Self-discharge of lithium-ion cells leads to voltage decay over time. In this work, the self-discharge was measured at 30 ∘C for three cell types at various voltage levels for about 150 days in a constant voltage mode determining the current at a high precision (float current). All cells exhibit a transient part leading to a steady-state, which is no longer influenced by reversible effects. To study the effect of the check-ups on the steady-state float current, the cells, interrupted and not interrupted by check-ups, were compared. The results indicate that both the transient processes and steady-state currents are highly reproducible. In the first period of the float current, the polarization dominates the measured current, followed by the anode overhang effect dominating the process for a period of 5−30 days. After the decline of both processes, a mostly constant steady-state in the order of μA is observed. The check-up interruption generally shows no apparent effect on the reached s... [more]

This work focuses on the simulation and testing of an innovative storage system for a PHEV vehicle, investigating the possibility of replacing the car’s original storage system with a mixed-storage system with lithium-ion batteries and supercapacitors connected in direct parallel without the use of an intermediate DC/DC converter. The aim is to evaluate the behavior of the supercapacitors’ branch compared with that of the Li-ion cells, both in the discharge/charge transients and over an entire WLTP cycle (Worldwide harmonized Light vehicles Test Procedure). The analysis started with the definition of the digital models of a lithium cell and a supercapacitor. The parameters of the models were tuned through experimental characterization of the two storage cells, Li-ion and supercapacitor. Subsequently, the overall models of the branch with the lithium cells and the branch with the supercapacitors were constructed and connected. The overall storage system was sized for application to a PH... [more]

In this article, typomorphic associations of microelements in carbonaceous caustobioliths and oils are defined as indicators of naphthogenesis based on the analytical survey of the literature and our own research. Various approaches to the studying of crude oil genesis from the position of abiotic and complex approaches (polygenesis) are considered. Such approaches are relevant to the prospect and development of offshore oil deposits, localized at ultra-deep levels. For deep deposits, the most prominent hypothesis of oil origin is the abiogenious theory. In the foundation of that approach lays the assumption that hydrocarbons are formed mainly due to reactions of the formed mantle gases and the host rock. Key factors for these reactions to proceed are specific conditions concerning temperature, pressure, and specific catalysts. The article presents the results of thermodynamic and quantum-chemical modeling of the possibility of the organic and organometallic compound formation using th... [more]

Rechargeable lithium-ion batteries are currently the most viable option for energy storage systems in electric vehicle (EV) applications due to their high specific energy, falling costs, and acceptable cycle life. However, accurately predicting the parameters of complex, nonlinear battery systems remains challenging, given diverse aging mechanisms, cell-to-cell variations, and dynamic operating conditions. The states and parameters of batteries are becoming increasingly important in ubiquitous application scenarios, yet our ability to predict cell performance under realistic conditions remains limited. To address the challenge of modelling and predicting the evolution of multiphysics and multiscale battery systems, this study proposes a cloud-based AI-enhanced framework. The framework aims to achieve practical success in the co-estimation of the state of charge (SOC) and state of health (SOH) during the system’s operational lifetime. Self-supervised transformer neural networks offer ne... [more]

In the past decade, there has been renewed interest in wave energy harvesting utilizing oscillating water columns (OWC), one of the most well-studied wave energy harnessing technologies. In the OWC, pneumatic power from ocean waves is converted to mechanical energy by Wells turbines. It should be noted, however, that such turbines tend to perform poorly, have a limited operating range, and have low efficiency. In the present study, we incorporate a rectangular Gurney flap (GF) at the trailing edge (TE) of a Wells turbine consisting of hybrid airfoil (NACA 0015 and NACA 0025) blades with variable chord distribution along the span. This passive flow control mechanism was adopted to achieve increased power production by the Wells turbine. This study aimed to determine the aerodynamic performance of the variable chord turbine with GF compared to a turbine with a constant chord. By using ANSYS™ CFX, the three-dimensional, steady-state, incompressible Reynolds averaged Navier−Stokes (RANS) e... [more]

