Due to the substantial usage of fossil fuels, the utilization of lignocellulosic biomass as renewable sources for fuels and chemical production has been widely explored. The dissolution of lignocellulosic biomass in proper solvents is vital prior to the extraction of its important constituents, and ionic liquids (ILs) have been found to be efficient solvents for biomass dissolution. However, the high viscosity of ILs limits the dissolution process. Therefore, with the aim to enhance the dissolution of lignocellulosic biomass, a series of new ether-functionalized ILs with low viscosity values were synthesized and characterized. Their properties, such as density, viscosity and thermal stability, were analyzed and discussed in comparison with a common commercial IL, namely 1-butyl-3-methylimidazolium chloride (BMIMCl). The presence of the ether group in the new ILs reduces the viscosity of the ILs to some appreciable extent in comparison to BMIMCl. 1-2(methoxyethyl)-3-methylimidazolium chloride (MOE-MImCl), which possesses the lowest viscosity value among the other ether-functionalized ILs, demonstrates an ability to be a powerful solvent in the application of biomass dissolution via the sonication method. In addition, an optimization study employing response surface methodology (RSM) was carried out in order to obtain the optimum conditions for maximum dissolution of biomass in the solvents. Results suggested that the maximum biomass dissolution can be achieved by using 3 weight% of initial biomass loading with 40% amplitude of sonication at 32.23 min of sonication period.