Browse
Subjects
Records with Subject: Materials
Showing records 206 to 230 of 4208. [First] Page: 1 6 7 8 9 10 11 12 13 14 Last
Influence of Insulation Material Thickness on Spread of Thermal Runaway in Battery Packs
Qinghua Bai, Kuining Li, Jianming Zan, Jian Liu, Junfeng Ou, Jiangyan Liu
June 7, 2023 (v1)
Subject: Materials
Keywords: heat insulation thickness, lithium iron phosphate battery, thermal propagation, thermal runaway, triggered by heating
Thermal runaway occasionally happens in batteries. A single battery, after thermal runaway, will release heat and transfer it to neighboring batteries, leading to thermal runaway of battery packs. Thus, it is necessary to explore the diffusion law of thermal runaway in battery modules. Heating is by far the most common way to trigger thermal runaway propagation of battery modules. In this paper, experiments and simulations were conducted to explore the influence of different heat insulation thicknesses on the thermal propagation of lithium iron phosphate batteries, and the result shows that the best thickness between adjacent batteries is 2 mm. For complex modules, the simulation analysis shows that when the spacing between adjacent modules in the battery pack was 10 mm and thermal runaway occurred on one side of the battery pack, it did not occur on the other side for a certain period of time. Therefore, the recommended spacing between modules in the battery pack is 10 mm. This lays a... [more]
Study on the Mechanism and Control of Strong Rock Pressure in Thick Coal Seam Mining under the Goaf of Very Close Multiple Coal Seams
Junwen Feng, Wenmiao Wang, Zhen Wang, Fang Lou, Hongzhi Wang, Rang Wu, Yongyong Jia, Mingchao Yong
June 7, 2023 (v1)
Subject: Materials
Keywords: close-range coal seam group, fracture energy, layered mining, strong rock pressure manifestation
With the increasing proportion of close-distance coal seam mining in China, the problem of strong mining pressure during the mining of close-distance coal seams is becoming more and more severe. This article focuses on the complex stress environment and severe mining pressure encountered in the mining of thick coal seams under the multi-coal-seam goaf of Zhunnan Coal Mine. By using research methods, such as similar material simulation, theoretical analysis, and numerical simulation, it studies in depth the instability characteristics of the overlying rock structure of the W1701 working face, the inducing factors and mechanisms of strong mining pressure during the mining process, and control measures. The results show that the roof structure of the W1701 working face can be divided into “high-level key layer (hard rock)−giant thick soft and weak rock group−low-level key layer (hard rock)”, and the law of mining pressure manifestation presents a small cycle formed by the instability of “... [more]
Fatigue Life and Crack Initiation in Monopile Foundation by Fatigue FE Analysis
Zhen-Ming Wang, Kyong-Ho Chang, Shazia Muzaffer, Mikihito Hirohata
June 7, 2023 (v1)
Subject: Materials
Keywords: fatigue crack initiation, fatigue FE analysis, fatigue life, monopile structure, residual stress
The construction of new renewable energy infrastructures and the development of new ocean resources continues to proceed apace. In this regard, the increasing size and capacity of offshore wind turbines demands that the size of their accompanying supporting marine structures likewise increase. The types of marine structures utilized for these offshore applications include gravity base, monopile, jacket, and tripod structures. Of these four types, monopile structures are widely used, given that they are comparatively easy to construct and more economical than other structures. However, constant exposure to harsh cyclic environmental loads can cause material deterioration or the initiation of fatigue cracks, which can then lead to catastrophic failures. In this paper, a 3D fatigue finite element analysis was performed to predict both the fatigue life and the crack initiation of a welded monopile substructure. The whole analysis was undertaken in three steps. First, a 3D non-steady heat c... [more]
Assessment of Adhesively Bonded Joints of Similar and Dissimilar Materials: Industrial Case Study
Nergizhan Anaç
