The objective of the study is to investigate the thermal, electrical, and exergetic performance of a hybrid photovoltaic−thermal (PVT) system under the influence of copper oxide (CuO) nanofluid and phase change material (Vaseline (petroleum jelly)) as a heat storage medium. A mathematical model was developed with the help of various energy-balance equations over the layers of the hybrid system. The performance evaluation of the PVT system was performed using pure water, CuO-water nanofluid (0.2 and 0.4% weight fractions), and CuO-water nanofluid 0.4% weight fraction with Vaseline as a phase change material. The results of the overall analysis show that the performance of the PVT system is better using CuO-water nanofluid (0.4% wt. fraction) with PCM as compared to the water-cooled PVT system and CuO-water nanofluid. The results obtained from the study show indicate that the cell temperature of PVT was reduced by 4.45% using nanofluid cooling with PCM compared to a water-cooled PVT syst... [more]

This study presents the analysis of the exergy load distribution in a separation process by extractive distillation for ethanol dehydration. The methodology carried out is divided into three parts: the calculation of the flow exergy considering the physical and chemical exergies of the distillation process; the calculation of the primary and transformed exergy contributions considering the consumed exergy; and finally, the overall process efficiency, which shows the real percentage of energy being used in the process. The simulation of an extractive distillation separation system is carried out using Aspen Plus®, from Aspen Tech Version 9. In general, heat transfer processes (heating or cooling) are the ones that generate the greatest exegetic destruction, which is why they must be the operations that must be optimized. As a result of our case study, the local exergy efficiency of the extractive distillation column is 13.80%, which is the operation with the greatest energy loss, and th... [more]

To strike a better balance between gas quality and production cost of biomass-based syngas, a process for high-safety and cost-effective syngas production is designed and studied, which takes advantage of biomass O2-enriched air gasification with 40−70% O2 purity and methanation synthesis. Based on the simulation data, the process is evaluated from techno-economic aspects, including syngas composition, higher heat value (HHV), upper and lower explosive limits (UEL and LEL), toxicity, unit production cost (UPC) and levelized cost of energy (LCOE). Five kinds of biomass are studied as feedstock. The effects of O2 purity, methanation pressure, feedstock cost, and plant scale are determined, respectively. The results show that O2 purity is an important parameter for technical performance, while methanation pressure is a minor parameter except for exergy efficiency. With respect to cost indicators, feedstock cost, and plant scale are crucial variables; by contrast, O2 purity plays a relativ... [more]

Combustion processes continue to be essential for the energy supply sector. A reliable energetic evaluation of these processes is crucial, particularly since the pollutants resulting from combustion have a significant impact on global warming. This work evaluates a combustion using the exergetic evaluation and the Physical Optimum (PhO) as it is described in VDI-Guideline 4663. Differences between PhO and exergy are investigated, allowing a distinct differentiation and examining the PhO’s added value in combustion analysis. Based on the evaluation of a simulated methane combustion, this paper shows that the PhO-Factor may be used to evaluate combustion processes. However, it shows that the PhO of a combustion process is a simplification of this fuels exergy and does not provide advantages to the exergy evaluation. Nevertheless, an adaption of the PhO is not carried out in the context of this work since the minimal deviation of the simulated energy indicators currently cannot justify an... [more]

A numerical analysis of a photovoltaic-thermal (PVT) hybrid system with different cooling configurations is developed. The PVT system consists mainly of a photovoltaic panel and cooling fluid channels. The developed model is used to simulate the system PVT and to study the influence of different cooling patterns, operating and weather conditions on the system performance and to evaluate its energy and exergy efficiency. Five cooling patterns were tested: the first is cooled by air above the panel and water below the panel; the second is air cooling from above and below; the third is cooled by air above the panel only; the fourth is cooled by air below the panel only; and the fifth is cooled by water below the panel only. It was shown that the results of the developed model are consistent with the results of other published works. The performance of the PVT system was analyzed under the weather conditions of Sakaka Al-Jouf, KSA, in summer and winter. It was found that the best cooling p... [more]

