A significant contribution to the reduction of carbon emissions will be enabled through the transition from a centralised fossil fuel system to a decentralised, renewable electricity system. However, due to the intermittent nature of renewable energy, storage is required to provide a suitable response to dynamic loads and manage the excess generated electricity with utilisation during periods of low generation. This paper investigates the use of stationary hydrogen-based energy storage systems for microgrids and distributed energy resource systems. An exploratory study was conducted in Australia based on a mixed methodology. Ten Australian industry experts were interviewed to determine use cases for hydrogen-based energy storage systems’ requirements, barriers, methods, and recommendations. This study suggests that the current cost of the electrolyser, fuel cell, and storage medium, and the current low round-trip efficiency, are the main elements inhibiting hydrogen-based energy storage systems. Limited industry and practical experience are barriers to the implementation of hydrogen storage systems. Government support could help scale hydrogen-based energy storage systems among early adopters and enablers. Furthermore, collaboration and knowledge sharing could reduce risks, allowing the involvement of more stakeholders. Competition and innovation could ultimately reduce the costs, increasing the uptake of hydrogen storage systems.