For the centrifugal pump, the rotor−stator interaction (RSI) induces high-energy pressure pulsation, which directly affects the stability of systems and equipment. Therefore, this work proposes a new staggered impeller structure to suppress high-energy pressure pulsation in centrifugal pumps. The original impeller blade is divided into two layers and is staggered at 10°, 20° and 30° to form a staggered impeller. The dynamic pressure pulsation characteristics of both the original impeller and the staggered impeller are predicted using large eddy simulation (LES). The results indicate that the uniform staggered arrangement of blades can significantly reduce the pressure pulsation energy in the pump by 54.69% under the design conditions, while also achieving the best performance. Even under off-design conditions, the pressure pulsation energy can still be effectively suppressed by the staggered blades. The study of the time−frequency domain of the monitoring points near the tongue found t... [more]

Ammonia (NH3) has been receiving the attention of researchers as an alternative promising green fuel to replace fossil sources for energy production. However, the high NOx emissions are one of the drawbacks and restrictions of using NH3 on a broad scale. The current study investigates NO production/consumption for a 70/30 (vol%) NH3/H2 mixture using kinetic reaction mechanism concepts to shed light on the essential reaction routes that promote/inhibit NO formation. Sixty-seven kinetic reaction mechanisms from the literature have been investigated and compared with recently reported measurements at a wide range of equivalence ratios (ϕ) (0.6−1.4), atmospheric pressure and temperature conditions. Both numerical simulations and experimental measurements used the same combustion reactor configuration (premixed stabilized stagnation flame). To highlight the best kinetic model for the predicting of the NO experimental measurements of NO, a symmetric mean absolute percentage error (SMAPE) has... [more]

Direct numerical simulations (DNSs) of spatially developing thermal turbulent boundary layers over angle-ribbed walls were performed. Four rib angles (γ=90°,60°,45° and 30°) were examined. It was found that the 45° ribs produced the highest drag coefficient, whereas the 30° ribs most improved the Stanton number. In comparison to the transverse rib case, streamwise velocity and dimensionless temperature in the V-shaped cases significantly increased in the near wall region and were attenuated by secondary flows further away from the ribs, which suggested a break of the outer-layer similarity in the scenario presented. The surprising improvement of heat transfer performance in the 30° rib case was mainly due to its large dispersive heat flux, while dispersive stress reached its peak value in the 45° case, emphasizing the dissimilarity in transporting momentum and heat by turbulence over a ribbed surface. Additionally, by calculating the global and local Reynolds analogy factors, we conclu... [more]

Solid oxide cells are capable of efficiently converting various chemical energy carriers to electricity and vice versa. The urgent challenge nowadays is the faster degradation rate compared with other fuel cell/electrolyzer technologies. To understand the degradation mechanisms, simulation of a solid oxide cell is helpful. Since most previous research developed models using commercial software, such as COMSOL and ANSYS Fluent, a gap for knowledge transfer is being gradually formed between academia and industry due to licensing issues. This paper introduces a multiphysics model, developed by a computational code, openFuelCell2. The code is implemented with an open-source library, OpenFOAM. It accounts for momentum transfer, mass transfer, electrochemical reactions and metal interconnect oxidation. The model can precisely predict I−V curves under different temperatures, fuel humidity and operation modes. Comparison between OpenFOAM and COMSOL simulations shows good agreement. The metal i... [more]

The analyses of the influence of spatial harmonics on the electromagnetic torque of the multi-phase induction machine and reducing this influence are important tasks to ensure the high efficiency of the induction machine. Designing the machine to consider the influence of spatial harmonics is essential to ensure the desired mechanical and energy characteristics. In the case of the sinusoidal winding supply of the induction machine, the magnetomotive force has high spatial harmonics, which are caused by the machine-winding design. The interaction between the 5th, 7th, 11th and 13th spatial harmonics of the winding function and the first time-harmonic of the winding supply causes the appearance of the 6th and 12th harmonics in the electromagnetic torque of the machine. A prototype of the symmetrical six-phase induction machine and the experimental study for the influence of spatial harmonics on the harmonic content of the stator currents in different machine modes are given in this paper... [more]