Cryogenic air separation processes are widely used for the large-scale production of nitrogen and oxygen. The most widely used design for this process involves two distillation columns operating at different pressures. This work focuses on the selection of suitable cryogenic air separation process by evaluating seven alternative designs of the two-column air separation process based on detailed exergy analysis. The feed conditions (500 tons/h, and 50% relative humidity of air), product purities (99 mole% for both nitrogen and oxygen), and operational conditions (pressures of both distillation columns) are kept same in all designs. The two cryogenic distillation columns in each configuration are heat-integrated to eliminate the need for external utilities. Steady-state simulation results are used to calculate the exergy efficiency (%) of each equipment as well as its contribution toward the overall exergy destruction rate (kW) of the process. The results show that the compression sectio... [more]

The article describes a method of integrating small distributed generation components in the power system of the Republic of Vietnam. The features of the energy system of Vietnam and the technologies used for mini thermal power plants are considered. The classification of small distributed generation components is presented with implantation of the most used resources of Vietnam—fossil and renewable. A generalized methodology for selection and calculation of technological schemes for mini thermal power plants is considered. The schemes of steam-turbine mini thermal power plants operating with coal and gas-turbine mini thermal power plants with solar air heaters are selected. Based on the calculation of the selected mini thermal power plant schemes, their distribution in the territory of the Republic of Vietnam has been obtained. The thermoeconomic efficiency has been chosen as the criterion for the best option for placing mini thermal power plants; its value for the proposed option is... [more]

As an important part of a micro-compressed air energy storage system, the scroll expander directly affects the efficiency of the whole energy storage system. The effects of resistance on the efficiency of scroll expander caused by inlet structure and size are discussed with theory analysis and experimental methods in this paper. Micro-compressed air energy storage system has aroused widespread attention because of its pollution-free, high flexibility, in the community, remote areas power supply. Comprehensive experimental work with the selections of different size and structure of the air inlet of the scroll expander was performed with the cutting angle of air inlet chamber of the scroll expander. The results of the experiments are discussed on how exergy efficiency and inlet flow of the scroll expander were affected resulting from the cutting angles dissected. The results show that a maximum value exists for exergy efficiency of the scroll expander. Therefore, the exergy efficiency of... [more]

This study analyzes the thermodynamic, economic, and regulatory aspects of boil-off hydrogen (BOH) in liquid hydrogen (LH2) carriers that can be re-liquefied using a proposed re-liquefaction system or used as fuel in a fuel cell stack. Five LH2 carriers sailing between two designated ports are considered in a case study. The specific energy consumption of the proposed re-liquefaction system varies from 8.22 to 10.80 kWh/kg as the re-liquefaction-to-generation fraction (R/G fraction) is varied. The economic evaluation results show that the cost of re-liquefaction decreases as the re-liquefied flow rate increases and converges to 1.5 $/kg at an adequately large flow rate. Three energy efficient design index (EEDI) candidates are proposed to determine feasible R/G fractions: an EEDI equivalent to that of LNG carriers, an EEDI that considers the energy density of LH2, and no EEDI restrictions. The first EEDI candidate is so strict that the majority of the BOH should be used as fuel. In the... [more]

In order to fully understand the energy and exergy transfer processes in sinter vertical coolers, a simulation model of the fluid flow and heat transfer in a vertical cooler was established, and energy and exergy efficiency analyses of the gas−solid heat transfer in a vertical cooler were conducted in detail. Based on the calculation method of the whole working condition, the suitable operational parameters of the vertical cooler were obtained by setting the net exergy efficiency in the vertical cooler as the indicator function. The results show that both the quantity of sinter waste heat recovery (SWHR) and energy efficiency increased as the air flow rate (AFR) increased, and they decreased as the air inlet temperature (AIT) increased. The increase in the sinter inlet temperature (SIT) resulted in an increase in the quantity of SWHR and a decrease in energy efficiency. The air net exergy had the maximum value as the AFR increased, and it only increased monotonically as the SIT and AIT... [more]

