Based on computational fluid dynamics (CFD) and Realizable k-ε turbulence model, we established a numerical simulation method for wind and vapor-concentration fields of various external floating-roof tanks (EFRTs) (single, two, and four) and verified its feasibility using wind-tunnel experiments. Subsequently, we analysed superposition effects of wind speed and concentration fields for different types of EFRTs. The results show that high concentrations of vapor are found near the rim gap of the floating deck and above the floating deck surface. At different ambient wind speeds, interference between tanks is different. When the ambient wind speed is greater than 2 m/s, vapor concentration in leeward area of the rear tank is greater than that between two tanks, which makes it easy to reach explosion limit. It is suggested that more monitoring should be conducted near the bottom area of the rear tank and upper area on the left of the floating deck. Superposition in a downwind direction from the EFRTs becomes more obvious with an increase in the number of EFRTs; vapor superposition occurs behind two leeward tanks after leakage from four large EFRTs. Considering safety, environmental protection, and personnel health, appropriate measures should be taken at these positions for timely monitoring, and control.