LAPSE:2020.0189
Published Article
LAPSE:2020.0189
Pd/Au Based Catalyst Immobilization in Polymeric Nanofibrous Membranes via Electrospinning for the Selective Oxidation of 5-Hydroxymethylfurfural
February 12, 2020
Innovative nanofibrous membranes based on Pd/Au catalysts immobilized via electrospinning onto different polymers were engineered and tested in the selective oxidation of 5-(hydroxymethyl)furfural in an aqueous phase. The type of polymer and the method used to insert the active phases in the membrane were demonstrated to have a significant effect on catalytic performance. The hydrophilicity and the glass transition temperature of the polymeric component are key factors for producing active and selective materials. Nylon-based membranes loaded with unsupported metal nanoparticles were demonstrated to be more efficient than polyacrylonitrile-based membranes, displaying good stability and leading to high yield in 2,5-furandicarboxylic acid. These results underline the promising potential of large-scale applications of electrospinning for the preparation of catalytic nanofibrous membranes to be used in processes for the conversion of renewable molecules.
Record ID
Keywords
electrospinning, HMF oxidation, polymeric catalytic membranes
Subject
Suggested Citation
Bonincontro D, Fraschetti F, Squarzoni C, Mazzocchetti L, Maccaferri E, Giorgini L, Zucchelli A, Gualandi C, Focarete ML, Albonetti S. Pd/Au Based Catalyst Immobilization in Polymeric Nanofibrous Membranes via Electrospinning for the Selective Oxidation of 5-Hydroxymethylfurfural. (2020). LAPSE:2020.0189
Author Affiliations
Bonincontro D: Department of Industrial Chemistry Toso Montanari, University of Bologna, Viale Risorgimento, 4, 40136 Bologna, Italy [ORCID]
Fraschetti F: Department of Industrial Chemistry Toso Montanari, University of Bologna, Viale Risorgimento, 4, 40136 Bologna, Italy
Squarzoni C: Department of Industrial Chemistry Toso Montanari, University of Bologna, Viale Risorgimento, 4, 40136 Bologna, Italy
Mazzocchetti L: Department of Industrial Chemistry Toso Montanari, University of Bologna, Viale Risorgimento, 4, 40136 Bologna, Italy; Interdepartmental Center for Industrial Research on Advanced Applications in Mechanical Engineering and Materials Technology, CIRI-MAM, [ORCID]
Maccaferri E: Department of Industrial Chemistry Toso Montanari, University of Bologna, Viale Risorgimento, 4, 40136 Bologna, Italy [ORCID]
Giorgini L: Department of Industrial Chemistry Toso Montanari, University of Bologna, Viale Risorgimento, 4, 40136 Bologna, Italy; Interdepartmental Center for Industrial Research on Advanced Applications in Mechanical Engineering and Materials Technology, CIRI-MAM, [ORCID]
Zucchelli A: Interdepartmental Center for Industrial Research on Advanced Applications in Mechanical Engineering and Materials Technology, CIRI-MAM, University of Bologna, Viale Risorgimento, 2, 40136 Bologna, Italy; Department of Industrial Engineering, University of [ORCID]
Gualandi C: Interdepartmental Center for Industrial Research on Advanced Applications in Mechanical Engineering and Materials Technology, CIRI-MAM, University of Bologna, Viale Risorgimento, 2, 40136 Bologna, Italy; Department of Chemistry Giacomo Ciamician and INSTM [ORCID]
Focarete ML: Department of Chemistry Giacomo Ciamician and INSTM UdR of Bologna, University of Bologna, Via Selmi, 2, 40126 Bologna, Italy [ORCID]
Albonetti S: Department of Industrial Chemistry Toso Montanari, University of Bologna, Viale Risorgimento, 4, 40136 Bologna, Italy [ORCID]
Fraschetti F: Department of Industrial Chemistry Toso Montanari, University of Bologna, Viale Risorgimento, 4, 40136 Bologna, Italy
Squarzoni C: Department of Industrial Chemistry Toso Montanari, University of Bologna, Viale Risorgimento, 4, 40136 Bologna, Italy
Mazzocchetti L: Department of Industrial Chemistry Toso Montanari, University of Bologna, Viale Risorgimento, 4, 40136 Bologna, Italy; Interdepartmental Center for Industrial Research on Advanced Applications in Mechanical Engineering and Materials Technology, CIRI-MAM, [ORCID]
Maccaferri E: Department of Industrial Chemistry Toso Montanari, University of Bologna, Viale Risorgimento, 4, 40136 Bologna, Italy [ORCID]
Giorgini L: Department of Industrial Chemistry Toso Montanari, University of Bologna, Viale Risorgimento, 4, 40136 Bologna, Italy; Interdepartmental Center for Industrial Research on Advanced Applications in Mechanical Engineering and Materials Technology, CIRI-MAM, [ORCID]
Zucchelli A: Interdepartmental Center for Industrial Research on Advanced Applications in Mechanical Engineering and Materials Technology, CIRI-MAM, University of Bologna, Viale Risorgimento, 2, 40136 Bologna, Italy; Department of Industrial Engineering, University of [ORCID]
Gualandi C: Interdepartmental Center for Industrial Research on Advanced Applications in Mechanical Engineering and Materials Technology, CIRI-MAM, University of Bologna, Viale Risorgimento, 2, 40136 Bologna, Italy; Department of Chemistry Giacomo Ciamician and INSTM [ORCID]
Focarete ML: Department of Chemistry Giacomo Ciamician and INSTM UdR of Bologna, University of Bologna, Via Selmi, 2, 40126 Bologna, Italy [ORCID]
Albonetti S: Department of Industrial Chemistry Toso Montanari, University of Bologna, Viale Risorgimento, 4, 40136 Bologna, Italy [ORCID]
Journal Name
Processes
Volume
8
Issue
1
Article Number
E45
Year
2020
Publication Date
2020-01-01
Published Version
ISSN
2227-9717
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Original Submission
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PII: pr8010045, Publication Type: Journal Article
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LAPSE:2020.0189
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doi:10.3390/pr8010045
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[v1] (Original Submission)
Feb 12, 2020
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Feb 12, 2020
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https://psecommunity.org/LAPSE:2020.0189
Original Submitter
Calvin Tsay
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