LAPSE:2019.1598
Published Article
LAPSE:2019.1598
The Synthesis of N-(Pyridin-2-yl)-Benzamides from Aminopyridine and Trans-Beta-Nitrostyrene by Fe2Ni-BDC Bimetallic Metal−Organic Frameworks
Trinh Duy Nguyen, Oanh Kim Thi Nguyen, Thuan Van Tran, Vinh Huu Nguyen, Long Giang Bach, Nhan Viet Tran, Dai-Viet N. Vo, Tuyen Van Nguyen, Seong-Soo Hong, Sy Trung Do
December 16, 2019
A bimetallic metal−organic framework material, which was generated by bridging iron (III) cations and nickel (II) cations with 1,4-Benzenedicarboxylic anions (Fe2Ni-BDC), was synthesized by a solvothermal approach using nickel (II) nitrate hexahydrate and iron (III) chloride hexahydrate as the mixed metal source and 1,4-Benzenedicarboxylic acid (H2BDC) as the organic ligand source. The structure of samples was determined by X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy, and nitrogen physisorption measurements. The catalytic activity and recyclability of the Fe2Ni-BDC catalyst for the Michael addition amidation reaction of 2-aminopyridine and nitroolefins were estimated. The results illustrated that the Fe2Ni-BDC catalyst demonstrated good efficiency in the reaction under optimal conditions. Based on these results, a reaction mechanism was proposed. When the molar ratio of 2-aminopyridine and trans-β-nitrostyrene was 1:1, and the solvent was dichloromethane, the isolated yield of pyridyl benzamide reached 82%; at 80 °C over 24 h. The catalyst can be reused without a substantial reduction in catalytic activity with 77% yield after six times of reuse.
Keywords
bimetallic metal–organic frameworks, decarboxylative amidation, metal–organic framework
Subject
Suggested Citation
Nguyen TD, Nguyen OKT, Tran TV, Nguyen VH, Bach LG, Tran NV, Vo DVN, Nguyen TV, Hong SS, Do ST. The Synthesis of N-(Pyridin-2-yl)-Benzamides from Aminopyridine and Trans-Beta-Nitrostyrene by Fe2Ni-BDC Bimetallic Metal−Organic Frameworks. (2019). LAPSE:2019.1598
Author Affiliations
Nguyen TD: Center of Excellence for Green Energy and Environmental Nanomaterials (; NTT Institute of High Technology, Nguyen Tat Thanh University, 300A Nguyen Tat Thanh Street, Ho Chi Minh City 755414, Vietnam [ORCID]
Nguyen OKT: Center of Excellence for Green Energy and Environmental Nanomaterials (; NTT Institute of High Technology, Nguyen Tat Thanh University, 300A Nguyen Tat Thanh Street, Ho Chi Minh City 755414, Vietnam [ORCID]
Tran TV: Center of Excellence for Green Energy and Environmental Nanomaterials (; NTT Institute of High Technology, Nguyen Tat Thanh University, 300A Nguyen Tat Thanh Street, Ho Chi Minh City 755414, Vietnam [ORCID]
Nguyen VH: Center of Excellence for Green Energy and Environmental Nanomaterials (; NTT Institute of High Technology, Nguyen Tat Thanh University, 300A Nguyen Tat Thanh Street, Ho Chi Minh City 755414, Vietnam [ORCID]
Bach LG: NTT Institute of High Technology, Nguyen Tat Thanh University, 300A Nguyen Tat Thanh Street, Ho Chi Minh City 755414, Vietnam
Tran NV: Faculty of Chemical Technology, Ho Chi Minh City University of Food Industry, 140 Le Trong Tan, Ho Chi Minh City 705800, Vietnam
Vo DVN: Center of Excellence for Green Energy and Environmental Nanomaterials ( [ORCID]
Nguyen TV: Institute of Chemistry, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Hanoi 10072, Vietnam
Hong SS: Department of Chemical Engineering, Pukyong National University, 365 Shinsunro, Nam-ku, Busan 48547, Korea
Do ST: Institute of Chemistry, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Hanoi 10072, Vietnam
Journal Name
Processes
Volume
7
Issue
11
Article Number
E789
Year
2019
Publication Date
2019-11-01
Published Version
ISSN
2227-9717
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PII: pr7110789, Publication Type: Journal Article
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LAPSE:2019.1598
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doi:10.3390/pr7110789
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Dec 16, 2019
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Dec 16, 2019
 
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Calvin Tsay
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