Mathematical models for the simulation of the operation of various projectile-throwing systems are continuously modified, simultaneously with the development of propellants. For these models, properly determined values of energetic ballistic characteristics of propellants are very important. This paper presents an original test and the results of closed vessel comparative investigations. The study analyses specific combustion characteristics of single-base propellants using conventional black powder ignition, plasma ignition, and gas ignition. The results of the study indicate the need to take into account—in the calculation of the burning rate—not only the dynamics of gas pressure changes but also the real (experimental) form function, which differs from the theoretical one resulting from the assumed geometric burning model. The obtained results allow for a critical analysis of the existing methods used for the determination of values of ballistic characteristics of propellants. Further, it will allow for creating pyrostatic test conditions that would reflect the condition of instantaneous ignition of propellant grains over their entire surface in the most realistic way.