LAPSE:2024.0564
Published Article
LAPSE:2024.0564
Evaluation of the Bioenergy Potential of Blends (Green Coconut Shells and Fish Scales) as a Feedstock in Thermochemical Processes for Clean Energy Production
Ayrton Pablo Raiol Monroe, Arthur Vinicius Sousa Silva, Mariana Silva Melo, Julie Brenda Santos da Silva, Ramón Raudel Peña Garcia, Maria Alexsandra de Sousa Rios, Waldir Antônio Bizzo, Glauber Cruz
June 5, 2024
Abstract
Brazil is among the world’s largest producers of green coconut, which contributes to inappropriate disposal and socioenvironmental impacts. Concomitantly, some of its coastal cities produce a great diversity of fish and large amounts of solid waste. This paper reports on the use of samples of fish scales (100FS) and green coconut shells (100GCS) and their mixtures in 75%FS:25%GCS (B25), 50%FS:50%GCS (B50), and 25%FS:75%GCS (B75) proportions and quantification of their Higher Heating Values (HHV) and Lower Heating Values (LHV), and Ultimate (UA) and Proximate Analyses (PA). Their thermal behavior was investigated by thermogravimetry (TG/DTG) and differential scanning calorimetry (DSC), whereas scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), and Fourier transformed infrared (FTIR) were employed for analyses of their physicochemical and morphostructural properties. When compared to in natura samples, SEM images of the blends detected a structural disorder and a highly fibrous structure with an elongated chain and surface roughness. HHV were superior in samples with 100GCS (16.64 MJ kg−1), B75 (15.80 MJ kg−1), and B50 (14.98 MJ kg−1), and lower in B25 (14.16 MJ kg−1) and 100FS (13.03 MJ kg−1), with acceptable values for different biomasses. TG/DTG and DSC curves showed similarities among the samples, with the detection of their main thermoconversion stages. According to the data, the samples can be applied as renewable energy sources to mitigate socioecological illnesses and social vulnerabilities resulting from the archaic and inadequate management of solid waste.
Keywords
fibrous structure, socioenvironmental impacts, solid residues, thermal behavior
Suggested Citation
Monroe APR, Silva AVS, Melo MS, da Silva JBS, Peña Garcia RR, Rios MADS, Bizzo WA, Cruz G. Evaluation of the Bioenergy Potential of Blends (Green Coconut Shells and Fish Scales) as a Feedstock in Thermochemical Processes for Clean Energy Production. (2024). LAPSE:2024.0564
Author Affiliations
Monroe APR: Processes and Thermochemical Systems Laboratory (LPSisTer), Department of Mechanical Engineering, Federal University of Maranhão, Av. dos Portugueses 1966, São Luís 65080-505, Maranhão, Brazil
Silva AVS: Programa de Pós-Graduação em Engenharia Mecânica (CPG-EM), Faculdade de Engenharia Mecânica, Universidade Estadual de Campinas, Cidade Universitária Zeferino Vaz, Campinas 13083-970, São Paulo, Brazil
Melo MS: Department of Chemical Engineering, Federal University of Maranhão, Av. dos Portugueses 1966, São Luís 65080-505, Maranhão, Brazil
da Silva JBS: Postgraduate Program in Mechanical Engineering (PPGMEC), Department of Mechanical and Materials, Federal Institute of Education, Science, and Technology of Maranhão, Av. Getúlio Vargas 04, São Luís 65030-005, Maranhão, Brazil
Peña Garcia RR: Rua Cento e Sessenta e Três 300—Cohab, Academic Unit of Cabo de Santo Agostinho, Federal Rural University of Pernambuco, Cabo de Santo Agostinho 64049-550, Pernambuco, Brazil
Rios MADS: Postgraduate Program in Chemical Engineering (PPGEQ), Department of Chemical Engineering, Campus Universitário do Pici, Federal University of Ceará, Fortaleza 60455-760, Ceará, Brazil [ORCID]
Bizzo WA: Programa de Pós-Graduação em Engenharia Mecânica (CPG-EM), Faculdade de Engenharia Mecânica, Universidade Estadual de Campinas, Cidade Universitária Zeferino Vaz, Campinas 13083-970, São Paulo, Brazil [ORCID]
Cruz G: Processes and Thermochemical Systems Laboratory (LPSisTer), Department of Mechanical Engineering, Federal University of Maranhão, Av. dos Portugueses 1966, São Luís 65080-505, Maranhão, Brazil [ORCID]
Journal Name
Processes
Volume
12
Issue
4
First Page
710
Year
2024
Publication Date
2024-03-30
ISSN
2227-9717
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Original Submission
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PII: pr12040710, Publication Type: Journal Article
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