June 7, 2023 (v1)
Subject: Materials
Keywords: additive manufacturing, adhesive bonding, mechanical properties, rubber-metal buffer
Joining similar or dissimilar materials has recently become a hot topic in industries. In this study, an adhesive technique was used to join plastic materials produced by additive manufacturing (3D printing) with metal materials. The effects of the type of material that forms the joint pairs on the joint strength were investigated. In addition, a case study was carried out on the “rubber-metal buffer” part, which is a rubber industry product. The “rubber-metal buffer” part, traditionally produced by vulcanization, was re-manufactured by changing the body material and production technique. Samples were produced from Tough PLA and TPU materials using a 3D printer at 80% and 100% fill rates. Adhesive joints were made by bonding dissimilar (Tough PLA/Galvanized steel, TPU/Galvanized steel, Tough PLA/TPU) and similar materials (Tough PLA/Tough PLA, TPU/TPU, Galvanized steel/Galvanized steel) using Loctite 9466 adhesive. The mechanical properties of the joints were determined using tensile a... [more]
Combined Utilization of Cylinder and Different Shaped Alumina Nanoparticles in the Base Fluid for the Effective Cooling System Design of Lithium-Ion Battery Packs
Fatih Selimefendigil, Furkan Dilbaz, Hakan F. Öztop
May 26, 2023 (v1)
Subject: Materials
Keywords: cylinder, finite element method, lithium-ion battery pack, nanoparticle shape, thermal management
It is important to consider the thermal management of lithium-ion batteries to overcome their limitations in usage and improve their performance and life cycles. In this study, a novel cooling system for the thermal management of lithium-ion battery packs is proposed by using an inner cylinder in the cooling channel and different-shaped nanoparticles in the base fluid, which is used as the cooling medium. The performance improvements in a 20 Ah capacity battery are compared by using a water−boehmite alumina (AlOOH) nanofluid, considering cylinder-, brick-, and blade-shaped nanoparticles up to a solid volume fraction of 2%. The numerical analysis is conducted using the finite element method, and Reynolds numbers between 100 and 600 are considered. When the efficacy of the coolants utilized is compared, it is apparent that as the Reynolds number increases, both cooling media decrease the highest temperature and homogenize the temperatures in the battery. The utilization of the cylinder i... [more]
Design of an Experimental Approach for Characterization and Performance Analysis of High-Frequency Transformer Core Materials
Daniel van Niekerk, Brydon Schoombie, Pitshou Bokoro
May 24, 2023 (v1)
Subject: Materials
Keywords: characterization jig, efficiency performance, half-bridge converter, high-frequency transformer core material, nanocrystalline, polycrystalline, switching frequency
High-frequency transformer core materials are used in power converter applications due to high efficiency performance. Their volume and weight can be reduced when higher operating frequencies are used but at the expense of an increase in core material losses. Some studies analyzed transformer core material performance by using finite element method (FEM) analysis, while others used an experimental model. This study proposes an experimental approach to compare the high-frequency transformer efficiency performance of different core material types. In this way, newly produced core material performance can be rapidly analyzed by comparing it against a known core material type, thereby resulting in the fast identification of improved core material design. This empirical approach makes use of a standard half-bridge inverter topology to enable an analysis of high-frequency transformer core material efficiency performance. Actual voltage and current measurements are used to determine the effic... [more]
Perspectives of Using Sewage Sludge Char in CO2 Sequestration on Degraded and Brownfield Sites
Marcin Sajdak, Monika Zajemska, Miloud Ouadi, Walter Mucha, Edyta Misztal, Celina Pieszko, Grzegorz Gałko
May 24, 2023 (v1)
Subject: Materials
Keywords: brownfield sites, char, CO2 sequestration, degraded sites, sewage sludge
