LAPSE:2019.0984
Published Article
LAPSE:2019.0984
CO2 Hydrogenation to Methanol by a Liquid-Phase Process with Alcoholic Solvents: A Techno-Economic Analysis
Harri Nieminen, Arto Laari, Tuomas Koiranen
September 5, 2019
Synthesis of methanol from recirculated CO2 and H2 produced by water electrolysis allows sustainable production of fuels and chemical storage of energy. Production of renewable methanol has, however, not achieved commercial breakthrough, and novel methods to improve economic feasibility are needed. One possibility is to alter the reaction route to methanol using catalytic alcoholic solvents, which makes the process possible at lower reaction temperatures. To estimate the techno-economic potential of this approach, the feasibilities of the conventional gas-phase process and an alternative liquid-phase process employing 2-butanol or 1-butanol solvents were compared by means of flowsheet modelling and economic analysis. As a result, it was found that despite improved methanol yield, the presence of solvent adds complexity to the process and increases separation costs due to the high volatility of the alcohols and formation of azeotropes. Hydrogen, produced from wind electricity, was the major cost in all processes. The higher cost of the present, non-optimized liquid-phase process is largely explained by the heat required in separation. If this heat could be provided by heat integration, the resulting production costs approach the costs of the gas-phase process. It is concluded that the novel reaction route provides promising possibilities, but new breakthroughs in process synthesis, integration, optimization, and catalysis are needed before the alcoholic solvent approach surpasses the traditional gas-phase process.
Keywords
alcohol promoted, CO2 hydrogenation, liquid-phase process, methanol synthesis, process simulation, Technoeconomic Analysis
Suggested Citation
Nieminen H, Laari A, Koiranen T. CO2 Hydrogenation to Methanol by a Liquid-Phase Process with Alcoholic Solvents: A Techno-Economic Analysis. (2019). LAPSE:2019.0984
Author Affiliations
Nieminen H: Laboratory of Process Systems Engineering, Lappeenranta-Lahti University of Technology, P.O. Box 20 FI-53851 Lappeenranta, Finland
Laari A: Laboratory of Process Systems Engineering, Lappeenranta-Lahti University of Technology, P.O. Box 20 FI-53851 Lappeenranta, Finland
Koiranen T: Laboratory of Process Systems Engineering, Lappeenranta-Lahti University of Technology, P.O. Box 20 FI-53851 Lappeenranta, Finland
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Journal Name
Processes
Volume
7
Issue
7
Article Number
E405
Year
2019
Publication Date
2019-07-01
Published Version
ISSN
2227-9717
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PII: pr7070405, Publication Type: Journal Article
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LAPSE:2019.0984
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doi:10.3390/pr7070405
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Sep 5, 2019
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Calvin Tsay
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