LAPSE:2023.2798
Published Article

LAPSE:2023.2798
Assessment of the Possibilities for Removal of Ni (II) from Contaminated Water by Activated Carbon foam Derived from Treatment Products of RDF
February 21, 2023
Abstract
Carbon foam is a sophisticated porous material with wide applications that depend on its structure, low density, thermal conductivity and electrical characteristics. This study deals with the preparation of carbon foam by the thermo-oxidative modification with HNO3 of mixtures containing different organic materials with appropriate chemical characteristics—furfural and tar pitch derived from RDF. Carbon foam is characterized by thermogravimetry, differential scanning calorimetry, elemental analysis, Raman spectroscopy, N2 sorption, infrared spectroscopy and scanning electron spectroscopy. The investigation of adsorption activity of carbon foam towards nickel (II) in water solution is carried out. Experimental results fit very well with the Langmuir adsorption model. The carbon foam, obtained from tar pitch derived from RDF and furfural, shows a high adsorption capacity towards nickel ions (203.67 mg/g). The high adsorption capacity could be explained by the properties of the adsorbent—moderately high surface area, micro-mesoporous texture and presence of oxygen-containing surface groups.
Carbon foam is a sophisticated porous material with wide applications that depend on its structure, low density, thermal conductivity and electrical characteristics. This study deals with the preparation of carbon foam by the thermo-oxidative modification with HNO3 of mixtures containing different organic materials with appropriate chemical characteristics—furfural and tar pitch derived from RDF. Carbon foam is characterized by thermogravimetry, differential scanning calorimetry, elemental analysis, Raman spectroscopy, N2 sorption, infrared spectroscopy and scanning electron spectroscopy. The investigation of adsorption activity of carbon foam towards nickel (II) in water solution is carried out. Experimental results fit very well with the Langmuir adsorption model. The carbon foam, obtained from tar pitch derived from RDF and furfural, shows a high adsorption capacity towards nickel ions (203.67 mg/g). The high adsorption capacity could be explained by the properties of the adsorbent—moderately high surface area, micro-mesoporous texture and presence of oxygen-containing surface groups.
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Keywords
activation, Adsorption, carbon foam, pore structure, RDF
Subject
Suggested Citation
Stoycheva I, Tsyntsarski B, Kosateva A, Petrova B, Dolashka P. Assessment of the Possibilities for Removal of Ni (II) from Contaminated Water by Activated Carbon foam Derived from Treatment Products of RDF. (2023). LAPSE:2023.2798
Author Affiliations
Stoycheva I: Institute of Organic Chemistry with Centre of Phytochemistry, Bulgarian Academy of Sciences, Acad. G. Bonchev Str. BL.9, 1113 Sofia, Bulgaria
Tsyntsarski B: Institute of Organic Chemistry with Centre of Phytochemistry, Bulgarian Academy of Sciences, Acad. G. Bonchev Str. BL.9, 1113 Sofia, Bulgaria
Kosateva A: Institute of Organic Chemistry with Centre of Phytochemistry, Bulgarian Academy of Sciences, Acad. G. Bonchev Str. BL.9, 1113 Sofia, Bulgaria
Petrova B: Institute of Organic Chemistry with Centre of Phytochemistry, Bulgarian Academy of Sciences, Acad. G. Bonchev Str. BL.9, 1113 Sofia, Bulgaria
Dolashka P: Institute of Organic Chemistry with Centre of Phytochemistry, Bulgarian Academy of Sciences, Acad. G. Bonchev Str. BL.9, 1113 Sofia, Bulgaria
Tsyntsarski B: Institute of Organic Chemistry with Centre of Phytochemistry, Bulgarian Academy of Sciences, Acad. G. Bonchev Str. BL.9, 1113 Sofia, Bulgaria
Kosateva A: Institute of Organic Chemistry with Centre of Phytochemistry, Bulgarian Academy of Sciences, Acad. G. Bonchev Str. BL.9, 1113 Sofia, Bulgaria
Petrova B: Institute of Organic Chemistry with Centre of Phytochemistry, Bulgarian Academy of Sciences, Acad. G. Bonchev Str. BL.9, 1113 Sofia, Bulgaria
Dolashka P: Institute of Organic Chemistry with Centre of Phytochemistry, Bulgarian Academy of Sciences, Acad. G. Bonchev Str. BL.9, 1113 Sofia, Bulgaria
Journal Name
Processes
Volume
10
Issue
3
First Page
570
Year
2022
Publication Date
2022-03-15
ISSN
2227-9717
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Original Submission
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PII: pr10030570, Publication Type: Journal Article
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LAPSE:2023.2798
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https://doi.org/10.3390/pr10030570
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Feb 21, 2023
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