One of the greatest challenges humankind currently faces is global warming, mainly caused by greenhouse gas emissions. Here we have attempted to show how thermal conversion products, specifically from the pyrolysis of biomass wastes such as sewage sludge, can be used effectively and equivalently to sequester CO2 in brownfield and degraded areas. Scenarios were devised that showed the significant potential for CO2 sequestration in the form of biochar from sewage sludge deposited on degraded and brownfield areas. With the current amount of sludge production, such sludge could even be used in its entirety as a raw material in pyrolysis processes, where, in addition to the biochar, the heat necessary for drying the sludge could be generated and high-energy gas and liquid fractions could be obtained, which could be used to produce alternative fuels. It is therefore important to consider both the potential for CO2 sequestration on degraded and brownfield sites and the potential for sludge di... [more]
Investigating Thermoelectric Batteries Based on Nanostructured Materials
Svyatoslav Yatsyshyn, Oleksandra Hotra, Pylyp Skoropad, Tetiana Bubela, Mykola Mykyichuk, Orest Kochan, Oksana Boyko
May 24, 2023 (v1)
Subject: Materials
Keywords: metallic glass, nanostructured material, thermocouple, thermoelectric battery, thermoelectric generator
This article discusses the characteristics of the design of thermoelectric generators (TEGs) for cold climates. Since the thermocouples of thermoelectric batteries are produced from different materials, their major properties are studied. Particular attention is given to nanostructured materials regarding the modern class of thermoelectric materials. Two-, three-, and four-component alloys (metallic glasses) of the Fe-Ni(Cu)-P-B system are chosen based on the experience of thermoelectric thermometry. The close chemical composition of two thermoelectrodes enables their compatibility in thermocouple production and satisfactory thermoelectric efficiency of batteries during long-term operation. The improvement of the thermoelectric battery characteristics related to a unit of mass is evaluated. The materials studied are distinguished by the absence of toxic components harmful to the environment at the manufacturing and operating stages.
Flow Characteristics of Electrochemical Catalytic Reduction of CO2 in Microchannel
Qingjun Yang, Rizhi Dong, Rui Zhu, Shangru Yang, Wen Xie
May 24, 2023 (v1)
Subject: Materials
Keywords: gas-liquid two-phase flow, microfluidic reaction device, photoelectrocatalysis, transfer coefficient
Human beings need abundant material support and energy supply in their exploration of the universe. The sustainable supply of materials is an important condition for long-term space exploration. In situ resource utilization technology (ISRU) is an important way to realize the sustainable development of space exploration, which uses the abundant raw materials in outer space to transform energy and materials. In this paper, a microfluidic reaction device based on in situ resource utilization is designed, which converts H2O and CO2 into O2 and organic matter through photoelectrocatalysis. The flow and mixing process of gas-liquid two-phase flow was studied, and both the characteristics of mass transfer and the chemical reaction of fluids in the microchannel were studied. The dynamic process of the fluid-in-microchannel chemical reaction was expounded, and a prediction model of the volumetric mass transfer coefficient was proposed. The results show that the mass transfer coefficient of the... [more]
Reducing Soot Nanoparticles and NOX Emissions in CRDI Diesel Engine by Incorporating TiO2 Nano-Additives into Biodiesel Blends and Using High Rate of EGR
Mohammed A. Fayad, Mohammed Sobhi, Miqdam T. Chaichan, Tawfik Badawy, Wisam Essmat Abdul-Lateef, Hayder A. Dhahad, Talal Yusaf, Wan Nor Roslam Wan Isahak, Mohd S. Takriff, Ahmed A. Al-Amiery
May 24, 2023 (v1)
Subject: Materials
Keywords: castor oil, EGR, NOX emissions, soot nanoparticles, TiO2 nano-additives
