LAPSE:2023.5736v1
Published Article

LAPSE:2023.5736v1
Effect of Steam Quality on Extra-Heavy Crude Oil Upgrading and Oil Recovery Assisted with PdO and NiO-Functionalized Al2O3 Nanoparticles
February 23, 2023
Abstract
This work focuses on evaluating the effect of the steam quality on the upgrading and recovering extra-heavy crude oil in the presence and absence of two nanofluids. The nanofluids AlNi1 and AlNi1Pd1 consist of 500 mg·L−1 of alumina doped with 1.0% in mass fraction of Ni (AlNi1) and alumina doped with 1.0% in mass fraction of Ni and Pd (AlNi1Pd1), respectively, and 1000 mg·L−1 of tween 80 surfactant. Displacement tests are done in different stages, including (i) basic characterization, (ii) waterflooding, (iii) steam injection at 0.5 quality, (iv) steam injection at 1.0 quality, (v) batch injection of nanofluids, and (vi) steam injection after nanofluid injection at 0.5 and 1.0 qualities. The steam injection is realized at 210 °C, the reservoir temperature is fixed at 80 °C, and pore and overburden pressure at 1.03 MPa (150 psi) and 5.51 MPa (800 psi), respectively. After the steam injection at 0.5 and 1.0 quality, oil recovery is increased 3.0% and 7.0%, respectively, regarding the waterflooding stage, and no significant upgrade in crude oil is observed. Then, during the steam injection with nanoparticles, the AlNi1 and AlNi1Pd1 increase the oil recovery by 20.0% and 13.0% at 0.5 steam quality. Meanwhile, when steam is injected at 1.0 quality for both nanoparticles evaluated, no incremental oil is produced. The crude oil is highly upgraded for the AlNi1Pd1 system, reducing oil viscosity 99%, increasing the American Petroleum Institute (API)° from 6.9° to 13.3°, and reducing asphaltene content 50% at 0.5 quality. It is expected that this work will eventually help understand the appropriate conditions in which nanoparticles should be injected in a steam injection process to improve its efficiency in terms of oil recovery and crude oil quality.
This work focuses on evaluating the effect of the steam quality on the upgrading and recovering extra-heavy crude oil in the presence and absence of two nanofluids. The nanofluids AlNi1 and AlNi1Pd1 consist of 500 mg·L−1 of alumina doped with 1.0% in mass fraction of Ni (AlNi1) and alumina doped with 1.0% in mass fraction of Ni and Pd (AlNi1Pd1), respectively, and 1000 mg·L−1 of tween 80 surfactant. Displacement tests are done in different stages, including (i) basic characterization, (ii) waterflooding, (iii) steam injection at 0.5 quality, (iv) steam injection at 1.0 quality, (v) batch injection of nanofluids, and (vi) steam injection after nanofluid injection at 0.5 and 1.0 qualities. The steam injection is realized at 210 °C, the reservoir temperature is fixed at 80 °C, and pore and overburden pressure at 1.03 MPa (150 psi) and 5.51 MPa (800 psi), respectively. After the steam injection at 0.5 and 1.0 quality, oil recovery is increased 3.0% and 7.0%, respectively, regarding the waterflooding stage, and no significant upgrade in crude oil is observed. Then, during the steam injection with nanoparticles, the AlNi1 and AlNi1Pd1 increase the oil recovery by 20.0% and 13.0% at 0.5 steam quality. Meanwhile, when steam is injected at 1.0 quality for both nanoparticles evaluated, no incremental oil is produced. The crude oil is highly upgraded for the AlNi1Pd1 system, reducing oil viscosity 99%, increasing the American Petroleum Institute (API)° from 6.9° to 13.3°, and reducing asphaltene content 50% at 0.5 quality. It is expected that this work will eventually help understand the appropriate conditions in which nanoparticles should be injected in a steam injection process to improve its efficiency in terms of oil recovery and crude oil quality.
Record ID
Keywords
Adsorption, nanoparticles, steam injection, steam quality, thermal enhanced oil recovery
Subject
Suggested Citation
Cardona L, Medina OE, Céspedes S, Lopera SH, Cortés FB, Franco CA. Effect of Steam Quality on Extra-Heavy Crude Oil Upgrading and Oil Recovery Assisted with PdO and NiO-Functionalized Al2O3 Nanoparticles. (2023). LAPSE:2023.5736v1
Author Affiliations
Cardona L: Research Group Yacimientos de Hidrocarburos, Department of Processes and Energy, Faculty of Mines, National University of Colombia, Medellín 050034, Colombia
Medina OE: Grupo de Investigación en Fenómenos de Superficie—Michael Polanyi, Department of Processes and Energy, Faculty of Mines, National University of Colombia, Medellín 050034, Colombia [ORCID]
Céspedes S: Grupo de Investigación en Fenómenos de Superficie—Michael Polanyi, Department of Processes and Energy, Faculty of Mines, National University of Colombia, Medellín 050034, Colombia [ORCID]
Lopera SH: Research Group Yacimientos de Hidrocarburos, Department of Processes and Energy, Faculty of Mines, National University of Colombia, Medellín 050034, Colombia
Cortés FB: Grupo de Investigación en Fenómenos de Superficie—Michael Polanyi, Department of Processes and Energy, Faculty of Mines, National University of Colombia, Medellín 050034, Colombia [ORCID]
Franco CA: Grupo de Investigación en Fenómenos de Superficie—Michael Polanyi, Department of Processes and Energy, Faculty of Mines, National University of Colombia, Medellín 050034, Colombia [ORCID]
Medina OE: Grupo de Investigación en Fenómenos de Superficie—Michael Polanyi, Department of Processes and Energy, Faculty of Mines, National University of Colombia, Medellín 050034, Colombia [ORCID]
Céspedes S: Grupo de Investigación en Fenómenos de Superficie—Michael Polanyi, Department of Processes and Energy, Faculty of Mines, National University of Colombia, Medellín 050034, Colombia [ORCID]
Lopera SH: Research Group Yacimientos de Hidrocarburos, Department of Processes and Energy, Faculty of Mines, National University of Colombia, Medellín 050034, Colombia
Cortés FB: Grupo de Investigación en Fenómenos de Superficie—Michael Polanyi, Department of Processes and Energy, Faculty of Mines, National University of Colombia, Medellín 050034, Colombia [ORCID]
Franco CA: Grupo de Investigación en Fenómenos de Superficie—Michael Polanyi, Department of Processes and Energy, Faculty of Mines, National University of Colombia, Medellín 050034, Colombia [ORCID]
Journal Name
Processes
Volume
9
Issue
6
First Page
1009
Year
2021
Publication Date
2021-06-07
ISSN
2227-9717
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Original Submission
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PII: pr9061009, Publication Type: Journal Article
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LAPSE:2023.5736v1
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https://doi.org/10.3390/pr9061009
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