LAPSE:2025.0221
Published Article

LAPSE:2025.0221
Steady-State Digital Twin Development for Heat and Shaft-Work Integration in a Dual-Stage Pressure Nitric Acid Plant Retrofit
June 27, 2025
Abstract
This study focuses on enhancing heat and shaft power integration within existing nitric acid production processes to optimize waste heat recovery and identify opportunities to improve process efficiency. A digital twin of the operational plant is utilized, which features a dual-stage pressure nitric acid production process with a capacity of 50 tons/h of HNO3 (100% equivalent). The authors conducted a simultaneous analysis of the thermal energy potential and the expansion capacity of tail gases to effectively fulfil the primary process's heating, cooling, and power requirements while increasing steam generation through waste heat recovery, all without compromising plant throughput. The proposed process modifications lead to a 23.8% reduction in cooling water usage and a 35.6% decrease in CO2 equivalent emissions while achieving a 13.1% increase in steam generation. These utility savings culminate in a 10.2% enhancement in plant throughput.
This study focuses on enhancing heat and shaft power integration within existing nitric acid production processes to optimize waste heat recovery and identify opportunities to improve process efficiency. A digital twin of the operational plant is utilized, which features a dual-stage pressure nitric acid production process with a capacity of 50 tons/h of HNO3 (100% equivalent). The authors conducted a simultaneous analysis of the thermal energy potential and the expansion capacity of tail gases to effectively fulfil the primary process's heating, cooling, and power requirements while increasing steam generation through waste heat recovery, all without compromising plant throughput. The proposed process modifications lead to a 23.8% reduction in cooling water usage and a 35.6% decrease in CO2 equivalent emissions while achieving a 13.1% increase in steam generation. These utility savings culminate in a 10.2% enhancement in plant throughput.
Record ID
Keywords
Subject
Suggested Citation
Boldyryev S, Krajacic G. Steady-State Digital Twin Development for Heat and Shaft-Work Integration in a Dual-Stage Pressure Nitric Acid Plant Retrofit. Systems and Control Transactions 4:438-443 (2025) https://doi.org/10.69997/sct.127061
Author Affiliations
Boldyryev S: University of Zagreb Faculty of Mechanical Engineering and Naval Architecture, Zagreb, Croatia
Krajacic G: University of Zagreb Faculty of Mechanical Engineering and Naval Architecture, Zagreb, Croatia
Krajacic G: University of Zagreb Faculty of Mechanical Engineering and Naval Architecture, Zagreb, Croatia
Journal Name
Systems and Control Transactions
Volume
4
First Page
438
Last Page
443
Year
2025
Publication Date
2025-07-01
Version Comments
Original Submission
Other Meta
PII: 0438-0443-1106-SCT-4-2025, Publication Type: Journal Article
Record Map
Published Article

