LAPSE:2020.0964
Published Article
LAPSE:2020.0964
A Fractal-Based Correlation for Time-Dependent Surface Diffusivity in Porous Adsorbents
Vassilis J. Inglezakis, Marco Balsamo, Fabio Montagnaro
September 15, 2020
Fluid−solid adsorption processes are mostly governed by the adsorbate transport in the solid phase and surface diffusion is often the limiting step of the overall process in microporous materials such as zeolites. This work starts from a concise review of concepts and models for surface transport and variable surface diffusivity. It emerges that the phenomenon of hindered surface diffusion for monolayer adsorption, which is common in zeolites, and models able to fit a non-monotonic trend of surface diffusivity against adsorbate solid phase concentration, have received limited attention. This work contributes to the literature of hindered diffusion by formulating a time-dependent equation for surface diffusivity based on fractal dynamics concepts. The proposed equation takes into account the contributions of both fractal-like diffusion (a time-decreasing term) and hopping diffusion (a time-increasing term). The equation is discussed and numerically analyzed to testify its ability to reproduce the possible different patterns of surface diffusivity vs. time.
Keywords
Adsorption, fractal-like dynamics, hindered diffusion, hopping, surface diffusivity, zeolites
Suggested Citation
Inglezakis VJ, Balsamo M, Montagnaro F. A Fractal-Based Correlation for Time-Dependent Surface Diffusivity in Porous Adsorbents. (2020). LAPSE:2020.0964
Author Affiliations
Inglezakis VJ: Environmental Science & Technology Group (ESTg), Chemical & Materials Engineering Department, School of Engineering & Digital Sciences, Nazarbayev University, Nur Sultan 010000, Kazakhstan; The Environment & Resource Efficiency Cluster (EREC), Nazarbayev [ORCID]
Balsamo M: Department of Chemical Sciences, University of Naples Federico II, Complesso Universitario di Monte Sant’Angelo, 80126 Naples, Italy
Montagnaro F: Department of Chemical Sciences, University of Naples Federico II, Complesso Universitario di Monte Sant’Angelo, 80126 Naples, Italy
Journal Name
Processes
Volume
8
Issue
6
Article Number
E689
Year
2020
Publication Date
2020-06-12
Published Version
ISSN
2227-9717
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Original Submission
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PII: pr8060689, Publication Type: Journal Article
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LAPSE:2020.0964
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doi:10.3390/pr8060689
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Sep 15, 2020
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Sep 15, 2020
 
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Calvin Tsay
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