LAPSE:2019.1521
Published Article
LAPSE:2019.1521
Microstructure Control of Tubular Micro-Channelled Supports Fabricated by the Phase Inversion Casting Method
Yuliang Liu, Arash Rahimalimamaghani, Martin van Sint Annaland, Fausto Gallucci
December 10, 2019
Thin-film membrane layers coated onto porous supports is widely considered as an efficient way to obtain high-performance oxygen transport membranes with both good permeability and high mechanical strength. However, conventional preparation methods of membrane supports usually result in highly tortuous channels with high mass transfer resistance. Tubular porous MgO and MgO/CGO supports were fabricated with a simple phase inversion casting method. Long finger-like channels were obtained inside the dual-phase supports by adjusting the ceramic loading, polymer concentration and particle surface area, as well as by introducing ethanol inside the casting slurries. Slurries that exhibit lower viscosity in the zero-shear viscosity region resulted in more pronounced channel growth. These supports were used to produce thin supported CGO membranes for possible application in O2 separation. Similar shrinkage speeds for the different layers during the sintering process are crucial for obtaining dense asymmetric membranes. The shrinkage of the support tube at a high temperature was greatly affected by the polymer/ceramic ratio and compatible shrinkage behaviours of the two layers were realized with polymer/ceramic weight ratios between 0.175 and 0.225.
Keywords
ceramic membrane, CGO-MgO support, channel length, phase inversion casting, shrinkage behaviour, tubular micro-channelled support
Suggested Citation
Liu Y, Rahimalimamaghani A, van Sint Annaland M, Gallucci F. Microstructure Control of Tubular Micro-Channelled Supports Fabricated by the Phase Inversion Casting Method. (2019). LAPSE:2019.1521
Author Affiliations
Liu Y: Inorganic Membranes and Membrane Reactors, Sustainable Process Engineering, Department of Chemical Engineering and Chemistry, Eindhoven University of Technology, De Rondom 70, 5612 AZ Eindhoven, The Netherlands
Rahimalimamaghani A: Inorganic Membranes and Membrane Reactors, Sustainable Process Engineering, Department of Chemical Engineering and Chemistry, Eindhoven University of Technology, De Rondom 70, 5612 AZ Eindhoven, The Netherlands
van Sint Annaland M: Chemical Process Intensification, Department of Chemical Engineering and Chemistry, Eindhoven University of Technology, De Rondom 70, 5612 AZ Eindhoven, The Netherlands
Gallucci F: Inorganic Membranes and Membrane Reactors, Sustainable Process Engineering, Department of Chemical Engineering and Chemistry, Eindhoven University of Technology, De Rondom 70, 5612 AZ Eindhoven, The Netherlands
[Login] to see author email addresses.
Journal Name
Processes
Volume
7
Issue
6
Article Number
E322
Year
2019
Publication Date
2019-05-31
Published Version
ISSN
2227-9717
Version Comments
Original Submission
Other Meta
PII: pr7060322, Publication Type: Journal Article
Record Map
Published Article

LAPSE:2019.1521
This Record
External Link

doi:10.3390/pr7060322
Publisher Version
Download
Files
[Download 1v1.pdf] (7.4 MB)
Dec 10, 2019
License
CC BY 4.0
Meta
Record Statistics
Record Views
463
Version History
[v1] (Original Submission)
Dec 10, 2019
 
Verified by curator on
Dec 10, 2019
This Version Number
v1
Citations
Most Recent
This Version
URL Here
https://psecommunity.org/LAPSE:2019.1521
 
Original Submitter
Calvin Tsay
Links to Related Works
Directly Related to This Work
Publisher Version