The exploitation of natural resources is associated with many natural hazards. Currently, the copper ore deposits exploited in Polish mines are located at a depth of about 1200 m below the surface. The primary temperature of the rocks in the exploited areas reaches 48 ∘C, which constitutes a major source of heat flux to the mine air. However, another important source of heat is the machine plant, which mainly consists of machines powered by diesel engines. Following the results of in situ measurements, boundary conditions for a simulation were determined and a geometric model of the cabin was created. Furthermore, an average human model was created, whose radiative heat transfer was included in the analysis. Three cases were studied: the first covering the current state of thermal conditions, based on the measurement results, and two cases of forecast conditions. In the second case, the temperature of the conditioned air was determined, and in the third, the flow velocity required to e... [more]

Standard technical solutions are not cost-effective for many small hydropower sites. This study aims to demonstrate the workflow for the tailor-made variable-speed axial propeller turbine and provide proof of this concept. The turbine is designed to meet the site’s specific space limitations and operating range needs. The runner shape is adjusted to the variable-speed operation and defined hydraulic profile using a parametric geometry model and CFD-based optimization. The variable-speed propeller turbine shows excellent flow control while keeping the mechanical design simple. The tailor-made approach minimizes construction costs using existing structures and is highly suitable for mini-hydropower applications. The prototype—an atypical turbine designed for highly restricted space and installed on-site—serves as proof of the concept. The findings on the design of axial variable-speed turbines are presented.

Due to the inherent uncertainty of wind conditions as well as the price unpredictability in the competitive electricity market, wind power producers are exposed to the risk of concurrent fluctuations in both price and volume. Therefore, it is imperative to develop strategies to effectively stabilize their revenues, or cash flows, when trading wind power output in the electricity market. In light of this context, we present a novel endeavor to construct multivariate derivatives for mitigating the risk of fluctuating cash flows that are associated with trading wind power generation in electricity markets. Our approach involves leveraging nonparametric techniques to identify optimal payoff structures or compute the positions of derivatives with fine granularity, utilizing multiple underlying indexes including spot electricity price, area-wide wind power production index, and local wind conditions. These derivatives, referred to as mixed derivatives, offer advantages in terms of hedge effe... [more]

Improving mass transfer in gas diffusion layers is critical to achieving high-performance proton-exchange membrane fuel cells (PEMFCs). Leaks through the interface between the gas and the membrane electrode assembly frame have been widely investigated, and the controllability of the cathode gas diffusion has not been achieved in most studies. In this study, we develop a structural parameter to investigate the controllability of the gas diffusion mechanism in the cathode in order to improve upon the design and performance of PEMFCs. This parameter accounts for the cathode gas diffusion layer porosity and carbon loading inside the catalyst layer. It is comprehensively calculated to relax the two segments’ distribution along three directions of the coordinate axis. The experimental and simulation results show that the obtained values of the parameter vary and change during voltage stabilization. According to the results, regardless of the materials in the cathode gas diffusion layer, the... [more]

The relevance of the application of hydraulic thruster technology is determined by the technological limitations of drilling both vertical and horizontal wells. The existing experimental studies confirm the effectiveness of the technology, but its widespread implementation is hindered by the lack of scientific foundations for its operation in combination with a downhole motor and bit. Our research methodology includes methods for analyzing scientific and technical information as well as methods of numerical modeling using programming languages and ready-made software packages for CFD calculations. Verification of the simulation results was carried out on the basis of the experimental field studies previously conducted with the participation of the authors of the article. This article presents the results of the analysis of the current state of the problem and computer physical and mathematical modeling of the work of the thruster together with the bit and downhole motor when drilling a... [more]