LAPSE:2025.0221
This Record
External Link

https://doi.org/10.69997/sct.127061
Article DOI
Download
Meta
Record Statistics
Record Views
968
Version History
[v1] (Original Submission)
Jun 27, 2025
Verified by curator on
Jun 27, 2025
This Version Number
v1
Citations
Most Recent
This Version
URL Here
http://psecommunity.org/LAPSE:2025.0221
Record Owner
PSE Press
Links to Related Works
References Cited
- Bouramdane AA. Multi-Criteria Evaluation of Carbon Capture Technologies in Steel, Cement, Petrochemical, and Fertilizer Industries: Insights for Emerging and Developed Countries. Sci. Total Environ. 957:177754 (2024) https://doi.org/10.1016/j.scitotenv.2024.177754
- Nascimento GRO, Dangelo JVH. Operating Parameters Analysis of a Nitric Acid Plant to Increase Production and Reduce NOx Gases Emission. Chem. Eng. Process. - Process Intensif. 196:109662 (2024) https://doi.org/10.1016/j.cep.2024.109662
- Pérez-Rami'rez J, Kapteijn F, Schöffel K, Moulijn JA. Formation and Control of N2O in Nitric Acid Production. Appl. Catal. B Environ. 44:117-151 (2003) https://doi.org/10.1016/S0926-3373(03)00026-2
- Clariant EnviCat N2O-S Catalyst to Cut CO2eq by 690,000 Tonnes/y at Hengli's Nitric Acid Plant in China. Focus Catal. 2024:6 (2024) https://doi.org/10.1016/j.focat.2024.11.063
- Aging of Industrial Fe-Zeolite Based Catalysts for Nitrous Oxide Abatement in Nitric Acid Production Plants. Catal. Sci. Technol. 12:7308-7321 (2022) https://doi.org/10.1039/D2CY01486F
- Buelvas Hernández A, Fajardo JG, Barreto D, Carrillo Caballero GE, Cárdenas Escorcia Y, Vidal Tovar CR, Gordon Hernández Y. Conventional and Advanced Exergoeconomic Indicators of a Nitric Acid Production Plant Concerning the Cooling Temperature in Compression Train's Intermediate Stages. Case Stud. Therm. Eng. 27:101214 (2021) https://doi.org/10.1016/j.csite.2021.101214
- Kirova-Yordanova Z. Application of the Exergy Method to the Environmental Impact Estimation: The Nitric Acid Production as a Case Study. Energy 36:3733-3744 (2011) https://doi.org/10.1016/j.energy.2010.12.039
- Abbasian Hamedani E, Abdalisousan A, Khoshgard A, Nazari M. Energy, Exergy, and Sustainability Analysis of an Industrial Nitric Acid Plant. Energy Sources Part Recovery Util. Environ. Eff. 45:10952-10970 (2023) https://doi.org/10.1080/15567036.2023.2253762
- Chatterjee IB, Joshi JB. Modeling, Simulation and Optimization: Mono Pressure Nitric Acid Process. Chem. Eng. J. 138:556-577 (2008) https://doi.org/10.1016/j.cej.2007.07.064
- Abbasian Hamedani E, Hamidzadeh Z, Mousavi SA, Kariman A, Mahnesaei A. Simulation of a Nitric Acid Production Unit in Aspen Hysys, 9th International Conference on Technology and Energy Management, Behshahr, Mazandaran, Iran (2024)
- Mukhitdinov D, Sattarov O, Akhmatov A, Abdullayeva D, Bekchanov E. Computer Simulation and Optimization of the Oxidation Process in the Production of Nitric Acid in the Aspen Plus Environment. E3S Web Conf. 417:05004 (2023) https://doi.org/10.1051/e3sconf/202341705004
- Ivaniš G, Lazarevic M, Radovic I, Kijevcanin M. Energy Integration of Nitric Acid Production Using Pinch Methodology. Hem. Ind. 69:39-39 (2014) https://doi.org/10.2298/HEMIND140204039I
- UniSim Design Suite. https://process.honeywell.com/us/en/products/industrial-software/process-optimization/unisim-design-suite
- UniSim Design, Simulation Basis, Reference Guide, Release 492. Honeywell (2022)
- Klemeš JJ, Varbanov PS, Alwi SRW, Manan ZA, Fan YV, Chin HH. Sustainable Process Integration and Intensification: Saving Energy, Water and Resources. Walter de Gruyter (2023) https://doi.org/10.1515/9783110782981
- Varbanov PS, Doyle S, Smith R. Modelling and Optimization of Utility Systems. Chem. Eng. Res. Des. 82:561-578 (2004) https://doi.org/10.1205/026387604323142603
- Smith R. Chemical Process Design and Integration. Wiley (2016)
- Peters MS, Timmerhaus KD. Plant Design and Economics for Chemical Engineers. McGraw-Hill (1980)
- Liu M, Shi Y, Fang F. Combined Cooling, Heating and Power Systems: A Survey. Renew. Sustain. Energy Rev. 35:1-22 (2014) https://doi.org/10.1016/j.rser.2014.03.054
(0.08 seconds)
[0.08 s]