Designing the most efficient parabolic trough solar collector (PTSC) is still a demanding and challenging research area in solar energy systems. Two effective recommended methods for this purpose that increase the thermal characteristics of PTSCs are adding turbulators and nanofluids. To study the effects of the two approaches on the energy efficiency of PTSCs, a stainless steel turbulator was used and solid nanoparticles of Cu/SBA-15 were added to the water with the volume concentrations of 0.019% to 0.075%. The generated turbulence in the fluid flow was modeled by the SST k−ω turbulent model. The results in daylight demonstrated that energy efficiency increases steadily by 11:30 a.m., and then, starts to drop gradually due to more irradiations at noon. It was observed that applying the turbulator to the studied PTSC has a significant influence on the enhancement of energy efficiency. Adding the nanoparticles augmented the average Nusselt number inside the solar collector in various s... [more]

The utilization of solar irradiation in the building sector is vital to create sustainable systems. Trigeneration systems are highly efficient systems that usually produce electricity, heating and cooling which are the main energy needs in the buildings. The objective of this work is the energetic and financial investigation of three different solar-driven trigeneration systems that can be applied in buildings with high energy needs (e.g., hospitals or commercial buildings). The parabolic trough solar collector (PTC) is selected to be used because it is the most mature solar concentrating technology. The examined configurations practically are different combinations of organic Rankine cycle (ORC) with heat pumps. System 1 includes a PTC coupled to an ORC which feeds an absorption heat pump machine. System 2 includes a PTC which simultaneously feeds an ORC and absorption machine. System 3 includes a PTC which feeds an ORC and a heat exchanger for heating, while the ORC is fed with and e... [more]

This study dealt with evaluating the (J85-GE-5H) military turbojet engine (TJE) in terms of exergetic and advanced exergetic analyses at Military (MIL) and Afterburner (AB) process modes by utilizing kerosene (JP-8) and hydrogen (H2) fuels. First, exergy and advanced exergy analyses of the engine were performed using JP-8 fuel as per actual engine operating conditions. These analyses of the turbojet engine using hydrogen fuel were also examined parametrically. The performance evaluation of the engine was lastly executed by comparing the obtained results for both fuels. Based on the parametric studies undertaken, the entire engine’s exergetic efficiency with JP-8 was reckoned 30.85% at the MIL process mode while it was calculated as 16.98% at the AB process mode. With the usage of H2, the efficiencies of the engine decreased to 28.62% and 15.33% for the above mentioned two modes, respectively. As the supreme exergy destructions occurred in the combustion chamber (CC) and afterburner exh... [more]

This study performs energetic and exergetic comparisons between the steam methane reforming and steam methanol reforming technologies combined with HT-PEMFC and a carbon capture/liquefaction system for use in hydrogen-fueled ships. The required space for the primary fuel and captured/liquefied CO2 and the fuel cost have also been investigated to find the more advantageous system for ship application. For the comparison, the steam methane reforming-based system fed by LNG and the steam methanol reforming-based system fed by methanol have been modeled in an Aspen HYSYS environment. All the simulations have been conducted at a fixed Wnet, electrical (475 kW) to meet the average shaft power of the reference ship. Results show that at the base condition, the energy and exergy efficiencies of the methanol-based system are 7.99% and 1.89% higher than those of the methane-based system, respectively. The cogeneration efficiency of the methane-based system is 7.13% higher than that of the methan... [more]

The competition and interlinkages between energy, water, and land resources are increasing globally and are exacerbated by climate change and a rapid increase in the world population. The nexus concept has emerged for a comprehensive understanding related to the management and efficiency of resource use. This paper assesses water−energy−land nexus (WELN) efficiency through integration of the principles of Life Cycle Assessment (LCA) and exergy analysis, using the Chilean energy sector (CES) as a study case. The cumulative exergy consumption (CExC) and cumulative degree of perfection (CDP) are used as indicators for WELN efficiency. The results show the production of 1 MWh of electricity required 17.3 GJex, with the energy component of WELN (fossil and renewable energy sources) being the main contributor (99%). Furthermore, the renewable energy technologies depicted higher CDP of the water−energy−land nexus due to lower CExC and higher technology efficiency concerning non-renewables. Th... [more]

