Dimethyl ether (DME)/diesel blended fuels are used to improve the emissions caused by spray wall impingement during the early injection period. However, experimental results have showed that the spray wall impingement still cannot be avoided due to the engine structure and low density of the in-cylinder charge at the early injection timing. Furthermore, the wall film formed in the spray wall impingement process directly affects fuel/air mixture formation, combustion, exhaust emissions and oil quality subsequently. In this paper, the wall film distribution of DME/diesel blended fuels formed during the spray wall impingement process has been experimentally investigated. The variations of wall film distribution, wall film area and average thickness with different injection pressures, impingement distances, impingement angles and blending ratios have been discussed under both dry wall and wet wall conditions. Results showed that the wall film distribution styles were mainly determined by the spray impingement momentum. The variation of the wall film area and average thickness were affected by three factors including the impingement momentum, wall film mass and fuel properties. Correlation analysis was introduced in order to evaluate the effect of each impact factor on the variation of wall film area and average thickness.