LAPSE:2021.0775
Published Article
LAPSE:2021.0775
Influence of the Ni-Co/Al-Mg Catalyst Loading in the Continuous Aqueous Phase Reforming of the Bio-Oil Aqueous Fraction
Pablo Lozano, Ana I. Simón, Lucía García, Joaquín Ruiz, Miriam Oliva, Jesús Arauzo
October 14, 2021
The effect of catalyst loading in the Aqueous Phase Reforming (APR) of bio-oil aqueous fraction has been studied with a Ni-Co/Al-Mg coprecipitated catalyst. Because of the high content of water in the bio-oil aqueous fraction, APR could be a useful process to convert this fraction into valuable products. Experiments of APR with continuous feeding of aqueous solution of acetol, butanol and acetic acid as the only compound, together with a simulated and a real aqueous fraction of bio-oil, were carried out. Liquid products in the liquid effluent of the APR model compounds were quantified and the reaction pathways were revised. The increase of catalyst loading produced an increase of gas production and a gas with higher alkanes content. Acetol was the compound with the highest reactivity while the conversion of acetic acid was very low. The presence of acetic acid in the feed caused catalyst deactivation.
Keywords
acetic acid, acetol, aqueous fraction, aqueous phase reforming, bio-oil, Butanol, Ni catalyst
Suggested Citation
Lozano P, Simón AI, García L, Ruiz J, Oliva M, Arauzo J. Influence of the Ni-Co/Al-Mg Catalyst Loading in the Continuous Aqueous Phase Reforming of the Bio-Oil Aqueous Fraction. (2021). LAPSE:2021.0775
Author Affiliations
Lozano P: Thermochemical Processes Group (GPT), Aragon Institute of Engineering Research (I3A), Universidad de Zaragoza, Mariano Esquillor S/N, 50018 Zaragoza, Spain
Simón AI: Thermochemical Processes Group (GPT), Aragon Institute of Engineering Research (I3A), Universidad de Zaragoza, Mariano Esquillor S/N, 50018 Zaragoza, Spain
García L: Thermochemical Processes Group (GPT), Aragon Institute of Engineering Research (I3A), Universidad de Zaragoza, Mariano Esquillor S/N, 50018 Zaragoza, Spain [ORCID]
Ruiz J: Thermochemical Processes Group (GPT), Aragon Institute of Engineering Research (I3A), Universidad de Zaragoza, Mariano Esquillor S/N, 50018 Zaragoza, Spain
Oliva M: Thermochemical Processes Group (GPT), Aragon Institute of Engineering Research (I3A), Universidad de Zaragoza, Mariano Esquillor S/N, 50018 Zaragoza, Spain
Arauzo J: Thermochemical Processes Group (GPT), Aragon Institute of Engineering Research (I3A), Universidad de Zaragoza, Mariano Esquillor S/N, 50018 Zaragoza, Spain
Journal Name
Processes
Volume
9
Issue
1
First Page
pr9010081
Year
2021
Publication Date
2021-01-01
Published Version
ISSN
2227-9717
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Original Submission
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PII: pr9010081, Publication Type: Journal Article
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LAPSE:2021.0775
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doi:10.3390/pr9010081
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Oct 14, 2021
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Oct 14, 2021
 
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Oct 14, 2021
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Calvin Tsay
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