The developments in the field of nano-additives have increased in the recent years due to the desire to reduce the level of exhaust emissions in diesel engines. The soot characteristics of particulate matter (PM) and nitrogen oxides (NOX) were experimentally investigated using two concentrations of titanium dioxide (TiO2) as nano-additives (25 ppm and 40 ppm) blended with C20D (composed of 20% castor oil methyl ester and 80% diesel fuel) and 30% exhaust gas recirculation (EGR). The combustion of C20D + TiO2 increases brake thermal efficiency (BTE) by 2.8% in comparison with neat C20D, while a significant reduction was obtained in BSFC 6.5% and NOX emissions were maintained at a level parallel with diesel. The results indicated that the technique involving a high EGR rate and the addition of 25 ppm and 40 ppm of TiO2 nanoparticles to the C20D exhibits better reductions in NOX emissions by 17.34% and 21.83%, respectively, compared to the technique comprising the use of C20D + TiO2 and C2... [more]
Circular Economy in Wastewater Treatment Plant—Water, Energy and Raw Materials Recovery
Marzena Smol
May 24, 2023 (v1)
Subject: Materials
Keywords: CE, circular economy, Energy, phosphorus, raw materials, Wastewater, wastewater treatment plant, Water, WWTP
Nowadays, the main challenge for industrial and municipal enterprises is related to the tightening regulations and recommendations regarding environmental protection, which have been included in the circular economy (CE) package. Enterprises from all sectors, including water and sewage management, are obliged to actively participate in the CE transition. Modern wastewater treatment plants (WWTPs) should include actions aimed at a more sustainable use of available resources (water, energy, raw materials) to contribute to the protection of natural resources. In this way, they can be treated as resource facilities. This paper proposes a conceptual framework for a ‘Wastewater Treatment Plant of the Future’ that includes several technological solutions that take into account circular management of waste streams generated in WWTPs, such as wastewater (WW), sewage sludge (SS) and sewage sludge ash (SSA). Many actions have been already taken to modernize and build WWTPs that can respond to cur... [more]
Review of Hysteresis Models for Magnetic Materials
Gustav Mörée, Mats Leijon
May 24, 2023 (v1)
Subject: Materials
Keywords: Coleman–Hodgdon model, Congruency model, Duhem model, electrical steel models, hysteresis models, Jiles–Atherton model, Madelung’s rules, magnetic material, magnetization models, phenomenological models, Preisach model, rate-dependent model, rate-independent model, Tellinen model
There are several models for magnetic hysteresis. Their key purposes are to model magnetization curves with a history dependence to achieve hysteresis cycles without a frequency dependence. There are different approaches to handling history dependence. The two main categories are Duhem-type models and Preisach-type models. Duhem models handle it via a simple directional dependence on the flux rate, without a proper memory. While the Preisach type model handles it via memory of the point where the direction of the flux rate is changed. The most common Duhem model is the phenomenological Jiles−Atherton model, with examples of other models including the Coleman−Hodgdon model and the Tellinen model. Examples of Preisach type models are the classical Preisach model and the Prandtl−Ishlinskii model, although there are also many other models with adoptions of a similar history dependence. Hysteresis is by definition rate-independent, and thereby not dependent on the speed of the alternating f... [more]
Phase Change Material Composite Battery Module for Thermal Protection of Electric Vehicles: An Experimental Observation
Alexander C. Budiman, Brian Azzopardi, Sudirja, Muhammad A. P. Perdana, Sunarto Kaleg, Febriani S. Hadiastuti, Bagus A. Hasyim, Amin, Rina Ristiana, Aam Muharam, Abdul Hapid
May 24, 2023 (v1)
Subject: Materials
Keywords: battery thermal management system, composites, electric vehicles, heat storage, latent heat, temperature uniformity
