LAPSE:2025.0231
Published Article

LAPSE:2025.0231
Solar Desalination and Porphyrin Mediated Visible-Light Photocatalysis in Decolouration of Dyes as Biological Analogues Applied in Advanced Water Treatment
June 27, 2025
Abstract
Engineering can be made simple and more impactful by observing and understanding how organisms in nature solve eminent problems. For example, scientists around the world have observed green plants thriving without organic food inputs using the complex photosynthesis process to kick-start a self-sustaining biochemical food chain. In this study, two biological analogues for advanced water treatment, i.e., visible-light photocatalysis using porphyrin-Bi12O17Cl2 and BiOIO3 compounds and interfacial solar desalination by a by Reduced Graphene Oxide-Black TiO2 (rGO-Black TiO2) were investigated. For the visible-light photocatalytic process for dye decolouration, a porphyrin@Bi12O17Cl2 system was applied to successfully degrade Rhodamine B dye in batch experiments, achieving up to 79% degradation within 240 minutes. These results show that more advances and more efficient engineered systems can be achieved by observing nature and how these systems have survived over billions of years. The rGO-Black TiO2 system achieved increases in temperature for 25oC to 60oC in less than 5 seconds. Based on these observations, the research group from the Water Utilisation Group at the University of Pretoria have studied and developed fundamental processes for the degradation and remediation of unwanted compounds such as disinfection byproducts (DBPs), volatile organic compounds (VOCs) and pharmaceutical products from water.
Engineering can be made simple and more impactful by observing and understanding how organisms in nature solve eminent problems. For example, scientists around the world have observed green plants thriving without organic food inputs using the complex photosynthesis process to kick-start a self-sustaining biochemical food chain. In this study, two biological analogues for advanced water treatment, i.e., visible-light photocatalysis using porphyrin-Bi12O17Cl2 and BiOIO3 compounds and interfacial solar desalination by a by Reduced Graphene Oxide-Black TiO2 (rGO-Black TiO2) were investigated. For the visible-light photocatalytic process for dye decolouration, a porphyrin@Bi12O17Cl2 system was applied to successfully degrade Rhodamine B dye in batch experiments, achieving up to 79% degradation within 240 minutes. These results show that more advances and more efficient engineered systems can be achieved by observing nature and how these systems have survived over billions of years. The rGO-Black TiO2 system achieved increases in temperature for 25oC to 60oC in less than 5 seconds. Based on these observations, the research group from the Water Utilisation Group at the University of Pretoria have studied and developed fundamental processes for the degradation and remediation of unwanted compounds such as disinfection byproducts (DBPs), volatile organic compounds (VOCs) and pharmaceutical products from water.
Record ID
Keywords
3D-printed Graphene Oxide, advanced water treatment, biological analogues, heterogenous photocatalysis, solar desalination
Subject
Suggested Citation
Chirwa EMN, Andualem BF, Ogbeifun O, Tichapondwa SM, Lawrence W, Manoto B. Solar Desalination and Porphyrin Mediated Visible-Light Photocatalysis in Decolouration of Dyes as Biological Analogues Applied in Advanced Water Treatment. Systems and Control Transactions 4:497-502 (2025) https://doi.org/10.69997/sct.155404
Author Affiliations
Chirwa EMN: University of Pretoria, Department of Chemical Engineering, Pretoria, Gauteng, South Africa
Andualem BF: University of Pretoria, Department of Chemical Engineering, Pretoria, Gauteng, South Africa
Ogbeifun O: University of Pretoria, Department of Chemical Engineering, Pretoria, Gauteng, South Africa
Tichapondwa SM: University of Pretoria, Department of Chemical Engineering, Pretoria, Gauteng, South Africa
Lawrence W: University of Pretoria, Department of Chemical Engineering, Pretoria, Gauteng, South Africa
Manoto B: University of Pretoria, Department of Chemical Engineering, Pretoria, Gauteng, South Africa
Andualem BF: University of Pretoria, Department of Chemical Engineering, Pretoria, Gauteng, South Africa
Ogbeifun O: University of Pretoria, Department of Chemical Engineering, Pretoria, Gauteng, South Africa
Tichapondwa SM: University of Pretoria, Department of Chemical Engineering, Pretoria, Gauteng, South Africa
Lawrence W: University of Pretoria, Department of Chemical Engineering, Pretoria, Gauteng, South Africa
Manoto B: University of Pretoria, Department of Chemical Engineering, Pretoria, Gauteng, South Africa
Journal Name
Systems and Control Transactions
Volume
4
First Page
497
Last Page
502
Year
2025
Publication Date
2025-07-01
Version Comments
Original Submission
Other Meta
PII: 0497-0502-1275-SCT-4-2025, Publication Type: Journal Article
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LAPSE:2025.0231
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Jun 27, 2025
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