of ESCAPE 35ISSN: 2818-4734
Volume: 4 (2025)
Table of Contents
LAPSE:2025.0231
Published Article
LAPSE:2025.0231
Solar Desalination and Porphyrin Mediated Visible-Light Photocatalysis in Decolouration of Dyes as Biological Analogues Applied in Advanced Water Treatment
Evans M. N. Chirwa, Bezza F. Andualem, Osemeikhain Ogbeifun, Shepherd M. Tichapondwa, Wesley Lawrence, Bonhle Manoto
June 27, 2025
Abstract
Engineering can be made simple and more impactful by observing and understanding how organisms in nature solve eminent problems. For example, scientists around the world have observed green plants thriving without organic food inputs using the complex photosynthesis process to kick-start a self-sustaining biochemical food chain. In this study, two biological analogues for advanced water treatment, i.e., visible-light photocatalysis using porphyrin-Bi12O17Cl2 and BiOIO3 compounds and interfacial solar desalination by a by Reduced Graphene Oxide-Black TiO2 (rGO-Black TiO2) were investigated. For the visible-light photocatalytic process for dye decolouration, a porphyrin@Bi12O17Cl2 system was applied to successfully degrade Rhodamine B dye in batch experiments, achieving up to 79% degradation within 240 minutes. These results show that more advances and more efficient engineered systems can be achieved by observing nature and how these systems have survived over billions of years. The rGO-Black TiO2 system achieved increases in temperature for 25oC to 60oC in less than 5 seconds. Based on these observations, the research group from the Water Utilisation Group at the University of Pretoria have studied and developed fundamental processes for the degradation and remediation of unwanted compounds such as disinfection byproducts (DBPs), volatile organic compounds (VOCs) and pharmaceutical products from water.
Keywords
3D-printed Graphene Oxide, advanced water treatment, biological analogues, heterogenous photocatalysis, solar desalination
Subject
Suggested Citation
Chirwa EMN, Andualem BF, Ogbeifun O, Tichapondwa SM, Lawrence W, Manoto B. Solar Desalination and Porphyrin Mediated Visible-Light Photocatalysis in Decolouration of Dyes as Biological Analogues Applied in Advanced Water Treatment. Systems and Control Transactions 4:497-502 (2025) https://doi.org/10.69997/sct.155404
Author Affiliations
Chirwa EMN: University of Pretoria, Department of Chemical Engineering, Pretoria, Gauteng, South Africa
Andualem BF: University of Pretoria, Department of Chemical Engineering, Pretoria, Gauteng, South Africa
Ogbeifun O: University of Pretoria, Department of Chemical Engineering, Pretoria, Gauteng, South Africa
Tichapondwa SM: University of Pretoria, Department of Chemical Engineering, Pretoria, Gauteng, South Africa
Lawrence W: University of Pretoria, Department of Chemical Engineering, Pretoria, Gauteng, South Africa
Manoto B: University of Pretoria, Department of Chemical Engineering, Pretoria, Gauteng, South Africa
Journal Name
Systems and Control Transactions
Volume
4
First Page
497
Last Page
502
Year
2025
Publication Date
2025-07-01
Version Comments
Original Submission
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PII: 0497-0502-1275-SCT-4-2025, Publication Type: Journal Article
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References Cited
  1. Wu L, Dong Z, Cai Z, Ganapathy T, Fang NX, Li C, Yu C, Zhang Y, Song Y, 2020. Highly efficient three-dimensional solar evaporator for high salinity desalination by localized crystallization. Nature Communications. 11:521. (2020) https://doi.org/10.1038/s41467-020-14366-1
  2. Dai X, Guan H, Wang X, Wu M, Jiang P, Chai Y, Wang X, 2024. Apple leaf-inspired bilayered Janus wood evaporator with decoupled light-vapor interfaces for high-efficiency solar steam generation. Chem Eng J. 499:155796. (2024) https://doi.org/10.1016/j.cej.2024.155796
  3. Sun S, Shi C, Kuang Y, Li M, Li S, Chan H, Zhang S, Chen G, Nilghaz A, Cao R, Tian J, 2022. 3D-printed solar evaporator with seashell ornamentation-inspired structure for zero liquid discharge desalination. Water Res. 226:119279. (2022) https://doi.org/10.1016/j.watres.2022.119279