A composite container for an electric vehicle (EV) battery module filled with a phase-change material (PCM) was experimentally tested at various discharge rates. The average cell temperatures at 1 C, 2 C, and 4 C discharge rates, respectively, might reach 38 °C, 50 °C, and 70 °C in the absence of any heat-absorbing material. The temperature was noticeably lower with PCM present than with a conventional battery module. For instance, at 4 C discharge rates, none of the battery cells inside the PCM-filled module were able to reach 70 °C. Unfortunately, the PCM addition also degraded the composite’s tensile qualities. Further investigations used Paraffin-20 and Caprylone since PCMs provide a notably different thermal performance due to their distinctive latent heat profiles. It was observed that a high melting temperature of the paraffin mixture, despite its slightly lower latent heat capacity compared to Caprylone, could lead to a more uniform temperature. Overall, both PCMs can be used a... [more]
A Modeling Framework to Develop Materials with Improved Noise and Vibration Performance for Electric Vehicles
Seyed Jamaleddin Mostafavi Yazdi, Seongchan Pack, Foroogh Rouhollahi, Javad Baqersad
May 24, 2023 (v1)
Subject: Materials
Keywords: damping, electric vehicles, finite element analysis, lightweight, NVH, vibration
The automotive and aerospace industries increasingly use lightweight materials to improve performance while reducing fuel consumption. Lightweight materials are frequently used in electric vehicles (EVs). However, using these materials can increase airborne and structure-borne noise. Furthermore, EV noise occurs at high frequencies, and conventional materials have small damping. Thus, there is an increasing need for procedures that help design new materials and coatings to reduce the transferred and radiated noise at desired frequencies. This study pioneered new techniques for microstructure modeling of coated and uncoated materials with improved noise, vibration, and harshness (NVH) performance. This work uses the microstructure of materials to study their vibration-damping capacity. Images from an environmental scanning electron microscope (ESEM) show the microstructure of a sample polymer and its coating. Tensile tests and experimental modal analysis were used to obtain the material... [more]
MOF-801/Graphene Adsorbent Material for Greenhouse Climate Control System—Numerical Investigation
Andrew N. Aziz, Raya Al-Dadah, Saad Mahmoud, Mohamed A. Ismail, Mohammed K. Almesfer, Marwa F. El-Kady, Hassan Shokry
May 24, 2023 (v1)
Subject: Materials
Keywords: Adsorption, COMSOL, Matlab, Modelling, MOF-801/Graphene, Simulation
Greenhouses with efficient controlled environment offer a promising solution for food security against the impacts of increasing global temperatures and growing water scarcity. However, current technologies used to achieve this controlled environment consume a significant amount of energy, which impacts on operational costs and CO2 emissions. Using advanced metal organic framework materials (MOFs) with superior water adsorption characteristics, this work investigates the development of a new technology for a greenhouse-controlled environment. The system consists of MOF coated heat exchanger, air to air heat exchanger, and evaporative cooler. A three-dimensional computational fluid dynamics (CFD) model was developed using COMSOL software and experimentally validated for the MOF-801/Graphene coated heat exchanger (DCHE) to determine the best cycle time and power input. It was found that using desorption time of 16 min and power input of 1.26 W, the maximum water removal rate was obtained... [more]
The Material Entropy and the Fourth Law of Thermodynamics in the Evaluation of Energy Technologies of the Future
Aleksander Jakimowicz
May 24, 2023 (v1)
Subject: Materials
Keywords: controlled fusion energy, energetic dogma, entropic debt, entropy of matter, flow–fund model, fourth law of thermodynamics, nuclear fission energy, Promethean recipe, solar energy, viability of energy technology
The primary purpose of this article is to use the laws of thermodynamics, mainly the second and fourth laws, to evaluate three energy technologies of the future: fusion, solar, and fission. Among the criteria used to evaluate them, the most important are the amount of matter needed to sustain the technology itself and the environmental impact. Much emphasis is placed here on the fourth law of thermodynamics, which introduces the concept of material entropy. Zemansky−Georgescu-Roegen’s Law of Inevitable Dissipation of Useful Concentrated Matter states that, in the economic process, some matter is inevitably degraded and becomes unavailable matter. This has tremendous implications for humanity as a whole since the Earth is thermodynamically a closed system, meaning that it cannot exchange matter with space but is open to the flow of solar energy. This results in the need to conserve matter and natural resources. This law can be used as an important criterion for the selection of energy t... [more]
