LAPSE:2021.0689
Published Article
LAPSE:2021.0689
Iron-Based Catalytically Active Complexes in Preparation of Functional Materials
Katarzyna Rydel-Ciszek, Tomasz Pacześniak, Izabela Zaborniak, Paweł Błoniarz, Karolina Surmacz, Andrzej Sobkowiak, Paweł Chmielarz
July 29, 2021
Iron complexes are particularly interesting as catalyst systems over the other transition metals (including noble metals) due to iron’s high natural abundance and mediation in important biological processes, therefore making them non-toxic, cost-effective, and biocompatible. Both homogeneous and heterogeneous catalysis mediated by iron as a transition metal have found applications in many industries, including oxidation, C-C bond formation, hydrocarboxylation and dehydration, hydrogenation and reduction reactions of low molecular weight molecules. These processes provided substrates for industrial-scale use, e.g., switchable materials, sustainable and scalable energy storage technologies, drugs for the treatment of cancer, and high molecular weight polymer materials with a predetermined structure through controlled radical polymerization techniques. This review provides a detailed statement of the utilization of homogeneous and heterogeneous iron-based catalysts for the synthesis of both low and high molecular weight molecules with versatile use, focusing on receiving functional materials with high potential for industrial application.
Keywords
“green” oxidants, controlled radical polymerization, heterogeneous catalysis, homogeneous catalysis, iron-based catalysts, oxidation processes
Suggested Citation
Rydel-Ciszek K, Pacześniak T, Zaborniak I, Błoniarz P, Surmacz K, Sobkowiak A, Chmielarz P. Iron-Based Catalytically Active Complexes in Preparation of Functional Materials. (2021). LAPSE:2021.0689
Author Affiliations
Rydel-Ciszek K: Department of Physical Chemistry, Faculty of Chemistry, Rzeszow University of Technology, Al. Powstańców Warszawy 6, 35-959 Rzeszów, Poland [ORCID]
Pacześniak T: Department of Physical Chemistry, Faculty of Chemistry, Rzeszow University of Technology, Al. Powstańców Warszawy 6, 35-959 Rzeszów, Poland
Zaborniak I: Department of Physical Chemistry, Faculty of Chemistry, Rzeszow University of Technology, Al. Powstańców Warszawy 6, 35-959 Rzeszów, Poland [ORCID]
Błoniarz P: Department of Physical Chemistry, Faculty of Chemistry, Rzeszow University of Technology, Al. Powstańców Warszawy 6, 35-959 Rzeszów, Poland [ORCID]
Surmacz K: Doctoral School of Engineering and Technical Sciences, Rzeszow University of Technology, Al. Powstańców Warszawy 8, 35-959 Rzeszów, Poland
Sobkowiak A: Department of Physical Chemistry, Faculty of Chemistry, Rzeszow University of Technology, Al. Powstańców Warszawy 6, 35-959 Rzeszów, Poland
Chmielarz P: Department of Physical Chemistry, Faculty of Chemistry, Rzeszow University of Technology, Al. Powstańców Warszawy 6, 35-959 Rzeszów, Poland [ORCID]
Journal Name
Processes
Volume
8
Issue
12
Article Number
E1683
Year
2020
Publication Date
2020-12-20
Published Version
ISSN
2227-9717
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Original Submission
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PII: pr8121683, Publication Type: Review
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LAPSE:2021.0689
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doi:10.3390/pr8121683
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Jul 29, 2021
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Jul 29, 2021
 
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Calvin Tsay
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