LAPSE:2024.0713
Published Article

LAPSE:2024.0713
Synergetic Mechanism of Multiple Industrial Solid Waste-Based Geopolymer Binder for Soil Stabilization: Optimization Using D-Optimal Mixture Design
June 6, 2024
Abstract
In order to improve the comprehensive utilization rate of industrial solid waste and the road quality, a novel low-carbon and environmental friendly soil stabilizer is proposed. In this study, steel slag (SS), carbide slag (CS), blast furnace slag (BFS), fly ash (FA), and desulfurized gypsum (DG) were used as raw materials to develop a multiple industrial solid waste-based soil stabilizer (MSWSS). The optimal mix ratio of the raw materials determined by D-optimal design was as follows: 5% SS, 50% CS, 15% BFS, 15% DG, and 15% FA. The 7-day unconfined compressive strength (UCS) of MSWSS-stabilized soil was 1.7 MPa, which was 36% higher than stabilization with ordinary portland cement (OPC) and met the construction requirements of highways. After 7 days of curing, the UCS of MSWSS-stabilized soil was significantly higher than that in the OPC group. X-ray powder diffraction (XRD), thermogravimetric analysis (TGA), and scanning electron microscopy (SEM) analysis indicated that the prominent hydration products were ettringite (AFt) and C-S-H gel. The results showed that an amount of AFt and C-S-H were formed in the initial stage of curing, resulting in a rapid improvement in early UCS. As the curing proceeded, the content of AFt and C-S-H increased constantly and grew intertwined with each other, which lead to the denser microstructure of stabilized soil and better mechanical strength.
In order to improve the comprehensive utilization rate of industrial solid waste and the road quality, a novel low-carbon and environmental friendly soil stabilizer is proposed. In this study, steel slag (SS), carbide slag (CS), blast furnace slag (BFS), fly ash (FA), and desulfurized gypsum (DG) were used as raw materials to develop a multiple industrial solid waste-based soil stabilizer (MSWSS). The optimal mix ratio of the raw materials determined by D-optimal design was as follows: 5% SS, 50% CS, 15% BFS, 15% DG, and 15% FA. The 7-day unconfined compressive strength (UCS) of MSWSS-stabilized soil was 1.7 MPa, which was 36% higher than stabilization with ordinary portland cement (OPC) and met the construction requirements of highways. After 7 days of curing, the UCS of MSWSS-stabilized soil was significantly higher than that in the OPC group. X-ray powder diffraction (XRD), thermogravimetric analysis (TGA), and scanning electron microscopy (SEM) analysis indicated that the prominent hydration products were ettringite (AFt) and C-S-H gel. The results showed that an amount of AFt and C-S-H were formed in the initial stage of curing, resulting in a rapid improvement in early UCS. As the curing proceeded, the content of AFt and C-S-H increased constantly and grew intertwined with each other, which lead to the denser microstructure of stabilized soil and better mechanical strength.
Record ID
Keywords
D-optimal mixture approach, hydration mechanism, industrial solid waste, soil stabilization
Subject
Suggested Citation
Wang X, Wang X, Fu P, Lei B, Shi J, Xu M. Synergetic Mechanism of Multiple Industrial Solid Waste-Based Geopolymer Binder for Soil Stabilization: Optimization Using D-Optimal Mixture Design. (2024). LAPSE:2024.0713
Author Affiliations
Wang X: School of Civil and Resources Engineering, University of Science and Technology Beijing, Beijing 100083, China; State Key Laboratory of Mineral Processing, Beijing 100160, China
Wang X: School of Civil and Resources Engineering, University of Science and Technology Beijing, Beijing 100083, China
Fu P: School of Civil and Resources Engineering, University of Science and Technology Beijing, Beijing 100083, China [ORCID]
Lei B: School of Civil and Resources Engineering, University of Science and Technology Beijing, Beijing 100083, China
Shi J: Cangzhou Municipal Engineering Company Limited, Cangzhou 061000, China; Road Materials and Technology Engineering Research Center of Hebei Province, Cangzhou 061000, China
Xu M: Cangzhou Municipal Engineering Company Limited, Cangzhou 061000, China; Road Materials and Technology Engineering Research Center of Hebei Province, Cangzhou 061000, China
Wang X: School of Civil and Resources Engineering, University of Science and Technology Beijing, Beijing 100083, China
Fu P: School of Civil and Resources Engineering, University of Science and Technology Beijing, Beijing 100083, China [ORCID]
Lei B: School of Civil and Resources Engineering, University of Science and Technology Beijing, Beijing 100083, China
Shi J: Cangzhou Municipal Engineering Company Limited, Cangzhou 061000, China; Road Materials and Technology Engineering Research Center of Hebei Province, Cangzhou 061000, China
Xu M: Cangzhou Municipal Engineering Company Limited, Cangzhou 061000, China; Road Materials and Technology Engineering Research Center of Hebei Province, Cangzhou 061000, China
Journal Name
Processes
Volume
12
Issue
3
First Page
436
Year
2024
Publication Date
2024-02-21
ISSN
2227-9717
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Original Submission
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PII: pr12030436, Publication Type: Journal Article
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LAPSE:2024.0713
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https://doi.org/10.3390/pr12030436
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