Performance of Mn-Ce-Fe/FA Catalysts on Selective Catalytic Reduction of NOX with CO under Different Atmospheres
Zheng Xia, Ruiping Zhang, Jixin Duan, Yanxing Liu, Zhengyuan Li, Xiang Gou
May 24, 2023 (v1)
Subject: Materials
Keywords: catalyst, CO-SCR, fly ash, nitrogen oxides
Gas turbines produce a large amount of NOx and CO due to high temperatures and insufficient combustion. Through the selective catalytic reduction of NO with CO (CO-SCR) in a gas turbine, the activities of the Mn-Fe-Ce/FA catalyst using fly ash (FA) as a carrier under different atmospheres were studied. The catalysts prepared by calcining different active materials under different atmospheres were used to analyze their denitrification abilities and resistance to water vapor. The denitrification performance of the catalyst prepared under reducing atmosphere is about 30 percent higher than that of the catalyst prepared under air atmosphere, and the decarburization performance is about 40 percent higher. In the presence of oxygen, the denitrification rate and decarburization rate of the 1:1 ratio of the Mn-Ce catalyst reach 67.16% and 59.57%, respectively. In an oxygen-containing atmosphere, the catalyst prepared by replacing Ce with Fe shows better denitrification and decarburization perf... [more]
Recent Trends in Additive Manufacturing and Topology Optimization of Reluctance Machines
Shahid Hussain, Ants Kallaste, Toomas Vaimann
May 23, 2023 (v1)
Subject: Materials
Keywords: additive manufacturing, binder jetting, Genetic Algorithm, level set, material density, ON-OFF method, power bed fusion, soft magnetic materials, switch reluctance machine, synchronous reluctance machine, topology optimization
Additive manufacturing (AM) or 3D printing has opened up new opportunities for researchers in the field of electrical machines, as it allows for more flexibility in design and faster prototyping, which can lead to more efficient and cost-effective production. An overview of the primary AM techniques utilized for designing electrical machines is presented in this paper. AM enables the creation of complex and intricate designs that are difficult or impossible to achieve using traditional methods. Topology Optimization (TO) can be used to optimize the design of parts for various purposes such as weight, thermal, material usage and structural performance. This paper primarily concentrates on the most recent studies of the AM and TO of the reluctance machines. The integration of AM with TO can enhance the design and fabrication process of magnetic components in electrical machines by overcoming current manufacturing limitations and enabling the exploration of new design possibilities. The t... [more]
A Low-Density Polyethylene-Reinforced Ternary Phase-Change Composite with High Thermal Conductivity for Battery Thermal Management
Yueliang Yu, Hongmei Qin, Shusen Ran, Jinhui Song, Wenlai Xia, Shan Wang, Chuanxi Xiong
May 23, 2023 (v1)
Subject: Materials
Keywords: battery thermal management, expanded graphite, low-density polyethylene, paraffin, phase change material, thermal conductivity
Paraffin phase change materials (PCMs) exhibit great potential in battery thermal management (BTM); nevertheless, their application has been hampered by the handicap of low thermal conductivity, leakage, and volume expansion during phase transition. In this work, ternary composite PCMs formed of paraffin, expanded graphite (EG), and low-density polyethylene (LDPE) were developed for application in BTM. The structure and properties of the composite PCMs were characterized via X-ray diffraction, scanning electron microscopy, differential scanning calorimetry, and thermal constant analysis. The result shows that EG can form a large-size graphite frame as heat conduction paths to improve the thermal conductivity of the composite PCM, and LDPE can form an interpenetrating network within the composite PCM to resist the internal stress of paraffin expansion and prevent deformation. The latent heat and thermal conductivity of the composite PCMs loaded with 10 wt% EG and 4 wt% LDPE can reach 17... [more]
