LAPSE:2019.0888
Published Article
LAPSE:2019.0888
Hydroxymethylation-Modified Lignin and Its Effectiveness as a Filler in Rubber Composites
Nor Anizah Mohamad Aini, Nadras Othman, M. Hazwan Hussin, Kannika Sahakaro, Nabil Hayeemasae
July 31, 2019
Kraft lignin was modified by using hydroxymethylation to enhance the compatibility between rubber based on a blend of natural rubber/polybutadiene rubber (NR/BR) and lignin. To confirm this modification, the resultant hydroxymethylated kraft lignin (HMKL) was characterized using Fourier transform infrared (FTIR) and nuclear magnetic resonance (NMR) spectroscopy. It was then incorporated into rubber composites and compared with unmodified rubber. All rubber composites were investigated in terms of rheology, mechanical properties, aging, thermal properties, and morphology. The results show that the HMKL influenced the mechanical properties (tensile properties, hardness, and compression set) of NR/BR composites compared to unmodified lignin. Further evidence also revealed better dispersion and good interaction between the HMKL and the rubber matrix. Based on its performance in NR/BR composites, hydroxymethylated lignin can be used as a filler in the rubber industry.
Keywords
bio-filler, hydroxymethylation, lignin, rubber composite
Subject
Suggested Citation
Mohamad Aini NA, Othman N, Hussin MH, Sahakaro K, Hayeemasae N. Hydroxymethylation-Modified Lignin and Its Effectiveness as a Filler in Rubber Composites. (2019). LAPSE:2019.0888
Author Affiliations
Mohamad Aini NA: School of Materials and Mineral Resources Engineering, Engineering Campus, Universiti Sains Malaysia, Nibong Tebal 14300, Malaysia
Othman N: School of Materials and Mineral Resources Engineering, Engineering Campus, Universiti Sains Malaysia, Nibong Tebal 14300, Malaysia
Hussin MH: School of Chemical Science, Universiti Sains Malaysia, Minden 11800, Malaysia [ORCID]
Sahakaro K: Department of Rubber Technology and Polymer Science, Faculty of Science and Technology, Pattani Campus, Prince of Songkla University, Pattani 94000, Thailand [ORCID]
Hayeemasae N: Department of Rubber Technology and Polymer Science, Faculty of Science and Technology, Pattani Campus, Prince of Songkla University, Pattani 94000, Thailand
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Journal Name
Processes
Volume
7
Issue
5
Article Number
E315
Year
2019
Publication Date
2019-05-25
Published Version
ISSN
2227-9717
Version Comments
Original Submission
Other Meta
PII: pr7050315, Publication Type: Journal Article
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LAPSE:2019.0888
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doi:10.3390/pr7050315
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Jul 31, 2019
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CC BY 4.0
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Jul 31, 2019
 
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Jul 31, 2019
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Original Submitter
Calvin Tsay
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