The kaolin suspension calcination technology is currently gaining attention as a new process of calcining kaolin. In this paper, the cooling system of the kaolin suspension calcination process designed by CBMI Construction Co., Ltd. is simulated using ANSYS Fluent software to analyze the velocity field and temperature field of the gas−solid two-phase flow using the Eulerian model. A compiled UDF (User-Defined Function) is used to simulate the transfer of mass and heat from the downcomer tube to the different elements. The gas, coming from the gas outlet of the cyclone, enters the next level twin-cylinder cyclone in a spiral state. The results show that the airflow in the cyclone consists of an external spiral flow from the top to the bottom and an internal spiral flow from the bottom to the top. During the downward movement of the airflow, the outer spiral flow is continuously transformed into an inner cyclonic flow. The part of the airflow that rotates close to the inner cylinder is l... [more]

Offshore photovoltaic installations are the future technology in solar energy since they enable the use of the large amount of maritime space, which is especially important when land space is not available. Various research groups are working to create viable installations. However, there are currently no tools available that an offshore system designer can use to quantify the effect of wave response motion on offshore photovoltaic installations. This research presents a new simulation tool termed the Offshore Solar Irradiance Calculator (OSIC) that is able to quantify this effect. Furthermore, a yearly parametric analysis is presented to show the effects of a characteristic wave equation on different offshore tracking systems; namely, horizontal single-axis tracking, vertical single-axis tracking and dual-axis tracking. Finally, another parametric analysis is presented to show the effects of varying wave amplitudes of oscillations on the incident irradiance received by these tracking... [more]

Cyclic ethers (CEs) can be promising future biofuel candidates. Most CEs possess physico-chemical and combustion indicators comparable to conventional fuels, making them suitable for internal combustion engines. This work computationally investigates the kinetic behaviors of hydrogen abstraction from 2-methyl tetrahydrofuran (2MTHF), one of the promising CEs, by hydroxyl radicals under combustion and atmospheric relevant conditions. The various reaction pathways were explored using the CCSD(T)/cc-pVTZ//M06-2X/aug-cc-pVTZ level of theory. The Rice−Ramsperger−Kassel−Marcus-based master equation (RRKM-ME) rate model, including treatments for hindered internal rotation and tunneling, was employed to describe time-dependent species profiles and pressure and temperature-dependent rate coefficients. Our kinetic model revealed that the H-abstraction proceeds via an addition-elimination mechanism forming reaction complexes at both the entrance and exit channels. Eight different reaction channel... [more]

The accurate quantification of the performance loss rate of photovoltaic systems is critical for project economics. Following the current research activities in the photovoltaic performance and reliability field, this work presents a comparative assessment between common change point methods for performance loss rate estimation of fielded photovoltaic installations. An extensive testing campaign was thus performed to evaluate time series analysis approaches for performance loss rate evaluation of photovoltaic systems. Historical electrical data from eleven photovoltaic systems installed in Nicosia, Cyprus, and the locations’ meteorological measurements over a period of 8 years were used for this investigation. The application of change point detection algorithms on the constructed monthly photovoltaic performance ratio series revealed that the obtained trend might not always be linear. Specifically, thin film photovoltaic systems showed nonlinear behavior, while nonlinearities were als... [more]

A simulation model based on Dymola modelling was developed to investigate the dynamic characteristics of automatic generation control (AGC) for variable-load thermal power units in this study. Specifically, a 300 MW unit from a power plant in northern China was used to verify the model’s validity in steady-state processes and to analyze the behavior of the main thermal parameters under different rates of load changes. The economic performance of the unit under different rates of load changes is also analyzed by combining the economic indexes of “two regulations” in the power grid. Results indicate that as the rate of load changes increases, boiler output, main steam temperature, reheat steam temperature, main steam pressure, and working temperatures of various equipment fluctuate more intensely. Specifically, at a rate of load reduction of 2.0% Pe MW/min, the maximum deviation of the main steam temperature can reach 7.6 °C, with the screen-type superheater experiencing the largest heat... [more]