Preliminary Results of Heat Transfer and Pressure Drop Measurements on Al2O3/H2O Nanofluids through a Lattice Channel
Sandra Corasaniti, Michele Potenza, Ivano Petracci
May 23, 2023 (v1)
Subject: Materials
Keywords: 3D printing lattice channel, additive manufacturing, convective heat transfer, nanofluids, periodic cellular material
A nanofluid is composed of a base fluid with a suspension of nanoparticles that improve the base fluid’s thermophysical properties. In this work, the authors have conducted experimental tests on an alumina-based nanofluid (Al2O3/H2O) moving inside a 3D-printed lattice channel. The unit cell’s lattice shape can be considered a double X or a double pyramidal truss with a common vertex. The test channel is 80 mm long and has a cross-sectional area, without an internal lattice with that has the dimensions H × W, with H = 5 mm and W = 15 mm. A nanofluid and a lattice duct can represent a good compound technique for enhancing heat transfer. The channel is heated by an electrical resistance wound onto its outer surface. The heat transfer rate absorbed by the nanofluid, the convective heat transfer coefficients, and the pressure drops are evaluated. The experimental tests are carried out at various volumetric contents of nanoparticles (φ = 1.00%, φ = 1.50% and φ = 2.05%) and at various volumet... [more]
Characterization of the Hydropower Inlet Effect on the Electric Network Frequency
Jesús Álvarez-Higueruela, Francisco-José Gutiérrez-Villalba, José-María Sierra-Fernández, Juan-José González-de-la-Rosa, Olivia Florencias-Oliveros, José-Carlos Palomares-Salas, Agustín Agüera-Pérez, Manuel-Jesús Espinosa-Gavira
May 23, 2023 (v1)
Subject: Materials
Keywords: correlation power frequency, frequency stability, hydropower, power quality analysis
One of the challenges posed by renewable energies is the stabilization of parameters related to the quality of electrical energy. This study demonstrates the existence of a relationship between input blocks of hydropower and the variation of the fundamental frequency of the electricity grid. By mapping production data provided by the Spanish Electric Network with frequency measured in the laboratory, it is shown that gradients of hydropower are correlated with frequency fluctuations for certain characteristic times. Considering hourly instances of energy input, the study compares two methods for calculating hydropower gradients (linear regression and pseudo-linear regression) and two methods for calculating local frequency extrema (the “specular inertia” method and analysis by comparison with the moving average) in order to corroborate the results.
Honeycomb-like Hierarchical Porous Carbon from Lignosulphonate by Enzymatic Hydrolysis and Alkali Activation for High-Performance Supercapacitors
Xin Zhang, Shi Liu, Yuqi Zhao, Haicun Yang, Jinchun Li
May 23, 2023 (v1)
Subject: Materials
Keywords: alkali activation, calcium lignosulfonate, enzymatic hydrolysis, hierarchical porosity, supercapacitors
Porous carbon materials (PCs) were prepared via hydrothermal carbonization from calcium lignosulfonate (CL) based on enzymatic hydrolysis and alkali activation. The effects of enzymatic hydrolysis and different KOH feeding ratios on the structure and electrochemical properties of enzymatic hydrolysis CL (EHCL)-derived PCs were evaluated in detail. The results showed that the EHCL-derived PCs showed a higher SSA than that of CL. When the mass ratio of KOH/EHCL was 3/2, the PCs exhibited a honeycomb-like microscopic morphology with a specific surface area of up to 1771 m2/g and a 3D hierarchical porous structure composed of abundant micropores, mesopores, and macropores. As an electrode in a supercapacitor, the highest specific capacitance was 147 F/g at a current density of 0.25 A/g, and it maintained 78% of the initial value at a high current density of 10 A/g. The excellent electrochemical cycle and structural stability were confirmed on the condition of a higher capacitance retention... [more]