  4. Liu H, Chen C, Chen G, Kuang Y, Zhao X, Song J, Jia C, Xu X, Hitz E, Xie H, Wang S, Jiang F, Li T, Li Y, Gong A, Yang R, Das S, Hu L, 2018. High-Performance Solar Steam Device with Layered Channels: Artificial Tree with a Reversed Design. Advanced Energy Materials. 8:1701616. (2018) https://doi.org/10.1002/aenm.201701616
  5. Li T, Liu H, Zhao X, Chen G, Dai J, Pastel G, Jia C, Chen C, Hitz E, Siddhartha D, Yang R, Hu L, 2018. Scalable and Highly Efficient Mesoporous Wood-Based Solar Steam Generation Device: Localized Heat, Rapid Water Transport. Adv Funct Mater. 28:1707134. (2018) https://doi.org/10.1002/adfm.201707134
  6. Wang Y, Lee J, Werber JR, Elimelech M, 2020. Capillary-driven desalination in a synthetic mangrove. Science Advances. 6:eaax5253. (2020) https://doi.org/10.1126/sciadv.aax5253
  7. Han D-D, Chen Z-D, Li J-C, Mao J-W, Jiao Z-Z, Wang W, Zhang W, Zhang Y-L, Sun H-B, 2020. Airflow Enhanced Solar Evaporation Based on Janus Graphene Membranes with Stable Interfacial Floatability. ACS Applied Materials & Interfaces. 12:25435-25443. (2020) https://doi.org/10.1021/acsami.0c05401
  8. Abdelsalam MA, Sajjad M, Raza A, AlMarzooqi F, Zhang T, 2024. Sustainable biomimetic solar distillation with edge crystallization for passive salt collection and zero brine discharge. Nature Communications. 15:874. 10.1038/s41467-024-45108-2 (2024) https://doi.org/10.1038/s41467-024-45108-2
  9. Tudu BK, Gupta V, Kumar A, Sinhamahapatra A, 2020. Freshwater production via efficient oil-water separation and solar-assisted water evaporation using black titanium oxide nanoparticles. J Colloid Interface Sci. 566:183-193. (2020) https://doi.org/10.1016/j.jcis.2020.01.079
  10. Ghumro SS, Lal B, Pirzada T, Qazi MA, Ali A, Altaf AA, Thebo KH, Kazi M, 2025. Exploring the hetero-catalytic proficiencies of pristine and carbon-doped titania nanocatalysts in dye degradation and their synergetic profiles against bacteria. J Mol Struct. 1319:139462. https://doi.org/10.1016/j.molstruc.2024.139462
  11. Hassaan MA, El-Nemr MA, Elkatory MR, Ragab S, Niculescu V-C, El Nemr A, 2023. Principles of Photocatalysts and Their Different Applications: A Review. Top Curr Chem. 381:31. (2023) https://doi.org/10.1007/s41061-023-00444-7
  12. Khan K, Tareen AK, Aslam M, Sagar RUR, Zhang B, Huang W, Mahmood A, Mahmood N, Khan K, Zhang H, Guo Z, 2020. Recent Progress, Challenges, and Prospects in Two-Dimensional Photo-Catalyst Materials and Environmental Remediation. Nano-Micro Letters. 12:167. (2020) https://doi.org/10.1007/s40820-020-00504-3
  13. Arumugam M, Choi MY, 2020. Recent progress on bismuth oxyiodide (BiOI) photocatalyst for environmental remediation. Journal of Industrial and Engineering Chemistry. 81:237-268.(2020) https://doi.org/10.1016/j.jiec.2019.09.013
  14. Wang Y, Shi Z-q, Fan C-m, Hao X-g, Ding G-y, Wang Y-f, 2012. Synthesis of BiOCl photocatalyst by a low-cost, simple hydrolytic technique and its excellent photocatalytic activity. International Journal of Minerals, Metallurgy, and Materials. 19:467-472. (2012) https://doi.org/10.1007/s12613-012-0581-7
  15. Lal M, Sharma P, Singh L, Ram C, 2023. Photocatalytic degradation of hazardous Rhodamine B dye using sol-gel mediated ultrasonic hydrothermal synthesized of ZnO nanoparticles. Results in Engineering. 17:100890. (2023) https://doi.org/10.1016/j.rineng.2023.100890
  16. Zhang M, Bi C, Lin H, Cao J, Chen S, 2017. Construction of novel Au/Bi12O17Cl2 composite with intensive visible light activity enhancement for contaminants removal. Mater Lett. 191:132-135. (2017) https://doi.org/10.1016/j.matlet.2016.12.089
  17. Bi C, Cao J, Lin H, Wang Y, Chen S, 2016. BiOI/Bi12O17Cl2: A novel heterojunction composite with outstanding photocatalytic and photoelectric performances. Mater Lett. 166:267-270. (2016) https://doi.org/10.1016/j.matlet.2015.12.089