To optimize the performance of the transcritical CO2 two-stage compression refrigeration system, the energy analysis and the exergy analysis are conducted. It is found that higher COP, lower compression power, and less exergy destruction can be achieved when the auxiliary gas cooler is applied. Moreover, the discharge temperature of the compound compressor (HPS) can be reduced by decreasing the temperature at the outlet of the auxiliary gas cooler (Tagc,out). When the Tagc,out is reduced from 30 to 12 °C, the discharge temperature of the compound compressor (HPS) can be decreased by 13.83 °C. Furthermore, the COP and the exergy efficiency can be raised by enhancing the intermediate pressure. Based on these results, the optimizations of system design and system operation are put forward. The application of the auxiliary gas cooler can improve the performance of the transcritical CO2 two-stage compression refrigeration system. Operators can decrease the discharge temperature of the compo... [more]

The microporous layer (MPL) constitutes a critical component of the gas diffusion layer within the membrane electrode assembly (MEA) of a proton exchange membrane fuel cell (PEM FC). The MPL plays a fundamental role in various processes during FC operation: control of membrane humidification, heat distribution throughout the MEA, excess water removal from the cathode, and transportation of fuel to the reaction sites. Previously, we investigated the performance of a fuel cell unit employing an MPL based on laser-induced graphene (LIG) produced by the laser pyrolysis of polymeric (polyimide) substrates. The prototype LIG-based unit was tested over the typical range of relative humidity and temperature conditions. The polarization curves observed in that study displayed broad ohmic loss regions and high stability along the concentration loss regions, an interesting electrical behavior that justified developing the present voltage-current density study for the same FC prototype compared to... [more]

A three-electrode alternating current fused magnesia furnace (AFMF) with advanced control technology was evaluated by combined energy and exergy analysis. To gain insight into the mass flow, energy flow and exergy efficiency of the present fused magnesia furnace, the exergy destruction was analysed to study the energy irreversibility of the furnace. Two different production processes, the magnesite ore smelting process (MOP) and light-calcined magnesia process (LMP), are discussed separately. Two methods were carried out to improve LMP and MOP; one of which has been applied in factories. The equipment consists of an electric power supply system, a light-calcined system and a three-electrode fused magnesia furnace. All parameters were tested or calculated based on the data investigated in industrial factories. The calculation results showed that for LMP and MOP, the mass transport efficiencies were 16.6% and 38.3%, the energy efficiencies were 62.2% and 65.5%, and the exergy destruction... [more]

This paper examines the exergy efficiency and exergy destruction rate of the R744/R404A cascade refrigeration system (CRS) using an internal heat exchanger in supermarkets according to various conditions affecting the system. A refrigerant of a low-temperature cycle uses R744 and a refrigerant of a high-temperature cycle in the CRS uses R404A. Experiments were conducted by changing various conditions on the high- and low-temperature side, and exergy analysis was performed accordingly. The main results are summarized as follows: (1) the lower the total exergy destruction rate of the CRS, the higher the exergy efficiency of the system, and accordingly the coefficient of performance (COP) of the system is also improved. (2) In the CRS, since the optimum cascade evaporation temperature exists (about −16 °C), it can be said that the limit point, that is, the cascade evaporation temperature with the maximum COP of the system, is the optimum point at about −16 °C. Therefore, at this optimum p... [more]

The heat pump system has been widely used in residential and commercial applications due to its attractive advantages of high energy efficiency, reliability, and environmental impact. The massive exergy loss during the isenthalpic process in the expansion valve is a major drawback of the heat pump system. Therefore, the Tesla turbine exergy analysis in terms of transiting exergy efficiency is investigated and integrated with the transcritical heat pump system. The aim is to investigate the factors that reduce exergy losses and increase the coefficient of performance and exergy efficiency. The contribution of this paper is twofold. First, a three-dimensional numerical analysis of the supercritical CO2 flow simulation in the Tesla turbine in three different geometries is carried out. Second, the effect of the Tesla turbine on the coefficient of performance and exergy efficiency of the heat pump system is investigated. The effect of the rotor speed and disk spacing on the Tesla turbine po... [more]

