LAPSE:2023.26880
Published Article

LAPSE:2023.26880
Thermocatalytic Pyrolysis of Exhausted Arthrospira platensis Biomass after Protein or Lipid Recovery
April 3, 2023
Abstract
Microalgae and cyanobacteria are unicellular microorganism that contain high-added-value compounds. To make their extraction economically feasible, the biorefinery concept is the only solution. In this study, the residues resulting from lipid or protein extraction from Arthrospira platensis biomass were valorized by catalytic pyrolysis using ZSM5 zeolite or amorphous silica−alumina as catalyst. The reaction was performed in a quartz reactor, and the catalysts were placed in a fixed bed, to force the reaction gases to pass through it. The reaction products were analyzed by FTIR and GC−MS analyses. The reaction gases and liquids obtained from the extraction residues had higher hydrocarbon contents compared with the untreated biomass. Moreover, the pyrolysis of biomass after protein extraction led to fractions with lower nitrogenated component contents, while that after lipid extraction to fractions with lower oxygenated component contents. This study showed that the pyrolysis process could be used to valorize the microalgae extraction residues, aiming to make biofuels production and extraction of high-added-value products more economically feasible.
Microalgae and cyanobacteria are unicellular microorganism that contain high-added-value compounds. To make their extraction economically feasible, the biorefinery concept is the only solution. In this study, the residues resulting from lipid or protein extraction from Arthrospira platensis biomass were valorized by catalytic pyrolysis using ZSM5 zeolite or amorphous silica−alumina as catalyst. The reaction was performed in a quartz reactor, and the catalysts were placed in a fixed bed, to force the reaction gases to pass through it. The reaction products were analyzed by FTIR and GC−MS analyses. The reaction gases and liquids obtained from the extraction residues had higher hydrocarbon contents compared with the untreated biomass. Moreover, the pyrolysis of biomass after protein extraction led to fractions with lower nitrogenated component contents, while that after lipid extraction to fractions with lower oxygenated component contents. This study showed that the pyrolysis process could be used to valorize the microalgae extraction residues, aiming to make biofuels production and extraction of high-added-value products more economically feasible.
Record ID
Keywords
Biofuels, FTIR, GC–MS, microalgae, silica–alumina, zeolite
Subject
Suggested Citation
Spennati E, Casazza AA, Converti A, Busca G. Thermocatalytic Pyrolysis of Exhausted Arthrospira platensis Biomass after Protein or Lipid Recovery. (2023). LAPSE:2023.26880
Author Affiliations
Spennati E: Department of Civil, Chemical and Environmental Engineering, University of Genoa, via Opera Pia, 16145 Genova, Italy [ORCID]
Casazza AA: Department of Civil, Chemical and Environmental Engineering, University of Genoa, via Opera Pia, 16145 Genova, Italy [ORCID]
Converti A: Department of Civil, Chemical and Environmental Engineering, University of Genoa, via Opera Pia, 16145 Genova, Italy [ORCID]
Busca G: Department of Civil, Chemical and Environmental Engineering, University of Genoa, via Opera Pia, 16145 Genova, Italy [ORCID]
Casazza AA: Department of Civil, Chemical and Environmental Engineering, University of Genoa, via Opera Pia, 16145 Genova, Italy [ORCID]
Converti A: Department of Civil, Chemical and Environmental Engineering, University of Genoa, via Opera Pia, 16145 Genova, Italy [ORCID]
Busca G: Department of Civil, Chemical and Environmental Engineering, University of Genoa, via Opera Pia, 16145 Genova, Italy [ORCID]
Journal Name
Energies
Volume
13
Issue
20
Article Number
E5246
Year
2020
Publication Date
2020-10-09
ISSN
1996-1073
Version Comments
Original Submission
Other Meta
PII: en13205246, Publication Type: Journal Article
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LAPSE:2023.26880
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https://doi.org/10.3390/en13205246
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Apr 3, 2023
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