Water pollution is a worldwide problem that needs to be solved urgently and has a significant impact on the efficiency of sustainable cities. The evaluation of water pollution is a Multiple Criteria Decision-Making (MCDM) problem and using a MCDM model can help control water pollution and protect human health. However, different evaluation methods may obtain different results. How to effectively coordinate them to obtain a consensus result is the main aim of this work. The purpose of this article is to develop an ensemble learning evaluation method based on the concept of water quality to help policy-makers better evaluate surface water quality. A valid application is conducted to illustrate the use of the model for the surface water quality evaluation problem, thus demonstrating the effectiveness and feasibility of the proposed model.