Bio-hydrogen from residual biomass may involve energy-intensive pre-treatments for drying and size management, as in the case of wet agro-industrial residues. This work assesses the performance of an alternative process layout for bio-hydrogen production from citrus peel gasification, with the aim of cogenerating heat and power along with hydrogen, using minimal external energy sources. The process consists of an air-steam fluidized bed reactor, a hydrogen separation unit, a hydrogen compression unit, and a combined heat and power unit fed by the off-gas of the separation unit. Process simulations were carried out to perform sensitivity analyses to understand the variation in bio-hydrogen production’s thermodynamic and environmental performance when the steam to biomass ratios (S/B) vary from 0 to 1.25 at 850 °C. In addition, energy and exergy efficiencies and the integrated renewability (IR) of bio-hydrogen production are evaluated. As main results, the analysis showed that the highes... [more]

In this study, drying characteristics, kinetic modelling, energy and exergy analyses of a convective hot air dryer are presented for water yam. The drying experiments were carried out at temperature levels of 50, 60, and 70°C and slice thicknesses of 3, 6, and 9 mm. The effects of drying variables on the drying rate (DR), moisture diffusivity (Deff), activation energy (Ea), energy utilization (EU), energy utilization ratio (EUR), exergy loss (EXL), exergy efficiency (EXeff), improvement potential (IP), and exergetic sustainability index (ESI) were investigated. The results showed that increasing air temperature increased the DR, Deff, EU, EUR, EXL, EXeff, IP, and ESI, while increasing the slice thickness increased Deff and Ea, but decreased the DR. The highest Deff and Ea values were 4.2 × 10−8 m2/s, and 53 KJ/mol, respectively. EU and EUR varied from 10 to 150 J/s and 0.39 to 0.79, respectively. EXL and EXeff varied between 2 and 12.5 J/s and 58 to 75 %, respectively. Midilli’s model... [more]

This study reports the thermodynamic analysis of a high-temperature recuperative organic Rankine cycle comprising a water heating system that can provide a net power of 585.7 kW and hot water for domestic use at 35 °C. The performance was analysed using seasonal ambient temperature and water temperature data from Seoul, South Korea. The working fluid was separated into two different mass fractions after emerging from the turbine 1 outlet; one fraction provided heat to recuperate the organic Rankine cycle, and the other fraction was transferred to the water heating system for heating water. Mass fractions were balanced based on the projected seasonal need for hot water. Four working fluids with high critical temperatures and five working fluids with low critical temperatures were examined for top and bottom cycles, respectively. Chlorobenzene was selected for the top cycle and R601 was selected for the bottom cycle. The system achievement in individual months was analysed using thermal... [more]

In current power station boilers, fuel burns at a low temperature, which results in low exergy efficiency. This research combined the second law of t with the boiler structure to maximize the efficiency of a 350 MW power plant boiler. A three-dimensional simulation of the combustion process at the power plant boiler is performed. A one-dimensional simulation model of the boiler is then constructed to calculate the combustion exergy loss, heat transfer exergy loss, and boiler exergy efficiency. Under the principle of high-temperature air combustion technologies, this paper also proposes a new structure and improved operating parameters to improve the exergy efficiency of boilers by reducing the heat exchange area of the economizer and increasing the heat exchange area of the air preheater. Simulation results show that the exergy efficiency of the boiler increased from 47.29% to 48.35% through the modified model. The simulation outcomes can instruct future optimal boiler design and contr... [more]

The ground source heat pump heating system is considered as one of the best solutions for the transition towards green heating under the continental climate conditions like Kazakhstan. In this paper, experimental and theoretical investigations were carried out to develop a ground source heat pump-based heating system under the weather conditions in Kazakhstan and to evaluate its thermodynamic performance. The water-to-water heat pump heating system, integrated with a ground source heat exchanger and used refrigerant R134a, was designed to provide hot water to meet the requirements for space heating. The predicted values of the coefficient of performance and the experimental results were found to be in good agreement within 6.2%. The thermodynamic performance of the system was also assessed using various environment-friendly refrigerants, such as R152a, R450A, R513A, R1234yf and R1234ze, as potential replacements for R134a. Although R152a is found to be a good alternative for R134a in t... [more]