  18. Yang Y, Zeng Y, Jin T, Zhang X, Teng H, Wang S, Chen H, 2022. Construction of oxygen vacancy on Bi12O17Cl2 nanosheets by heat-treatment in H2O vapor for photocatalytic NO oxidation. Journal of Materials Science & Technology. 123:234-242. (2022) https://doi.org/10.1016/j.jmst.2022.02.018
  19. Ye L, Su Y, Jin X, Xie H, Zhang C, 2014. Recent advances in BiOX (X = Cl, Br and I) photocatalysts: synthesis, modification, facet effects and mechanisms. Environmental Science: Nano. 1:90-112. (2014) https://doi.org/10.1039/c3en00098b
  20. Zheng H, Chen G, Zhang A, Tan Z, Wang R, Wang H, Mei Y, Zhang X, Ran J, 2021. Enhanced photocatalytic activity of Bi24O31Br10 microsheets constructing heterojunction with AgI for Hg0 removal. Sep Purif Technol. 262:118296. (2021) https://doi.org/10.1016/j.seppur.2020.118296
  21. Joseph M, Haridas S, 2020. Recent progresses in porphyrin assisted hydrogen evolution. Int J Hydrogen Energy. 45:11954-11975. https://doi.org/10.1016/j.ijhydene.2020.02.103
  22. Medforth CJ, Wang Z, Martin KE, Song Y, Jacobsen JL, Shelnutt JA, 2009. Self-assembled porphyrin nanostructures. Chem Commun. 7261-7277. (2009) https://doi.org/10.1039/b914432c
  23. Mei S, Gao J, Zhang Y, Yang J, Wu Y, Wang X, Zhao R, Zhai X, Hao C, Li R, Yan J, 2017. Enhanced visible light photocatalytic hydrogen evolution over porphyrin hybridized graphitic carbon nitride. J Colloid Interface Sci. 506:58-65. (2017) https://doi.org/10.1016/j.jcis.2017.07.030
  24. Rabbani M, Rafiee F, Ghafuri H, Rahimi R, 2016. Synthesis of Fe3O4 nonoparticles via a fast and facile mechanochemicl method: Modification of surface with porphyrin and photocatalytic study. Mater Lett. 166:247-250. (2016) https://doi.org/10.1016/j.matlet.2015.12.087
  25. Wang H, Zhou D, Wu Z, Wan J, Zheng X, Yu L, Phillips DL, 2014. The visible light degradation activity and the photocatalytic mechanism of tetra(4-carboxyphenyl) porphyrin sensitized TiO2. Mater Res Bull. 57:311-319. (2014) https://doi.org/10.1016/j.materresbull.2014.06.017
  26. Zhao P, Huang Y, Chen J, Shao S, Miao H, Xia J, Jia C, Hua M, 2020. Preparation of meso-tetraphenyl porphyrin modified defect-rich BiOCl with enhanced visible-light photocatalytic activity for antibiotic degradation and mechanism insight. Journal of Photochemistry and Photobiology. 3-4:100014. (2020) https://doi.org/10.1016/j.jpap.2020.100014
  27. Vo HT, Nguyen AT, Tran CV, Nguyen SX, Tung NT, Pham DT, Nguyen DD, La DD, 2021. Self-Assembly of Porphyrin Nanofibers on ZnO Nanoparticles for the Enhanced Photocatalytic Performance for Organic Dye Degradation. ACS Omega. 6:23203-23210. (2021) https://doi.org/10.1021/acsomega.1c02808
  28. La DD, Rananaware A, Salimimarand M, Bhosale SV, 2016. Well-dispersed assembled porphyrin nanorods on graphene for the enhanced photocatalytic performance. ChemistrySelect. 1:4430-4434. (2016) https://doi.org/10.1002/slct.201601001
  29. Ogbeifun O, Tichapondwa SM, Chirwa EMN, 2023. Self-assembled micro and nano rod-shaped porphyrin@Bi12O17Cl2 composite as an efficient photocatalyst for degradation of organic contaminants. Discover Nano. 18:137. (2023) https://doi.org/10.1186/s11671-023-03915-4
  30. Bezza FA, Iwarere SA, Brink HG, Chirwa EMN, 2024. Design and fabrication of porous three-dimensional Ag-doped reduced graphene oxide (3D Ag@rGO) composite for interfacial solar desalination. Scientific Reports. 14:13793. (2024) https://doi.org/10.1038/s41598-024-62987-z
  31. Liu X, Zhu Q, Qian Y, Wu W, 2025. Enhanced photothermal interface evaporation via coupling of Ag-GO aerogel with thermal insulation substrate. Sep Purif Technol. 360:131080. (2025) https://doi.org/10.1016/j.seppur.2024.131080
  32. Moshari M, Rabbani M, Rahimi R, 2016. Synthesis of TCPP-Fe3O4@S/RGO and its application for purification of water. Res Chem Intermed. 42:5441-5455. (2016) https://doi.org/10.1007/s11164-015-2378-6
  33. Zhang Z, Liu H, Xu J, Zeng H, 2017. CuTCPP/BiPO4 composite with enhanced visible light absorption and charge separation. Journal of Photochemistry and Photobiology A: Chemistry. 336:25-31. (2017) https://doi.org/10.1016/j.jphotochem.2016.12.020
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