Pore Structure and Fractal Characteristics of Coal-Measure Sedimentary Rocks Using Nuclear Magnetic Resonance (NMR) and Mercury Intrusion Porosimetry (MIP)
Na Zhang, Shuaidong Wang, Xingjian Xun, Huayao Wang, Xiaoming Sun, Manchao He
May 23, 2023 (v1)
Subject: Materials
Keywords: coal-measure sedimentary rocks, mercury intrusion porosimetry (MIP), multifractal dimensions, nuclear magnetic resonance (NMR), pore structure
Analyzing and mastering the fractal features of coal-measure sedimentary rocks is crucial for accurately describing the pore structure of coalbed methane resources. In this work, mercury intrusion porosimetry (MIP) and nuclear magnetic resonance (NMR) are performed on coal-measure sedimentary rocks (i.e., shale, mudstone, and sandstone) to analyze their pore structure. Pore size distributions (PSDs) and the multifractal dimensions of the investigated samples are discussed. Moreover, multivariable linear regression models of multifractal dimensions are established through a comprehensive analysis of multifractal characteristics. The results show that sandstone (SS-1) and clay rocks are dominated by nanopores of 0.01 to 1 μm, while sandstone (SS-2) is mostly mesopores and macropores in the range of 1 to 10 μm. The fractal characteristics of the investigated rock samples show a prominent multifractal characteristic, in which DA reflects the surface structure of micropores, while DS repres... [more]
Geochemical and Microstructural Characteristics of Clay Minerals and Their Effects on the Pore Structure of Coal-Measure Shale: A Case Study in Qinshui Basin, China
Kunjie Li, Shaoqi Kong, Yanxia Liang, Muhammad Ali, Yongfa Zhang, Yuqiong Zhao
May 23, 2023 (v1)
Subject: Materials
Keywords: clay minerals, coal-measure shale, compaction, kaolinite, pore structure
As the essential component of shale, clay minerals have a vital influence on the pore structure and the gas content of reservoirs. To investigate the compositional characteristics of coal-measure shale and its effects on pore structure, a total of thirteen Taiyuan formation shale samples were collected from the Qinshui Basin and were analyzed using a combination of X-ray diffraction analysis, X-ray fluorescence spectrometry, Fourier transform infrared spectroscopy (FE-SEM), polarized optical microscopy, and field emission scanning electron microscopy. The results show that the principal minerals of the samples are quartz, kaolinite, and illite. Most of the kaolinite was an original terrigenous detrital material with low crystallinity and a low degree of ordering, whereas the illite was mainly composed of 1Md resulting from diagenesis. Clay minerals developed slits, irregularly-shaped or multisized pores during diagenesis, which can be classed into interlayered pores, intergranular pore... [more]
Analysis of a Phase Change Material-Based Condenser of a Low-Scale Refrigeration System
Augusto Cavargna, Luigi Mongibello, Marcello Iasiello, Nicola Bianco
May 23, 2023 (v1)
Subject: Materials
Keywords: experimental validation, numerical modeling, phase change materials, refrigeration system
This study concerns the numerical simulation and the experimental implementation of a low-scale Phase Change Material-based (PCM-based) condenser, to be included in a PCM-based portable cooling systems. In this category of cooling systems, the PCM can be integrated either in the condenser or in the evaporator. In the present study, the PCM is integrated in the condenser of the vapor compression cycle to absorb the heat power released from the refrigerant fluid (R134a) during condensation, thus eliminating the need to transfer heat to the external environment. The main objective of the present study is to realize and validate a numerical model capable of simulating both the refrigerant fluid and the PCM thermofluid dynamics. For this purpose, a commercial solver was used for the implementation of the developed numerical model, and experimental tests were performed to validate the numerical simulations results. The paper reports the details and test results of both the numerical model an... [more]
Showing records 206 to 230 of 4208. [First] Page: 1 6 7 8 9 10 11 12 13 14 Last
[Show All Subjects]