As we move away from internal combustion engines to tackle climate change, the importance of hydrogen-powered vehicles and polymer electrolyte membrane fuel cell (PEMFC) technology has dramatically increased. In the present study, we aimed to determine the optimal configuration for the power output of a PEMFC system using computational fluid dynamics (CFD) modelling to analyse variations of the primary serpentine design of gas flow channels. This helps improve efficiency and save on valuable materials used, reducing potential carbon emissions from the production of hydrogen vehicles. Different numbers of serpentine gas channels were represented with various spacing between them, within the defined CFD model, to optimise the gas channel geometry. The results show that the optimum configuration was found to have 11 serpentine channels with a spacing of 3.25 mm. In this optimum configuration, the ratio between the channel width, channel spacing, and serpentine channel length was found to... [more]

This study discusses the influence of natural wind on the air flow of air-cooled condensers (ACCs) and then proposes a partition speed-regulation strategy for a fan group with enhanced generalized capability, which is of great practical significance for optimizing energy-saving operations. The stochastic time-varying features of natural wind are characterized by sine−Gaussian, Weibull, and composed winds. In a natural wind disturbance, using the Sugon Supercomputing Center, the transient numerical simulation of the dynamic evolution of the ACC flow field was found: the dynamic system of air flow is a typical time-varying nonlinear process. Cluster analysis was used to extract the nonlinear features of air flow, divide the fan group into four subregions with generalization capability, and implement a partitioned speed operation. It was found that giving priority to increasing the fan speed in the headwind partition can suppress the natural wind disturbance and improve the overall air fl... [more]

The permissible speed of suspended monorails in underground mines is determined by the internal regulations of each country and depends on the type of transportation. In the case of passenger transportation, the maximal driving speed in Polish underground mining regulations is 2 ms−1. Regarding the higher permitted driving speed in other countries, it is reasonable to consider changes to these regulations that would raise the permitted speed limit. Increasing the permissible travel speed would improve the efficiency of mining operations because of the significant reduction in the inefficient working time of miners traveling on the monorail from the shaft to their place of work. However, at the same time, an increase in the permissible speed of travel results in higher values of forces and accelerations affecting both the crew riding the train and the underground working infrastructure (the suspended route, slings, and arches yielding support). The results of the series of works carried... [more]

This paper presents a holistic Reynolds-averaged Navier−Stokes (RANS) turbulence modeling framework for the computational fluid dynamics (CFD) simulations of complex wall-bounded turbulent flows. Based on the elliptic relaxation idea, the deployed eddy viscosity turbulence model reconstructs the near-wall stress anisotropy and nonviscous effects. The appropriate selection of the turbulent quantities that are being solved for, together with the zero value wall boundary condition for the related turbulent quantities, renders the model less sensitive to the near-wall grid nonuniformities and resolution. The unified near-wall velocity profile, obtained based on the boundary layer theory, is used to devise the compound near-wall treatment that ensures the robustness of the numerical simulation. The proposed turbulence modeling framework is implemented into the general-purpose open-source CFD code and validated against the generic test cases with satisfactory agreement.

Determination of the heat transfer coefficient (HTC) distribution is important during the design and operation of many devices in microelectronics, construction, the car industry, drilling, the power industry and research on nuclear fusion. The first part of the manuscript shows works describing how a change in the coefficient affects the operation of devices. Next, various methods of determining the coefficient are presented. The most common method to determine the HTC is the use of Newton’s law of cooling. If this method cannot be applied directly, there are other methods that can be found in the open literature. They use analytical formulations, the lumped thermal capacity assumption, the 1D unsteady heat conduction equation for a semi-infinite wall, the fin model, energy conservation and the analogy between heat and mass transfer. The HTC distribution can also be calculated by means of computational fluid dynamics (CFD) modelling if all boundary conditions with fluid and solid prop... [more]